1,3-二氨基芘 | 92821-64-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 中文名称: 1,3-二氨基芘
• 英文名称: 1,3-diaminopyrene
• 英文别名: pyrene-1,3-diamine
• CAS: 92821-64-2
• 化学式: C₁₆H₁₂N₂
• 分子量: 232.285
• InChiKey: WOFKFNZIJZWWPZ-UHFFFAOYSA-N

物化性质

• 熔点：
  184 °C
• 沸点：
  511.0±30.0 °C(Predicted)
• 密度：
  1.394±0.06 g/cm3(Predicted)
• 溶解度：
  氘代氯仿

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  1,3-二氨基芘 、 双氧水 以2%的产率得到
  参考文献：
  名称：

  HASHIMOTO, YUICHI;SHUDA, KOICHI, CHEM. AND PHARM. BULL., 1984, 32, N 5, 1992-1994

  摘要：

  DOI：
• 作为产物：
  描述：

  芘 在 sodium hydrogensulfide 、 硝酸 作用下， 生成 1-氨基芘 、 1,8-二氨基芘 、 1,6-二氨基芘 、 1,3-二氨基芘
  参考文献：
  名称：

  Hashimoto, Yuichi; Shudo, Koichi, Chemical and pharmaceutical bulletin, 1984, vol. 32, # 5, p. 1992 - 1994

  摘要：

  DOI：

文献信息

• Liquid-Crystal Aligning Agent, Liquid-Crystal Alignment Film Comprising the Same, and Liquid-Crystal Element
  申请人：Tsutsui Kimiaki

  公开号：US20070224370A1

  公开（公告）日：2007-09-27

  It is to provide a liquid crystal aligning agent capable of forming a liquid crystal alignment film having favorable electrical characteristics, and excellent in the storage stability and the productivity. A liquid crystal aligning agent comprising at least one member selected from a polyamic acid obtained by polymerization of a diamine component with a tetracarboxylic dianhydride component, and a polyimide obtained by cyclodehydration of the polyamic acid, characterized in that the diamine component contains at least one of diamines represented by the following formula [1]: H 2 N-A-R—NH 2 [1] wherein A is a bivalent organic group comprising a benzene ring or an aromatic condensed ring, provided that one or more optional hydrogen atoms in the benzene ring or the aromatic condensed ring may be substituted by a monovalent organic group other than an amino group, and R is a C 1-10 bivalent saturated hydrocarbon group.

  本发明旨在提供一种液晶取向剂，能够形成具有良好电学特性、储存稳定性和生产率优异的液晶取向膜。液晶取向剂包括至少一种由二胺组分与四羧酸二酐组分聚合得到的聚酰胺酸和由聚酰胺酸环状脱水得到的聚酰亚胺，其特征在于二胺组分中包含下式[1]所表示的二胺之一：H2N-A-R—NH2[1]其中，A是一个双价的有机基团，包括苯环或芳香环，并且苯环或芳香环中的一个或多个可选氢原子可以被除氨基以外的一价有机基团取代，R是一个C1-10双价饱和碳氢基团。
• CROSSLINKED COMPOSITION
  申请人：Daicel Corporation

  公开号：EP2559720A1

  公开（公告）日：2013-02-20

  To provide a composition (e.g., a coating composition) useful for forming an organic semiconductor having excellent conductivity, solvent resistance, heat resistance, durability, and other properties, and an organic semiconductor formed with the composition. The composition comprises an aromatic polycarbonyl compound having a carbonyl group as a reactive site, and at least one aromatic reactive component selected from an aromatic polyamine having an amino group as a reactive site, and an aromatic heterocyclic compound having a plurality of unmodified α-carbon positions, as reactive sites, each of which is adjacent to a hetero atom of a heterocycl thereof. When the aromatic reactive component is an aromatic heterocyclic compound, the aromatic polycarbonyl compound is an aromatic polyaldehyde compound. Use of the composition in which at least one component of the aromatic polycarbonyl compound and the aromatic reactive component has not less than 3 reactive sites per molecule forms an organic semiconductor having a three-dimensional crosslinked structure.

  提供一种可用于形成具有优异导电性、耐溶剂性、耐热性、耐久性和其他性能的有机半导体的组合物（例如涂层组合物），以及用该组合物形成的有机半导体。 该组合物包括具有羰基作为反应位点的芳香族聚碳化合物，以及至少一种芳香族反应性成分，该芳香族反应性成分选自具有氨基作为反应位点的芳香族多胺和具有多个未修饰的α-碳位作为反应位点的芳香族杂环化合物，其中每个反应位点都与杂环的杂原子相邻。当芳香活性组分为芳香杂环化合物时，芳香多羰基化合物为芳香多醛化合物。使用芳香族多羰基化合物和芳香族活性组分中至少一种组分每分子具有不少于 3 个活性位点的组合物，可形成具有三维交联结构的有机半导体。
• ALL-SOLID SECONDARY BATTERY, SOLID ELECTROLYTE COMPOSITION AND ELECTRODE SHEET FOR BATTERY USED THEREIN, AND METHODS OF MANUFACTURING ELECTRODE SHEET FOR BATTERY AND ALL-SOLID SECONDARY BATTERY
  申请人：Fujifilm Corporation

