Process for preparing hydrophobically modified low foaming copolymers, hydrophobically modified low foaming copolymers and their use as cement additives
申请人:Dow Deutschland Inc.,
Zweigniederlassung Stade
公开号:EP0985691A1
公开(公告)日:2000-03-15
The present invention refers to a process for the preparation of a copolymer containing structural units derived from alpha, beta unsaturated mono- or dicarboxylic acids and their salts, half-esters of dicarboxylic acids or salts thereof, an olefin and a hydrophobic moiety, said hydrophobic moiety being incorporated into the copolymer chain; said process comprises reacting
a) at least one monomer selected from alpha, beta unsaturated mono-carboxylic acids and their salts; and alpha, beta unsaturated dicarboxylic acids, their halfesters and salts thereof;
b) at least one monomer selected from olefins; and
c) at least one hydrophobic compound free of olefinic unsaturation containing units of the formula:
wherein R1 is independently at each occurrence selected from hydrogen and C1-C4 alkyl with the proviso that at least one R1 is selected from C1-C4 alkyl in an amount of 0.01 to 30 wt% based on the total amount of a), b) and c);
at a temperature in the range of 25°C-100°C, and in the presence of a free-radical initiator in an amount of 1.5wt%-25wt% based on the total weight of a), b) and c), to copolymers obtainable therefrom and the use of these polymers as cement additives.
本发明涉及一种共聚物的制备工艺,该共聚物含有由α、β不饱和单羧酸或二羧酸及其盐、二羧酸半酯或其盐、烯烃和疏水基团衍生而来的结构单元,所述疏水基团与共聚物链结合;所述工艺包括以下反应
a) 至少一种选自 α、β 不饱和单羧酸及其盐;以及 α、β 不饱和二羧酸及其半酯和盐的单体;
b) 至少一种选自烯烃的单体;以及
c) 至少一种不含烯烃不饱和的疏水性化合物,含有式中的单元:
其中 R1 在每次出现时均独立地选自氢和 C1-C4 烷基,但至少有一个 R1 选自 C1-C4 烷基,其含量为 a)、b)和 c)总量的 0.01 至 30 wt%;
在 25℃-100℃的温度范围内,在自由基引发剂的存在下,以 a)、b)和 c)的总重量为基准,加入 1.5wt%-25wt% 的自由基引发剂,得到共聚物,并将这些聚合物用作水泥添加剂。