1-氨基-5-苯甲酰胺基蒽醌 | 117-06-6

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 1-氨基-5-苯甲酰胺基蒽醌
• 中文别名: 1-氨基-5-苯甲酰基氨基蒽醌
• 英文名称: 1-amino-5-benzamidoanthraquinone
• 英文别名: 1-benzoylamino-5-amino-anthraquinone；1-Amino-5-benzoylamino-9,10-anthraquinone；1-amino-5-benzoylaminoanthraquinone；5-benzamido-1-aminoanthraquinone；N-(5-amino-9,10-dioxo-9,10-dihydro-[1]anthryl)-benzamide；N-(5-Amino-9,10-dioxo-9,10-dihydro-[1]anthryl)-benzamid；N-(5-amino-9,10-dioxoanthracen-1-yl)benzamide
• CAS: 117-06-6
• 化学式: C₂₁H₁₄N₂O₃
• mdl: MFCD00019168
• 分子量: 342.354
• InChiKey: FWEQPMZEKHHFTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  89.3
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2924299090

反应信息

• 作为反应物：
  描述：

  1-氨基-5-苯甲酰胺基蒽醌 在 ammonium vanadate 、 硫酸 、 硝基苯 作用下， 生成 8-amino-7H-benzo[e]perimidin-7-one
  参考文献：
  名称：

  Wittenberger, Melliand Textilberichte, 1949, vol. 30, p. 159

  摘要：

  DOI：
• 作为产物：
  描述：

  1-benzoylamino-5-(toluene-4-sulfonylamino)-anthraquinone 在 硫酸 作用下， 生成 1-氨基-5-苯甲酰胺基蒽醌
  参考文献：
  名称：

  Acylamino-anthraquinones and process of producing the same

  摘要：

  公开号：

  US01939218A1

文献信息

• Zur Kenntnis der Dinitro-anthrachinone
  作者：Eugen Hefti

  DOI：10.1002/hlca.19310140620

  日期：1931.12.1

  Bei der Dinitrierung des Anthrachinons nach den bekannten gebräuchlichen Methoden wurden rein erhalten: ca. 40% 1,5-Dinitro-anthrachinon vom Smp. 384,5–385° 37% 1,8-Dinitro-anthrachinon vom Smp. 311–312°, ferner 12–15% 1,6-Dinitro-anthrachinon vom Smp. 255–257°. Das 1,7-Dinitro-anthrachinon konnte nur unrein gewonnen werden, während die 2,6- und 2,7-Dinitro-anthrachinone überhaupt nicht isoliert wurden

  炭疽病防治法 40％1,5-二硝基anthrachinon vom Smp。384,5–385°37％1,8-二硝基-蒽醌vmp Smp。311–312°，蕨类植物12–15％1,6-二硝基-anthrachinon vom Smp。255–257°。1，7-二硝基-邻氨基苯并呋喃，与2,6-和2,7-二硝基-邻氨基苯甲酸异丁酯。
• Acetoacetylamino compounds and a process of making same
  申请人：DURAND &

  公开号：US02776983A1

  公开（公告）日：1957-01-08

  The invention comprises the N-acetoacetyl derivative of 1-chloro-2-aminoanthraquinone, and the preparation thereof and of other acetoacetylaminoanthraquinones by heating aminoanthraquinones with diketene in the presence of 90-100 per cent (preferably glacial) acetic acid at 40-80 DEG C. (preferably 60-70 DEG C.). Examples describe the acetoacetylation of 1- and 2-aminoanthraquinone, 1- and 3-chloro-2-aminoanthraquinone and 1-amino - 5 - benzoylaminoanthraquinone, and the di-acetoacetylation of 1 : 5-diaminoanthraquinone. Additional starting materials specified are 1-amino-4-benzoylaminoanthraquinone, 1 - amino - 4 - phenylaminoanthraquinone and 1 : 4 - diaminoanthraquinone. Specification 429,982 is referred to.ALSO:The invention comprises N - acetoacetyl derivatives of 4-benzoylaminodiphenylamine, carbazole, 1-aminobenzene-4-sulphonic acid 21-thiazolylamide, and naphthosultam, and the preparation thereof and of other acetoacetyl-amino compounds by heating a primary or secondary aromatic amine, or a heterocyclic compound containing a secondary nitrogen atom in the heterocyclic nucleus, with diketene in the presence of 90-100 per cent (preferably glacial) acetic acid at 40-80 DEG C. (preferably 60-70 DEG C.). Examples describe the acetoacetylation of the four compounds specified above and of 1-aminobenzene-4-sulphonic acid morpholide and diphenylamine. Additional starting materials specified include benzidine naphthoquinone, 1-aminobenzene-4-sulphonic acid p-phenylanilide and dimethylamide, 4-aminodiphenylsulphone, and N-phenyl-1-and-2-naphthylamine. Specification 429,982 is referred to.