  公开号：EP3258530A1

  公开（公告）日：2017-12-20

  Provided are an all solid state secondary battery having a positive electrode active material layer, an inorganic solid electrolyte layer, and a negative electrode active material layer in this order, in which at least one layer of the positive electrode active material layer, the inorganic solid electrolyte layer, or the negative electrode active material layer includes an electrolytic polymerizable compound and an inorganic solid electrolyte, in which the electrolytic polymerizable compound is an electrolytic polymerizable compound having a molecular weight of less than 1,000 which is represented by any one of Formulae (1) to (5) below, and the inorganic solid electrolyte contains a metal belonging to Group I or II of the periodic table and has an ion conductivity of the metal being contained, an electrode sheet for a battery, and method for manufacturing an electrode sheet for a battery and an all solid state secondary battery. Reference signs each independently represent a specific atom, substituent, or linking group.

  本发明提供了一种全固态二次电池，该电池依次具有正极活性材料层、无机固体电解质层和负极活性材料层，其中正极活性材料层、无机固体电解质层或负极活性材料层中至少有一层包括电解可聚合化合物和无机固体电解质、其中，电解可聚合化合物是分子量小于 1,000 的电解可聚合化合物，由下式（1）至（5）中的任一个表示，无机固体电解质含有属于元素周期表第 I 组或第 II 组的金属，并具有所含金属的离子电导率，电池电极片，以及电池电极片和全固态二次电池的制造方法。 参考符号各自独立地代表一个特定的原子、取代基或连接基团。
• 8-ARM POLYETHYLENE GLYCOL DERIVATIVE, MANUFACTURING METHOD AND MODIFIED BIO-RELATED SUBSTANCE THEREBY
  申请人：Xiamen Sinopeg Biotech Co., Ltd.

  公开号：EP3315531A1

  公开（公告）日：2018-05-02

  Disclosed are an 8-arm polyethylene glycol (PEG) derivative (formula 1), manufacturing method and modified bio-related substance thereby, wherein a tetravalent group U and four trivalent groups Ec form a highly symmetric octavalent central structure CORE0 together, Lc connects the octavalent center to eight PEG arms having polydiversity or monodiversity and having n1-n8 as the degrees of polymerization thereof. The terminal of one PEG chain is connected to at least one functional group F (k ≥ 1), and said PEG chain and F can be directly connected (g = 0) or connected with a divalent linking group L0 connected with a terminal branched group G (g = 1) therebetween. The latter provides more reacting sites to combine more pharmaceutical molecules, thereby increasing the drug loading capacity. The near-center symmetric structure of the derivative allows more precise control over the molecular weight during large-scale production, thereby facilitating acquisition of a product having a narrower molecular weight distribution. A bio-related substance modified thereby has a more uniform and controllable performance.

  本发明公开了一种 8 臂聚乙二醇（PEG）衍生物（式 1）、其制造方法和改性生物相关物质，其中一个四价基团 U 和四个三价基团 Ec 共同形成一个高度对称的八价中心结构 CORE0，Lc 将八价中心连接到八个 PEG 臂上，这些 PEG 臂具有多元性或单元性，其聚合度为 n1-n8。一条 PEG 链的末端与至少一个官能团 F（k ≥ 1）相连，所述 PEG 链和 F 可以直接相连（g = 0），也可以通过二价连接基 L0 与中间的末端支化基 G（g = 1）相连。后者提供了更多的反应位点，可以结合更多的药物分子，从而提高药物负载能力。衍生物的近中心对称结构可以在大规模生产过程中更精确地控制分子量，从而有利于获得分子量分布更窄的产品。由此改性的生物相关物质具有更均匀、更可控的性能。
• RUBBER COMPOSITION AND MOLDED ARTICLE
  申请人：Zeon Corporation

  公开号：EP3473671A1

  公开（公告）日：2019-04-24

  Provided are a shaped product having excellent heat resistance and a rubber composition with which the shaped product can be formed. The rubber composition contains a rubber including an ethylenically unsaturated monomer unit having at least one carboxyl group, a compound having at least one amino group and an aromatic condensed ring structure including at least three rings, and one or more carbon nanotubes. The shaped product is obtained through shaping of the rubber composition.

  本发明提供了一种具有优异耐热性能的异型产品和一种橡胶组合物，该橡胶组合物可用于成型该异型产品。该橡胶组合物含有一种橡胶，其中包括具有至少一个羧基的乙烯不饱和单体单元、具有至少一个氨基和至少包括三个环的芳香缩合环结构的化合物，以及一个或多个碳纳米管。成型产品通过橡胶组合物的成型获得。