1,6,7,12-四氯-3,4,9,10-四甲酸酰胺 | 115662-06-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 1,6,7,12-四氯-3,4,9,10-四甲酸酰胺
• 英文名称: N,N-dihydro-1,6,7,12-tetrachloro-3,4,9,10-tetracarboxyl perylene bisimide
• 英文别名: TCPDI；1,6,7,12-tetrachloroperylen-3,4:9,10-tetracarboxylic acid diimide；5,6,12,13-tetrachloroanthra(2,1,9-def:6,5,10-d'e'f')diisoquinoline-1,3,8,10(2H,9H)-tetrone；11,14,22,26-tetrachloro-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone
• CAS: 115662-06-1
• 化学式: C₂₄H₆Cl₄N₂O₄
• 分子量: 528.135
• InChiKey: SOGFVOVSOPPQPF-UHFFFAOYSA-N

物化性质

• 沸点：
  917.6±65.0 °C(Predicted)
• 密度：
  1.885±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  34
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  92.3
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 危险品标志：
  Xn
• 安全说明：
  S22,S36/37
• 危险类别码：
  R62

反应信息

• 作为反应物：
  描述：

  1,6,7,12-四氯-3,4,9,10-四甲酸酰胺 在 sodium dithionite 、 sodium hydroxide 作用下， 以 乙腈 为溶剂， 生成 2Na(1+)*TCPDI(2-)
  参考文献：
  名称：

  Self-assembly of twisted tetrachloroperylenediimide chromophores into two dimensional brick-stone aggregates: exciton dynamics and photoconductivity

  摘要：

  二维自组装已经在具有扭曲发色团的吡咯烷二酰亚胺中得到了证实，其中π-π堆积单元通过氢键相互作用相互连接。光谱测量和理论计算表明组装中存在微弱的J型激子耦合。二维晶体的高光导率使其成为进一步光电子应用的理想选择。

  DOI：

  10.1039/c2cc32112b
• 作为产物：
  描述：

  1,6,7,12-四氯-3,4,9,10-苝四甲酸二酐 在 ammonium acetate 、 丙酸 作用下， 反应 8.0h， 以90%的产率得到1,6,7,12-四氯-3,4,9,10-四甲酸酰胺
  参考文献：
  名称：

  Self-assembly of twisted tetrachloroperylenediimide chromophores into two dimensional brick-stone aggregates: exciton dynamics and photoconductivity

  摘要：

  二维自组装已经在具有扭曲发色团的吡咯烷二酰亚胺中得到了证实，其中π-π堆积单元通过氢键相互作用相互连接。光谱测量和理论计算表明组装中存在微弱的J型激子耦合。二维晶体的高光导率使其成为进一步光电子应用的理想选择。

  DOI：

  10.1039/c2cc32112b

文献信息

• An Anionic Imide Material Having Ferromagnetism At Room Temperature And The Use Thereof
  申请人：South China University Of Technology

  公开号：US20200247802A1

  公开（公告）日：2020-08-06

  The anionic imide material is obtained by preparing a solution or a suspension of an imide compound, then reducing and drying the same; the anionic material comprises anions of an imide compound, the anions being at least one selected from the following formula I or formula II; in formula I or II: n=1, 2, or 3; R 1 , R 2 are respectively selected from at least one of H, amino, carboxyl, hydroxy, thiol, and pyridyl groups; X 1 -X 4 are respectively an electron withdrawing group, and specifically selected from one of H, F, Cl, Br, CN, and NO 2 groups. The anionic material of the present invention has a Curie temperature larger than room temperature and ferromagnetism, and is an organic magnetic material; it may be used for preparing an organic magnetic material and/or an organic magnetic device.

