1,10-双(4-甲氧基苯基)癸烷 | 4280-60-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 1,10-双(4-甲氧基苯基)癸烷
• 英文名称: 1,10-bis-para-anisyldecane
• 英文别名: 1,10-bis(4-methoxyphenyl)decane；1,10-Bis-(4-methoxy-phenyl)-decan；1-Methoxy-4-[10-(4-methoxyphenyl)decyl]benzene
• CAS: 4280-60-8
• 化学式: C₂₄H₃₄O₂
• 分子量: 354.533
• InChiKey: RTURVHFRNGIAQJ-UHFFFAOYSA-N

物化性质

• 熔点：
  69.5-70 °C
• 沸点：
  470.4±20.0 °C(Predicted)
• 密度：
  0.976±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  26
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,10-双(4-甲氧基苯基)癸烷 在 ammonium cerium(IV) nitrate 、 四丁基碘化铵 作用下， 以 乙腈 为溶剂， 反应 72.0h， 以31%的产率得到1,10-bis-(3-iodo-4-methoxyphenyl)decane
  参考文献：
  名称：

  Catlin, Kelly K.; Heldrich, Frederick J., Synthetic Communications, 1990, vol. 20, # 3, p. 439 - 446

  摘要：

  DOI：
• 作为产物：
  描述：

  ethyl 5-(4-methoxyphenyl)pentanoate 在 copper-magnesium alloy 、 乙醚 、 乙醇 、 sodium 、 三溴化磷 、 magnesium 、 Petroleum ether 作用下， 生成 1,10-双(4-甲氧基苯基)癸烷
  参考文献：
  名称：

  The elasticity of the exine

  摘要：

  We pressed pollen grain exines of ten genera with sizes ranging from about 20 to over 100 mu m in diameter past a piston in a close fitting cylinder. The clearance between piston and cylinder was about 20 mu m. Except for exines of Betula all the other pollen types were at least twice the clearance diameter and could be expected to be greatly deformed, crushed or fractured. Cracks were evident with the light microscope in some grains and a few were clearly deformed but most appeared intact, even exines of Zea mays at a diameter of 100-110 mu m. With scanning electron microscopy cracks were apparent in most of the large grains (Zea, Lilium, Pinus, Crinum and Epilobium) but not in the smaller grains (Betula, Ephedra, Tulipa, Fagus and Typha). We also found many exines within exines. In some cases, e.g., Lilium, the exines entered through apertures but in other grains such as Zea and Pinus, exines came in through cracks which had opened during acetolysis or centrifugation, then closed so tightly that the cracks were difficult to see with light microscopy. This opening and closing of cracks in exines means that the pollen grain exine is very flexible and resilient and capable of withstanding shock without permanent deformation. To regain their original form the exine components that were severely cracked, ruptured or partly separated must spring back together like the partly separated halves of a tennis ball.

  DOI：

  10.1080/00173130150503759

文献信息

• Triply Threaded [4]Rotaxanes
  作者：Jonathan J. Danon、David A. Leigh、Paul R. McGonigal、John W. Ward、Jhenyi Wu

  DOI：10.1021/jacs.6b07733

  日期：2016.9.28

  three axles threaded through a single ring have been prepared through active metal template synthesis. Nickel-catalyzed sp(3)-sp(3) homocouplings of alkyl bromide "half-threads" through 37- and 38-membered 2,2':6',2″-terpyridyl macrocycles generate triply threaded [4]rotaxanes in up to 11% yield. An analogous 39-membered macrocycle produced no rotaxane products under similar conditions. The constitutions

  [4]通过活性金属模板合成制备了具有三个轴穿过单个环的轮烷。镍催化的 sp(3)-sp(3) 烷基溴“半线”通过 37 和 38 元 2,2':6',2"-三联吡啶大环的同偶联产生三重线 [4] 轮烷到 11% 的收率。类似的 39 元大环在类似条件下不产生轮烷产物。[4]轮烷的组成通过核磁共振光谱和质谱测定。双螺纹 [3] 轮烷也从反应中获得，但没有分离出 [2] 轮烷，这表明在脱金属后，单螺纹轮烷的轴可以滑过一个大环，该大环足够容纳三个螺纹。
• Synthesis and demethylation of 4,22-dimethoxy[2.10]metacyclophan-1-yne with BBr₃ to afford a novel [10](2,9)-5a,11a-benzofuro-5a-bora-11-bromochromenophane
  作者：Yuki Uchikawa、Kazuya Tazoe、Syogo Tanaka、Xing Feng、Taisuke Matsumoto、Junji Tanaka、Takehiko Yamato

  DOI：10.1139/v2012-014

  日期：2012.5

  4,22-Dimethoxy[2.10]metacyclophan-1-yne was prepared by bromination of [2.10]metacyclophan-1-ene followed by the dehydrobromination of the bromine adduct with KOBu-t. Treatment of 4,22-dimethoxy[2.10]metacyclophan-1-yne with BBr₃ in CH₂Cl₂ at room temperature led to the demethylation and a successive intramolecular cyclization reaction to afford a novel [10](2,9)-5a,11a-benzofuro-5a-bora-11-bromochromenophane in good yield. Similar treatment of a mixture of the corresponding meso- and dl-1,2-dibromo-4,22-dimethoxy[2.10]metacyclophane with BBr₃ in CH₂Cl₂ under the same conditions described above afforded cis-4b,9b-dihydro[10]benzofuro[3,2-b]benzofuranophane in 83% yield.

  4,22-二甲氧基[2.10]间环戊二炔通过对[2.10]间环戊-1-烯进行溴化反应，然后用KOBu-t对溴加合物进行脱溴反应制备。在室温下，用BBr3处理4,22-二甲氧基[2.10]间环戊二炔在CH2Cl2中，导致去甲基化和连续的分子内环化反应，产生一种新型的[10](2,9)-5a,11a-苯并呋喃-5a-硼-11-溴色烯烷，收率较高。类似地，将相应的中间体和dl-1,2-二溴-4,22-二甲氧基[2.10]间环戊烷混合物用BBr3在CH2Cl2中在相同条件下处理，得到83%产率的顺式-4b,9b-二氢[10]苯并呋喃[3,2-b]苯并呋喃烷。
• Synthesis and Structures of [2. <i>n</i> ]Metacyclophan‐1‐enes and their Conversion to Highly Strained [2. <i>n</i> ]Metacyclophane‐1‐ynes
  作者：Thamina Akther、Md. Monarul Islam、Zannatul Kowser、Taisuke Matsumoto、Junji Tanaka、Shofiur Rahman、Abdullah Alodhayb、Paris E. Georghiou、Carl Redshaw、Takehiko Yamato

  DOI：10.1002/ejoc.202000548

  日期：2020.7.23

  Synthesis and structures of [2.n ]metacyclophan‐1‐enes and their conversion to highly strained [2.n ]metacyclophane‐1‐ynes, in which the triple bonds are distorted from linearity with bond angles of 156.7°–161.4°, are discussed.

  ［2。n ] metacyclophan-1-烯及其转化为高应变[2。讨论了n ] metacyclophane-1-ynes，其中三键从156.7°–161.4°的键角线性偏离。
• α,ι-Di-p-hydroxyphenyl Alkanes
  作者：Edwin M. Richardson、E. Emmet Reid

  DOI：10.1021/ja01859a046

  日期：1940.2
• Kadkhodayan, Miryam; Singleton, Terry; Heldrich, F. J., Synthetic Communications, 1984, vol. 14, # 8, p. 707 - 712
  作者：Kadkhodayan, Miryam、Singleton, Terry、Heldrich, F. J.

  DOI：——

  日期：——