Ethane-1,2-diol;1-methoxybutane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Ethane-1,2-diol;1-methoxybutane
• 化学式: C7H18O3
• 分子量: 150.22
• InChiKey: QTFVHXWFRSTBOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• [EN] MATERIALS FOR ELECTRONIC DEVICES<br/>[FR] MATÉRIAUX POUR DISPOSITIFS ÉLECTRONIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2019002190A1

  公开（公告）日：2019-01-03

  The present application relates to a spirobifluorene derivative of a specific formula (I) which is suitable for use in electronic devices.

  本申请涉及一种特定化学式（I）的螺环双芴衍生物，适用于电子设备。
• Process for production of monoalkyl ethers
  申请人：KAO CORPORATION

  公开号：US20010056212A1

  公开（公告）日：2001-12-27

  A process for producing a monoalkyl ether which comprises a first step of contacting the following components (A) and (B):(A): an aqueous liquid phase containing: (a 1 ) a C 3-6 polyol having 3 or 4 hydroxyl groups, a palladium compound, a water-soluble tertiary phosphine or phosphite, and water; or (a 2 ) a C 3-6 polyol having 3 to 4 hydroxyl groups, a complex of palladium and a water-soluble tertiary phosphine or phosphite, and water, and (B): an oily liquid phase containing a conjugated diene, to give an alkadienyl ether containing an alkadienyl group resulting from dimerization of conjugated dienes; and a second step of hydrogenating the alkadienyl group in the alkadienyl ether in a hydrogen atmosphere in the presence of a catalyst containing an element selected from the Groups 8 to 10 elements of the periodic table. According to the process of the invention, monoalkyl ethers of polyols are produced selectively in a simple manner and advantageously from the economical viewpoint. The present process enables recovery and recycling of the catalyst.

  一种制备单烷基醚的方法，包括以下步骤：第一步，将以下组分（A）和（B）接触：（A）含有以下成分的水相液体：（a1）具有3或4个羟基的C3-6多元醇，钯化合物，水溶性三级膦或亚磷酸酯和水；或（a2）具有3到4个羟基的C3-6多元醇，钯和水溶性三级膦或亚磷酸酯的复合物和水；（B）含有共轭二烯的油状液相，以产生含有由二聚共轭二烯产生的烯基二烯醚的烯基二烯基醚；第二步，在氢气氛中，在周期表8至10族元素中选择的元素的催化剂存在下，对烯基二烯基醚中的烯基二烯基进行氢化。根据本发明的方法，可以简单地选择性地制备多元醇的单烷基醚，并从经济角度获得优势。本方法可以使催化剂得到回收和再利用。
• Liquid aqueous bleaching compositions
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0908512A2

  公开（公告）日：1999-04-14

  The present invention relates to a liquid aqueous composition having a viscosity of 1 cps to 100 cps when measured with a Brookfield viscometer at spindle 2, rpm 30 and 20°C, and comprising a peroxygen bleach, from 0.001% to 30% by weight of the total composition of an ethoxylated nonionic surfactant, from 0.001% to 20% by weight of a zwitterionic betaine surfactant and a viscosity controlling agent selected from the group consisting of: C3-C6 alkyl ammonium salt, glycol according to the formula:         R1-O- (Cx-H2x)n -R2, wherein R1 is a saturated or unsaturated, substituted or unsubstituted, linear or branched alkyl group containing from 1 to 5 carbon atoms, R2 is hydrogen or a saturated or unsaturated, substituted or unsubstituted, linear or branched alkyl group containing from 1 to 5 carbon atoms, x ranges from 2 to 4 and n ranges from 1 to 5; an alcohol having the formula Ra-OH wherein Ra is a linear or branched, saturated or unsaturated alkyl group containing from 3 to 8 carbon atoms, an aromatic alcohol according to the formula Rb-OH wherein Rb is an alkyl substituted or non-alkyl substituted aryl group containing from 5 to 15 carbon atoms, and mixtures thereof. These compositions are suitable to deliver improved stain removal performance and improved bleaching performance when used to pretreat fabrics while delivering low viscosity.

