1-乙基-3-甲基二(五氟乙基磺酰)亚胺 | 216299-76-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-乙基-3-甲基二(五氟乙基磺酰)亚胺
• 中文别名: 1-乙基-3-甲基咪唑啉双(五氟乙基磺酰基)亚胺
• 英文名称: 1-ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide
• 英文别名: bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium
• CAS: 216299-76-2
• 化学式: C₄F₁₀NO₄S₂*C₆H₁₁N₂
• 分子量: 491.331
• InChiKey: SUDHVXIPIDQEIT-UHFFFAOYSA-N

物化性质

• 熔点：
  ≤−1 °C(lit.)
• 密度：
  1,57 g/cm3
• 稳定性/保质期：

  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  2.66
• 重原子数：
  29
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  94.8
• 氢给体数：
  0
• 氢受体数：
  15

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : 1-Ethyl-3-methylimidazolium
bis(pentafluoroethylsulfonyl)imide
CAS-No. : 216299-76-2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Label elements
Caution - substance not yet tested completely.
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Synonyms : EMIMBeTi
Formula : C10H11F10N3O4S2
Molecular Weight : 491,33 g/mol

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Section 4. FIRST AID MEASURES
Description of first aid measures
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Hydrogen fluoride
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Avoid breathing vapors, mist or gas.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Normal measures for preventive fire protection.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Store under inert gas.
Specific end uses
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK
(EU EN 14387) respirator cartridges. Use respirators and components tested and approved under
appropriate government standards such as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: liquid, clear, viscous
Colour: colourless
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing Melting point/range: 1 °C
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Additional Information
RTECS: Not available

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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Section 15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available

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Section 16. OTHER INFORMATION
Further information
Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 N-ethyl bis(pentafluoroethanesulfonyl)imide 反应 1.0h， 以99%的产率得到1-乙基-3-甲基二(五氟乙基磺酰)亚胺
  参考文献：
  名称：

  FLUORINE-CONTAINING N-ALKYLSULFONYLIMIDE COMPOUND, MANUFACTURING METHOD THEREFOR, AND METHOD OF MANUFACTURING AN IONIC COMPOUND

  摘要：

  根据制备含氟N-烷基磺酰亚胺化合物的方法，可以通过用二烷基硫酸或二烷基碳酸烷基化含氟磺酰亚胺酸或含氟磺酰亚胺酸盐来安全地高回收率地生产含氟N-烷基磺酰亚胺化合物。

  公开号：

  US20120022269A1

文献信息

• Dissolution of oligo(tetrafluoroethylene) and preparation of poly(tetrafluoroethylene)-based composites by using fluorinated ionic liquids
  作者：Akiko Tsurumaki、Hiroyuki Ohno

  DOI：10.1039/c7cc08449h

  日期：——

  Fluorophilic ionic liquids (ILs) showing enhanced compatibility with poly(tetrafluoroethylene) (PTFE) have been newly synthesised. The as-designed ILs contributed both to the dissolution of PTFE oligomers and to the preparation of composites with PTFE with no fear of bleed-out of the ILs.

  新合成了显示出与聚四氟乙烯（PTFE）相容性增强的氟离子液体（IL）。设计的IL有助于PTFE低聚物的溶解，也有助于制备PTFE复合材料而无需担心IL的渗出。
• Exploring the effect of fluorinated anions on the CO₂/N₂ separation of supported ionic liquid membranes
  作者：Andreia S. L. Gouveia、Liliana C. Tomé、Elena I. Lozinskaya、Alexander S. Shaplov、Yakov S. Vygodskii、Isabel M. Marrucho

  DOI：10.1039/c7cp06297d

  日期：——

  based on the 1-ethyl-3-methylimidazolium cation ([C2mim]+) and different fluorinated anions, namely 2,2,2-trifluoromethylsulfonyl-N-cyanoamide ([TFSAM]−), bis(fluorosulfonyl) imide ([FSI]−), nonafluorobutanesulfonate ([C4F9SO3]−), tris(pentafluoroethyl)trifluorophosphate ([FAP]−), and bis(pentafluoroethylsulfonyl)imide ([BETI]−) anions, were measured using supported ionic liquid membranes (SILMs). The results

  基于1-乙基-3-甲基咪唑鎓阳离子（[C 2 mim] +）和不同氟化阴离子（即2,2,2-三氟甲基磺酰基-N-氰基酰胺）的离子液体（IL）的CO 2和N 2渗透性能（[TFSAM] -），双（氟磺酰基）酰亚胺（[FSI] -），九氟丁烷磺酸盐（[C 4 F 9 SO 3 ] -），三（五氟乙基）三氟磷酸盐（[FAP] -）和双（五氟乙基磺酰基）酰亚胺（[BETI] -使用支持的离子液体膜（SILM）测量阴离子。结果表明，含有[TFSAM] -和[FSI] -阴离子的纯ILs表现出最高的CO 2渗透率，753和843 Barrer，以及最大的CO 2 / N 2渗透率，分别为43.9和46.1，其中CO 2 / N 2分离性能高于或高于Robeson 2008上限。通过使用IL混合物研究了通过结构展开对[TFSAM] -阴离子的重新设计。该气体输送和CO 2 / N 2个分离性能通过纯[C
• JP2000016983A
  申请人：——

  公开号：JP2000016983A

  公开（公告）日：2000-01-18