1-(2-硝基苯氧基)-2-[2-(2-硝基苯氧基)苯基]苯 | 65811-04-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(2-硝基苯氧基)-2-[2-(2-硝基苯氧基)苯基]苯
• 英文名称: 2,2'-bis-(2-nitrophenoxy)-biphenyl
• 英文别名: 2,2'-di-(o-nitrophenoxy)-biphenyl；2,2'-Bis(2-nitrophenoxy)-1,1'-biphenyl；1-(2-nitrophenoxy)-2-[2-(2-nitrophenoxy)phenyl]benzene
• CAS: 65811-04-3
• 化学式: C₂₄H₁₆N₂O₆
• 分子量: 428.401
• InChiKey: RBQXUBJYPRPQAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  32
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1-(2-硝基苯氧基)-2-[2-(2-硝基苯氧基)苯基]苯 在 aluminum nickel 作用下， 以 1,4-二氧六环 为溶剂， 生成 2,2'-bis-(2-aminophenoxy)-biphenyl
  参考文献：
  名称：

  Aromatic diamines and their use as polycondensation components for the

  摘要：

  本文描述了新型多核芳香胺类化合物，例如2,2'-二-(对氨基苯氧基)-联苯，以及它们的制备方法和它们作为聚合物合成组分用于制造聚酰胺、聚酰胺酰亚胺和聚酰亚胺聚合物的用途。根据本发明使用芳香胺制备的聚合物易于溶解并且可以从熔融态加工，具有良好的热性能、电性能和/或机械性能。

  公开号：

  US04196144A1
• 作为产物：
  描述：

  2,2'-二羟基联苯 、 1-氟-2-硝基苯 在 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 72.0h， 以97.2%的产率得到1-(2-硝基苯氧基)-2-[2-(2-硝基苯氧基)苯基]苯
  参考文献：
  名称：

  Racemic and chiral expanded salen-type complexes derived from biphenol and binaphthol: Salbip and salbin

  摘要：

  The reaction of 2-fluoronitrobenzene with 2,2'-biphenol or (R)-binaphthol, followed by reduction and subsequent reaction of the resulting diamine with two equivalents of a salicylaldehyde, affords expanded salen-type ligands having backbones based on biphenol or binaphthol: salbipH(2), (R)-salbinH(2) and (R)-salbin(t-Bu)H-4(2). Deprotonation of these ligands with sodium methoxide or potassium hydride, followed by metallation with M(OAc)(2) (M = Mn, Co, Ni, or Cu), affords the corresponding metal complexes in good yield (61-85%). The species containing Mn, Co, and Ni all have distorted octahedral geometry, as determined by X-ray crystallography. The ethereal oxygen atoms occupy two coordination sites with metal-oxygen distances ranging from 2.19 to 2.36 angstrom. The imine nitrogen atoms are trans to each other in the solid state, an impossible geometry in traditional salen-type complexes. The species containing Cu are distorted square planar and show much longer metal-ethereal oxygen distances ranging from 2.79 to 3.22 angstrom. The manganese complexes are competent catalysts for the epoxidation of olefins. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.03.034

文献信息

• Aromatic diamines and their use as polycondensation components for the
  申请人：Ciba-Geigy Corporation

  公开号：US04196144A1

  公开（公告）日：1980-04-01

  New polynuclear aromatic diamines, such as 2,2'-di-(p-aminophenoxy)-biphenyl, a process for their manufacture and their use as polycondensation components for the manufacture of polyamide, polyamide-imide and polyimide polymers are described. The polymers obtained with the aromatic diamines according to the invention are readily soluble and can also be processed from the melt and are distinguished by good thermal, electrical and/or mechanical properties.

  本文描述了新型多核芳香胺类化合物，例如2,2'-二-(对氨基苯氧基)-联苯，以及它们的制备方法和它们作为聚合物合成组分用于制造聚酰胺、聚酰胺酰亚胺和聚酰亚胺聚合物的用途。根据本发明使用芳香胺制备的聚合物易于溶解并且可以从熔融态加工，具有良好的热性能、电性能和/或机械性能。
• US4196144A
  申请人：——

  公开号：US4196144A

  公开（公告）日：1980-04-01
• US4239880A
  申请人：——

  公开号：US4239880A

  公开（公告）日：1980-12-16
• Racemic and chiral expanded salen-type complexes derived from biphenol and binaphthol: Salbip and salbin
  作者：Joseph M. Grill、Joseph H. Reibenspies、Stephen A. Miller

  DOI：10.1016/j.jorganchem.2005.03.034

  日期：2005.6

  The reaction of 2-fluoronitrobenzene with 2,2'-biphenol or (R)-binaphthol, followed by reduction and subsequent reaction of the resulting diamine with two equivalents of a salicylaldehyde, affords expanded salen-type ligands having backbones based on biphenol or binaphthol: salbipH(2), (R)-salbinH(2) and (R)-salbin(t-Bu)H-4(2). Deprotonation of these ligands with sodium methoxide or potassium hydride, followed by metallation with M(OAc)(2) (M = Mn, Co, Ni, or Cu), affords the corresponding metal complexes in good yield (61-85%). The species containing Mn, Co, and Ni all have distorted octahedral geometry, as determined by X-ray crystallography. The ethereal oxygen atoms occupy two coordination sites with metal-oxygen distances ranging from 2.19 to 2.36 angstrom. The imine nitrogen atoms are trans to each other in the solid state, an impossible geometry in traditional salen-type complexes. The species containing Cu are distorted square planar and show much longer metal-ethereal oxygen distances ranging from 2.79 to 3.22 angstrom. The manganese complexes are competent catalysts for the epoxidation of olefins. (c) 2005 Elsevier B.V. All rights reserved.