1-乙氧基-1,3-丁二烯 | 5614-32-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-乙氧基-1,3-丁二烯
• 英文名称: 1-ethoxybuta-1,3-diene
• 英文别名: 1-Aethoxy-butadien-(1.3)；1-ethoxy-1,3-butadiene；1-Aethoxy-1,3-butadien；1-Ethoxy-1,3-butadien；1-Ethoxy-buta-1,3-diene
• CAS: 5614-32-4
• 化学式: C₆H₁₀O
• 分子量: 98.1448
• InChiKey: LDVKFLIDEBQMNX-UHFFFAOYSA-N

物化性质

• 沸点：
  111.5-112 °C
• 密度：
  0.8239 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-乙氧基-1,3-丁二烯 生成 乙基丁基醚
  参考文献：
  名称：

  The Effect on Attribute Prediction of Location Uncertainty in Spatial Data

  摘要：

  A datum is considered spatial if it contains location information. Typically, there is also attribute information, whose distribution depends on its location. Thus, error in location information can lead to error in attribute information, which is reflected ultimately in the inference drawn from the data. We propose a statistical model for incorporating location error into spatial data analysis. We investigate the effect of location error on the spatial lag, the covariance function, and optimal spatial linear prediction (that is, kriging). We show that the form of kriging after adjusting for location error is the same as that of kriging without adjusting for location error. However, location error changes entries in the matrix of explanatory variables, the matrix of co‐variances between the sample sites, and the vector of covariances between the sample sites and the prediction location. We investigate, through simulation, the effect that varying trend, measurement error, location error, range of spatial dependence, sample size, and prediction location have on kriging after and without adjusting for location error. When the location error is large, kriging after adjusting for location error performs markedly better than kriging without adjusting for location error, in terms of both the prediction bias and the mean squared prediction error.

  DOI：

  10.1111/j.1538-4632.2002.tb01088.x
• 作为产物：
  描述：

  3-氯丁醛二乙基缩醛 在 氢氧化钾 作用下， 生成 1-乙氧基-1,3-丁二烯
  参考文献：
  名称：

  Wichterle, Collection of Czechoslovak Chemical Communications, 1938, vol. 10, p. 497,502

  摘要：

  DOI：

文献信息

• Some new dienophiles in the diels-alder reaction with active cyclic dienes
  作者：M.G. Veliev、M.M. Guseinov、L.A. Yanovskaya、K.Ya. Burstein

  DOI：10.1016/s0040-4020(01)96453-1

  日期：1985.1

  A comparative study of the Diels-Alder reaction have been carried out for three types of cyclic dienes: cyclopentadiene (CPD), hexachlorocyclopentadiene (HCP), and tetrachloro-1,2-benzoquinone (TCBQ) with dienophiles of five types: monosubstituted acetylenes (propargyl alcohol and its esters), conjugated amines (allyl acetylene, allyl ethynyldimethylcarbonol and its esters), conjugated dienes (2-methylhexadiene-3

  已对三种类型的环状二烯进行Diels-Alder反应的比较研究：环戊二烯（CPD），六氯环戊二烯（HCP）和四氯-1,2-苯醌（TCBQ）与五种亲二烯体：单取代乙炔（炔丙醇及其酯），共轭胺（烯丙基乙炔，烯丙基乙炔基二甲基碳醇及其酯），共轭二烯（2-甲基己二烯-3,5-ol-2及其酯，1-乙氧基和1-乙氧基羰基丁二烯-1,3 ）和共轭三烯（hexatriene-1,3,5 and 5-methylhexatriene-1,3,5）。
• Synthesis of cyclopropanes by the reaction of olefins with dialkylzinc and methylene iodide
  作者：J. Furukawa、N. Kawabata、J. Nishimura

  DOI：10.1016/0040-4020(68)89007-6

  日期：1968.1

  A novel synthetic route to cyclopropanes by the reaction of olefins with dialkylzinc and methylene iodide is described. The essential feature of the reaction is similar to that of the Simmons-Smith reaction which involves the treatment of olefins with methylene iodide and zinc-copper couple. However, the novel route gives cyclopropanes more easily and is particularly suitable for the conversion of

  描述了一种通过烯烃与二烷基锌和亚甲基碘反应生成环丙烷的新颖合成途径。该反应的基本特征类似于Simmons-Smith反应的特征，该反应包括用亚甲基碘和锌-铜对处理烯烃。但是，该新方法更容易得到环丙烷，并且特别适合于将阳离子聚合性烯烃例如乙烯基醚转化为相应的环丙烷。当使用Simmons-Smith反应时，这类烯烃有时会因聚合反应而产生较低的环丙烷收率。
• Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane
  作者：Yu. V. Tomilov、A. B. Kostitsyn、E. V. Shulishov、O. M. Nefedov

  DOI：10.1055/s-1990-26844

  日期：——

  (Alkoxymethyl)-, (aminomethyl)-, (2-alkoxyethenyl)-, (2-acetoxyethenyl)-, and (2-siloxyethenyl)cyclopropanes are obtained in high yields by reaction of allyl alcohol or derivatives, allylamines, 1-alkoxy-, 1-acetoxy-, and 1-trimethylsiloxy-1,3-butadienes with diazomethane in dichloromethane/diethyl ether in the presence of bis(benzonitrile)palladium dichloride.

  通过在二氯甲烷/二乙醚中在二氯化双(苯腈)钯的存在下，使烯丙醇或其衍生物、烯丙胺、1-烷氧基、1-醋酸基和1-三甲基硅氧基-1,3-丁二烯与二氮甲烷反应，可以高产率地获得(烷氧基甲基)-、(氨基甲基)-、(2-烷氧基乙烯基)-、(2-醋酸氧基乙烯基)-和(2-硅氧基乙烯基)环丙烷。
• Khusid, A. Kh.; Sorokina, N. Yu., Journal of Organic Chemistry USSR (English Translation), 1983, vol. 19, p. 235 - 237
  作者：Khusid, A. Kh.、Sorokina, N. Yu.

  DOI：——

  日期：——
• Shermolovich, Yu. G.; Pazenok, S. V.; Slyusarenko, E. I., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 10.2, p. 1909 - 1913
  作者：Shermolovich, Yu. G.、Pazenok, S. V.、Slyusarenko, E. I.、Markovskii, L. N.

  DOI：——

  日期：——