  阴离子酰亚胺材料是通过制备酰亚胺化合物的溶液或悬浮液，然后还原和干燥而得到的；该阴离子材料包括酰亚胺化合物的阴离子，该阴离子至少选择以下公式I或公式II中的一种；在公式I或II中：n = 1、2或3；R1、R2分别选择至少一个H、氨基、羧基、羟基、硫醇和吡啶基；X1-X4分别是电子提取基团，并特别选择自H、F、Cl、Br、CN和NO2基团中的一种。本发明的阴离子材料具有大于室温的居里温度和铁磁性，并且是一种有机磁性材料；它可用于制备有机磁性材料和/或有机磁性器件。
• Anionic imide material having ferromagnetism at room temperature and the use thereof
  申请人：South China University Of Technology

  公开号：US11084816B2

  公开（公告）日：2021-08-10

  The anionic imide material is obtained by preparing a solution or a suspension of an imide compound, then reducing and drying the same; the anionic material comprises anions of an imide compound, the anions being at least one selected from the following formula I or formula II; in formula I or II: n=1, 2, or 3; R1, R2 are respectively selected from at least one of H, amino, carboxyl, hydroxy, thiol, and pyridyl groups; X1-X4 are respectively an electron withdrawing group, and specifically selected from one of H, F, Cl, Br, CN, and NO2 groups. The anionic material of the present invention has a Curie temperature larger than room temperature and ferromagnetism, and is an organic magnetic material; it may be used for preparing an organic magnetic material and/or an organic magnetic device.

  该阴离子酰亚胺材料是通过制备酰亚胺化合物的溶液或悬浮液，然后将其还原和干燥而得到的；该阴离子材料包括酰亚胺化合物的阴离子，该阴离子至少选自下式I或式II中的一种；在式I或式II中，n=1、2或3；R1、R2分别选自H、氨基、羧基、羟基、硫醇基和吡啶基中的至少一种；X1-X4分别是取电子基团，具体选自H、F、Cl、Br、CN和NO2基团中的一种。本发明的阴离子材料居里温度大于室温，具有铁磁性，是一种有机磁性材料，可用于制备有机磁性材料和/或有机磁性器件。
• FLUORIERTE RYLENTETRACARBONSÄUREDERIVATE UND DEREN VERWENDUNG
  申请人：BASF SE

  公开号：EP1987092B1

  公开（公告）日：2013-05-22
• METHOD FOR PRODUCING ORGANIC FIELD-EFFECT TRANSISTORS
  申请人：Konemann Martin

  公开号：US20070259475A1

  公开（公告）日：2007-11-08

  A method for producing an organic field-effect transistor, comprising the steps of: a) providing a substrate comprising a gate structure, a source electrode and a drain electrode located on the substrate, and b) applying an n-type organic semiconducting compound to the area of the substrate where the gate structure, the source electrode and the drain electrode are located, wherein the n-type organic semiconducting compound is selected from the group consisting of compounds of the formula I wherein R 1 , R 2 , R 3 and R 4 are independently hydrogen, chlorine or bromine, with the proviso that at least one of these radicals is not hydrogen, Y 1 is O or NR a , wherein R a is hydrogen or an organyl residue, Y 2 is O or NR b , wherein R b is hydrogen or an organyl residue, Z 1 , Z 2 , Z 3 and Z 4 are O, where, in the case that Y 1 is NR a , one of the residues Z 1 and Z 2 may be a NR c group, where R a and R c together are a bridging group having 2 to 5 atoms between the terminal bonds, where, in the case that Y 2 is NR b , one of the residues Z 3 and Z 4 may be a NR d group, where R b and R d together are a bridging group having 2 to 5 atoms between the terminal bonds.
• VERFAHREN ZUR HERSTELLUNG VON MIT RYLENTETRACARBONSAEUREDIIMIDEN BESCHICHTETEN SUBSTRATEN
  申请人：Konemann Martin

  公开号：US20090078312A1

  公开（公告）日：2009-03-26

  The present invention relates to a process for producing a substrate coated with rylenetetracarboximides, in which a substrate is treated with an N,N′-bisubstituted rylenetetracarboximide and the treated substrate is heated to a temperature at which the N,N′-bisubstituted rylenetetracarboximide is converted to the corresponding N,N′-unsubstituted compound. The present invention further relates to semiconductor units, organic solar cells, excitonic solar cells and organic light-emitting diodes which comprise a substrate produced by this process. The present invention further relates to a process for preparing N,N′-unsubstituted rylenetetracarboximides, in which the corresponding N,N′-bisubstituted rylenetetracarboximides are provided and heated to a temperature at which these compounds are converted to the corresponding N,N′-unsubstituted compounds.