1,2,5,6-二环氧-6-甲基-2-乙烯基-庚烷 | 84123-50-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 1,2,5,6-二环氧-6-甲基-2-乙烯基-庚烷
• 英文名称: 1,2;5,6-diepoxy-6-methyl-2-vinyl-heptane
• 英文别名: 1,2;5,6-Diepoxy-6-methyl-2-vinyl-heptan；3-[2-(2-Ethenyloxiran-2-yl)ethyl]-2,2-dimethyloxirane
• CAS: 84123-50-2
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: GZPMGNOGYNJNDI-UHFFFAOYSA-N

物化性质

• 沸点：
  219.6±15.0 °C(Predicted)
• 密度：
  1.052±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2,5,6-二环氧-6-甲基-2-乙烯基-庚烷 在 钯 作用下， 生成 2-ethyl-1,2;5,6-diepoxy-6-methyl-heptane
  参考文献：
  名称：

  Pigulewskii; Adrowa, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 136; engl. Ausg. S. 151

  摘要：

  DOI：
• 作为产物：
  描述：

  月桂烯 在 过氧乙酸 、 乙醚 作用下， 生成 2,2-二甲基-3-(3-亚甲基戊-4-烯基)环氧乙烷 、 1,2,5,6-二环氧-6-甲基-2-乙烯基-庚烷
  参考文献：
  名称：

  Pigulewskii; Adrowa, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 136; engl. Ausg. S. 151

  摘要：

  DOI：

文献信息

• Photocurable resin composition and resin composition for plastics comprising the same
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1630215A2

  公开（公告）日：2006-03-01

  A photocurable resin composition comprises a cationic polymerizable compound (A), an acrylic resin (B) and a cationic photopolymerization initiator (C), in which the acrylic resin (B) has a cationic polymerizable functional group, and the content of the component (A) is 30 to 95 parts by mass and the content of the component (B) is 5 to 70 parts by mass, based on 100 parts by mass of the total amount of the components (A) and (B). In addition, the functional group of the acrylic resin (B) preferably contains at least one of a cyclic ether group, a vinyloxy group, an acid adduct of a vinyloxy group, and an active hydrogen group, with the active hydrogen group being a hydroxyl group is more preferable. The photocurable resin composition which has sufficient curability and sufficient adhesiveness to rigid plastics such as polycarbonate and PET having poor adhesive property.

  一种光固化树脂组合物包括阳离子可聚合化合物 (A)、丙烯酸树脂 (B) 和阳离子光聚合引发剂 (C)，其中丙烯酸树脂 (B) 具有阳离子可聚合官能团，以组分 (A) 和 (B) 总量的 100 重量份为基准，组分 (A) 的含量为 30 至 95 重量份，组分 (B) 的含量为 5 至 70 重量份。此外，丙烯酸树脂（B）的官能团最好含有环醚基、乙烯氧基、乙烯氧基的酸加合物和活性氢基中的至少一种，活性氢基最好是羟基。 这种光固化树脂组合物对聚碳酸酯和 PET 等粘合性较差的硬质塑料具有足够的固化性和足够的粘合性。
• CATIONICALLY PHOTOPOLYMERIZABLE RESIN COMPOSITION AND OPTICAL DISK SURFACE PROTECTION MATERIAL
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1630189A1

  公开（公告）日：2006-03-01

  The invention provides a cation polymerizable resin composition excellent in curing properties and corrosion resistance with less resin coloration and less cure shrinkage, which is a material suitable as a surface protective material for optical disk. Specifically, the cation polymerizable resin composition comprises an epoxy compound (A) as an essential ingredient represented by formula 1 wherein R1 and R2 each represent a saturated or unsaturated carbon atom, and R3 represents a hydrogen atom or a saturated or unsaturated carbon atom, a cation polymerizable compound (B) other than the epoxy compound represented by formula 1, a photo cation polymerization initiator (C) and a photo radical polymerization initiator (D).

  本发明提供了一种固化性能和耐腐蚀性能优异、树脂着色少、固化收缩小的阳离子可聚合树脂组合物，它是一种适用于光盘表面保护材料的材料。具体地说，阳离子可聚合树脂组合物包括作为基本成分的环氧化合物（A）（由式 1 表示，其中 R1 和 R2 分别代表饱和或不饱和碳原子，R3 代表氢原子或饱和或不饱和碳原子）、除式 1 所示环氧化合物以外的阳离子可聚合化合物（B）、光阳离子聚合引发剂（C）和光自由基聚合引发剂（D）。
• Epoxidation of olefins by β-bromoalkoxydimethylsulfonium ylides
  作者：George Majetich、Joel Shimkus、Yang Li

  DOI：10.1016/j.tetlet.2010.10.068

  日期：2010.12

  Olefins can be converted to their respective epoxides in a one-pot procedure by dissolving the olefin in anhydrous DMSO, adding NBS to the reaction mixture to generate a beta-bromoalkoxydimethylsulfonium ylide, and then adding DBU to the reaction mixture. A large variety of alkenes were successfully epoxidized with yields largely dependent on the structure of the alkene. Most importantly, the facial selectivity of this one-pot process is the opposite of that observed when using traditional epoxidizing reagents. Electron-poor alkenes are not epoxidized under these conditions. (C) 2010 Published by Elsevier Ltd.
• Epoxidation process
  申请人：DU PONT

  公开号：US02838524A1

  公开（公告）日：1958-06-10
• Phosphates of styrene-epoxy compound copolymers
  申请人：DU PONT

  公开号：US02692876A1

  公开（公告）日：1954-10-26