1,1-二甲氧基-3-(甲硫基)丙烷 | 13214-29-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1,1-二甲氧基-3-(甲硫基)丙烷
• 英文名称: 1,1-dimethoxy-3-methylsulfanyl-propane
• 英文别名: 3-methylsulfanyl-propionaldehyde dimethyl acetal；3-Methylmercapto-propionaldehyd-dimethylacetal；1,1-Dimethoxy-3-methylmercapto-propan；1,1-dimethoxy-3-(methylthio)propane；1,1-dimethoxy-3-methylthiopropane；1,1-dimethoxy-3-methylsulfanylpropane
• CAS: 13214-29-4
• 化学式: C₆H₁₄O₂S
• 分子量: 150.242
• InChiKey: BNYOSIKNPOOYIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.8
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2930909090

反应信息

• 作为产物：
  描述：

  Trimethyl Ortho(methylthio)propanoate 在 lithium aluminium tetrahydride 、 苯 作用下， 生成 1,1-二甲氧基-3-(甲硫基)丙烷
  参考文献：
  名称：

  A NEW METHOD FOR THE CONVERSION OF NITRILES TO ALDEHYDES¹

  摘要：

  DOI：

  10.1021/ja01154a547

文献信息

• Methional derivatives and compositions with a growth regulating effect
  申请人：Philagro S.A.

  公开号：US04153442A1

  公开（公告）日：1979-05-08

  Plant growth-regulating compounds of the formula ##STR1## wherein X and Y are separately oxygen, sulfur, N-B where B is hydrogen, lower alkyl, or acyl; R and R' are separately lower alkyl, acyl, amido, or form a cycle with ##STR2## corresponding to the formula ##STR3## in which R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are separately hydrogen, lower alkyl, halogen-substituted lower alkyl, NO.sub.2, hydroxy or lower alkoxy, and A is a single bond or an alkylene chain of 1-4 carbons, or an alkylene chain of 1-4 carbons interrupted by oxygen or N--B' where B' is hydrogen, lower alkyl, lower halogen-aided alkyl, lower hydroxylated alkyl, lower acyl, or a cycle having in common with the preceding cycle 1 or 2 carbon atoms and containing from 3 to 6 carbons, up to 2 oxygens and/or a group N-B, or a cycle corresponding to the formula

  植物生长调节化合物的公式为##STR1##其中X和Y分别为氧，硫，N-B，其中B为氢，较低的烷基或酰基；R和R'分别为较低的烷基，酰基，酰胺基，或形成与##STR2##对应的环式##STR3##其中R.sub.1，R.sub.2，R.sub.3和R.sub.4分别为氢，较低的烷基，卤代较低的烷基，NO.sub.2，羟基或较低的烷氧基，而A是1-4个碳原子的单键或烷基链，或被氧或N-B'中断的1-4个碳原子的烷基链，其中B'为氢，较低的烷基，较低的卤代烷基，较低的羟基化烷基，较低的酰基，或含有与前述环式1或2个碳原子相同且含有3-6个碳原子，最多2个氧原子和/或N-B基团的环式。
• Methional derivatives and compositions with a growth-regulating effect
  申请人：Philagro, service Brevets

  公开号：US04224051A1

  公开（公告）日：1980-09-23

  Plant growth-regulating compounds of the formula ##STR1## wherein X and Y are separately oxygen, sulfur, N-B where B is hydrogen, lower alkyl, or acyl; R and R' are separately lower alkyl, acyl, amido, or form a cycle with ##STR2## corresponding to the formula ##STR3## in which R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are separately hydrogen, lower alkyl, halogen-substituted lower alkyl, NO.sub.2, hydroxy or lower alkoxy, and A is a single bond or an alkylene chain of 1-4 carbons, or an alkylene chain of 1-4 carbons interrupted by oxygen or N-B' where B' is hydrogen, lower alkyl, lower halogen-aided alkyl, lower hydroxylated alkyl, lower acyl, or a cycle having in common with the preceding cycle 1 or 2 carbon atoms and containing from 3 to 6 carbons, up to 2 oxygens and/or a group N-B, or a cycle corresponding to the formula ##STR4##

  式为##STR1##的植物生长调节化合物，其中X和Y分别为氧、硫、N-B，其中B为氢、低碳基或酰基；R和R'分别为低碳基、酰基、酰胺基或形成与##STR2##对应的环式##STR3##，其中R.sub.1、R.sub.2、R.sub.3和R.sub.4分别为氢、低碳基、卤素取代的低碳基、NO.sub.2、羟基或低碳氧基，A为单键或1-4碳的烷基链或由氧或N-B'（其中B'为氢、低碳基、低卤素辅助烷基、低羟基化烷基、低酰基）中断的1-4碳的烷基链，或与前述环式共有1或2个碳原子并含有3至6个碳原子、最多2个氧原子和/或一个N-B基团的环式##STR4##。
• Addition reaction of chloromethyl methyl sulfide to olefins in sulfuric acid. Synthesis of 3-(methylthio)propionaldehyde
  作者：Takehiko Ichikawa、Hiroko Owatari、Tetsuya Kato

  DOI：10.1021/jo00827a011

  日期：1970.2
• The relative abilities of methoxy and methylthio substituents to stabilize double bonds
  作者：Jack Hine、Louis G. Mahone、Charles L. Liotta

  DOI：10.1021/jo01283a053

  日期：1967.8
• US4101307A
  申请人：——

  公开号：US4101307A

  公开（公告）日：1978-07-18