  本发明涉及一种液体水性组合物，用布鲁克菲尔德粘度计在主轴 2、转/分 30 和 20°C 下测量，其粘度为 1 cps 至 100 cps，该组合物包括过氧漂白剂、占总组合物重量 0.001%至 30%的乙氧基化非离子表面活性剂、占总组合物重量 0.001%至 20%的齐聚酰亚胺甜菜碱表面活性剂和选自以下组别的粘度控制剂： C3-C6 烷基铵盐、 按以下公式计算的乙二醇 R1-O- (Cx-H2x)n -R2、 其中 R1 为饱和或不饱和、取代或未取代、含有 1 至 5 个碳原子的直链或支链烷基，R2 为氢或饱和或不饱和、取代或未取代、含有 1 至 5 个碳原子的直链或支链烷基，x 为 2 至 4，n 为 1 至 5； 一种具有式 Ra-OH 的醇，其中 Ra 是含有 3 至 8 个碳原子的直链或支链、饱和或 不饱和烷基、 式中 Rb 是含有 5 至 15 个碳原子的烷基取代或非烷基取代芳基的芳香醇，以及它们的混合物。这些组合物用于预处理织物时，可提高去污性能和漂白性能，同时粘度较低。
• METHOD FOR PURIFYING TETRAKIS(FLUOROARYL) BORATE/MAGNESIUM HALIDE, TETRAKIS(FLUOROARYL) BORATE/ETHER COMPLEX AND PROCESS FOR PREPARING THE SAME, AND PROCESS FOR PREPARING TETRAKIS(FLUOROARYL) BORATE DERIVATIVE
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP0913400A1

  公开（公告）日：1999-05-06

  A method for purifying Ar4 BMgX which comprises treating a tetrakis(fluoroaryl) borate/magnesium halide (Ar4BMgX) with (1) an alkaline (earth) metal salt of carboxylic acid, (2) an acid, (3) an acid and then an alkaline (earth) metal hydroxide, or (4) an acid and then an alkaline (earth) metal salt of carboxylic acid; and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) which comprises reacting the treated Ar4BMgX with a compound capable of generating monovalent cationic species. The above purification method permits separation and removal of impurities contained in Ar4 BMgX in an efficient and simple manner. The invention also provides a tetrakis(fluoroaryl) borate/ether complex, a process for preparing the same, and a process for preparing a tetrakis(fluoroaryl) borate derivative (Ar4BZ) by using the ether complex and the compound capable of generating monovalent cationic species as starting compounds. The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl) borate derivatives.

  一种提纯 Ar4 BMgX 的方法，包括用(1)羧酸的碱(土)金属盐、(2)酸、(3)酸然后碱(土)金属氢氧化物或(4)酸然后羧酸的碱(土)金属盐处理四(氟芳基)硼酸盐/卤化镁(Ar4BMgX)；以及制备四（氟芳基）硼酸酯衍生物（Ar4BZ）的工艺，包括将处理过的 Ar4BMgX 与能够生成一价阳离子物种的化合物反应。上述纯化方法可以高效、简单地分离和去除 Ar4 BMgX 中所含的杂质。本发明还提供了一种四(氟芳基)硼酸酯/醚络合物、制备四(氟芳基)硼酸酯/醚络合物的工艺，以及以醚络合物和能够生成一价阳离子种类的化合物为起始化合物制备四(氟芳基)硼酸酯衍生物(Ar4BZ)的工艺。醚络合物很容易提纯到高纯度，因此适合用作制备各种四（氟芳基）硼酸酯衍生物的中间体。
• Tetrakis(fluoroaryl) borate/ether complexes and process for preparing the same
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1400524A1

  公开（公告）日：2004-03-24

  The invention provides a tetrakis(fluoroaryl) borate/ether complex, and the process for preparing the same, The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl)borate derivatives.

  本发明提供了一种四(氟芳基)硼酸酯/醚络合物及其制备方法，该醚络合物很容易提纯到高纯度，因此适合作为制备各种四(氟芳基)硼酸酯衍生物的中间体。