(9-菲基)甲基甲基丙烯酸酯 | 53223-82-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: (9-菲基)甲基甲基丙烯酸酯
• 中文别名: (9-菲基)甲基丙烯酸甲酯
• 英文名称: 9-(methacryloyloxymethyl)phenanthrene
• 英文别名: 9-(methacryloxymethyl)phenanthrene；(9-Phenanthryl)methyl methacrylate；phenanthren-9-ylmethyl 2-methylprop-2-enoate
• CAS: 53223-82-8
• 化学式: C₁₉H₁₆O₂
• 分子量: 276.335
• InChiKey: SKCCBBCEVTUWBS-UHFFFAOYSA-N

物化性质

• 熔点：
  75-76°C
• 溶解度：
  乙腈（少量溶解）、乙酸乙酯（少量溶解）、甲醇（少量溶解）

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916140000

反应信息

• 作为产物：
  描述：

  9-氯甲基菲 、 potassium methacrylate 在 对苯二酚 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 (9-菲基)甲基甲基丙烯酸酯
  参考文献：
  名称：

  Matynia,T. et al., Roczniki Chemii, 1974, vol. 48, p. 525 - 529

  摘要：

  DOI：

文献信息

• Functionalized Photoreactive Compounds
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20080274304A1

  公开（公告）日：2008-11-06

  The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式(I)的官能化光反应化合物，特别适用于液晶对准材料。由于在特定分子系统中的不饱和键直接连接到两个不饱和环系统上附加了一个电子受体基团，因此在包含本发明的这些官能化光反应化合物的材料中可以实现异常高的光敏性、优异的对准性能以及良好的机械稳健性。
• [EN] CYANOSTILBENES<br/>[FR] CYANOSTILBÈNES
  申请人：ROLIC AG

  公开号：WO2014191292A1

  公开（公告）日：2014-12-04

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及一种新型化合物，特别适用于用于光学或电光应用的从材料，尤其是液晶的定向，特别是光定向，如安全应用、液晶器件或光学或电光薄膜。
• CYANOSTILBENES
  申请人：ROLIC AG

  公开号：US20160083655A1

  公开（公告）日：2016-03-24

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及新型化合物，特别适用于对从材料进行定向，尤其是光定向，特别是用于光学或电光应用的从材料，例如安全应用、液晶器件或光学或电光薄膜。
• Fluorescent polymers and coating compositions
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0808855A2

  公开（公告）日：1997-11-26

  Disclosed is a method of preparing a fluorescent polymer, whereby an ethylenically unsaturated monomer is copolymerized with a polynuclear aromatic hydrocarbon or a substituted aromatic derivative thereof, such that the resultant polymer is fluorescent. Also disclosed are coating compositions containing such fluorescent polymers.

  本发明公开了一种荧光聚合物的制备方法，即乙烯基不饱和单体与多核芳香烃或其取代芳香衍生物共聚，从而得到荧光聚合物。还公开了含有这种荧光聚合物的涂料组合物。
• Method for identifying and quantifying fluorescent polymers
  申请人：ROHM AND HAAS COMPANY

  公开号：EP1205500A2

  公开（公告）日：2002-05-15

  The present invention is directed to a method for identifying and quantifying the amount, if any, of fluorescent polymer contained in a coating composition, such method comprising the steps of: (a) obtaining a sample of the coating composition or resulting coating to be tested; (b) detecting the fluorescence; and (c) measuring the intensity or the wavelength of the fluorescence of the fluorescent polymer contained in the sample.

  本发明涉及一种识别和量化涂层组合物中所含荧光聚合物量（如有）的方法，该方法包括以下步骤：(a) 获得待测涂层组合物或所得涂层的样品；(b) 检测荧光；以及 (c) 测量样品中所含荧光聚合物的荧光强度或波长。