  本发明涉及1-氯-2-氨基蒽醌的N-乙酰乙酰衍生物，以及通过在90-100％（优选为冰醋酸）乙酸存在下，在40-80℃（优选为60-70℃）下加热氨基蒽醌和二酮烯制备其他乙酰乙酰氨基蒽醌和1-和2-氨基蒽醌、1-和3-氯-2-氨基蒽醌、1-氨基-5-苯甲酰氨基蒽醌的例子描述，并且对1:5-二氨基蒽醌进行了双乙酰乙酰化。此外，指定了其他起始材料，包括1-氨基-4-苯甲酰氨基蒽醌、1-氨基-4-苯基氨基蒽醌和1:4-二氨基蒽醌。参考专利规格书429,982。 此外，本发明还涉及4-苯甲酰氨基二苯胺、咔唑、1-氨基苯并-4-磺酸21-噻唑酰胺和萘磺酰胺的N-乙酰乙酰衍生物，以及通过在90-100％（优选为冰醋酸）乙酸存在下，在40-80℃（优选为60-70℃）下加热含有二级氮原子的芳香胺或杂环化合物，制备其他乙酰乙酰氨基化合物。例子描述了上述四种化合物和1-氨基苯并-4-磺酸吗啉酰和二苯胺的乙酰乙酰化，指定的其他起始材料包括苯二胺萘醌、1-氨基苯并-4-磺酸对苯基苯胺酰和二甲基酰胺、4-氨基二苯磺酮和N-苯基-1-和2-萘胺。参考专利规格书429,982。
• PREPARATION METHOD OF ORIGINAL DYE OF VAT BROWN R
  申请人：Xiang Dezhi

  公开号：US20120296097A1

  公开（公告）日：2012-11-22

  A preparation method of original dye of Vat Brown R comprises the following steps: a. after acylation of 1,5-diaminoanthraquinone, 1-amino-5-benzamidoanthraquinone was prepared by acidic hydrolysis; b. 1-benzamido-4-bromoanthraquinone was obtained from 1-aminoanthraquinone by acylation and bromination; c. a condensate of Vat Brown R was obtained by condensation reaction of 1-amino-5-benzamidoanthraquinone and 1-benzamido-4-bromoanthraquinone; d. the original dye of Vat Brown R was obtained from the condensate of Vat Brown R by ring closing reaction and oxidation reaction. The method omits one oxidation step, economizes significant amount of oxidizing agent, and reduces significant amount of waste water, so it is very beneficial to environment protection; and the method also exhibited the advantages of highly increasing product yield and reducing the costs of raw materials to an extent of more than 30%.

  Vat Brown R的原料染料制备方法包括以下步骤：a.在1,5-二氨基蒽醌酰化后，通过酸性水解制备1-氨基-5-苯甲酰基蒽醌; b.从1-氨基蒽醌酰化和溴化中获得1-苯甲酰基-4-溴蒽醌; c.通过1-氨基-5-苯甲酰基蒽醌和1-苯甲酰基-4-溴蒽醌的缩合反应获得Vat Brown R的缩合物; d.通过环合反应和氧化反应从Vat Brown R的缩合物中获得原料染料。该方法省略了一个氧化步骤，节约了大量氧化剂，并减少了大量废水，因此对环境保护非常有益；此外，该方法还表现出高增加产品产量和降低原材料成本的优点，降低了30％以上的成本。
• Process for the preparation of anthraquinone imides
  申请人：Ciba-Geigy AG

  公开号：US04659831A1

  公开（公告）日：1987-04-21

  The invention relates to a process for the preparation of anthraquinone imides by condensing vattable anthraquinone compounds which contain at least one primary amino group with aromatic halogen compounds, in an organic solvent and at elevated temperature in the presence of a base and a copper catalyst. The process comprises first carrying out the condensation until a reaction of 60-95% has taken place, and then subjecting the reaction mixture, without isolating the reaction product, to an aftertreatment at a temperature which is 5.degree. to 60.degree. C. above the initial temperature of the condensation. This process permits the anthraquinone imides to be obtained in increased yield and additionally provides products with improved qualities. The intermediates so obtained can be further processed to vat dyes.

  本发明涉及一种通过在有机溶剂中，在碱和铜催化剂的存在下，将至少含有一个一级氨基的可染性蒽醌化合物与芳香卤素化合物缩合而制备蒽醌亚胺的方法。该方法首先进行缩合反应，直到反应达到60-95％，然后在不分离反应产物的情况下，将反应混合物在缩合的初始温度上升5℃到60℃的温度下进行后处理。该方法使得蒽醌亚胺的产率增加，并且还提供了具有改善质量的产品。所得到的中间体可以进一步加工成为邻菲染料。
• Organic dyes containing silane groups and process for preparing same
  申请人：Montedison S.p.A.

  公开号：US04609404A1

  公开（公告）日：1986-09-02

  This invention relates to organic dyes containing silane groups; composite pigments obtainable by grafting said dyes onto an inorganic substrate; and, the respective processes for preparing said dyes and composite pigments. The dyes have general formula: ##STR1## wherein R.sub.1 and R.sub.2, which may be equal or different, are selected from the group consisting of H, --NH.sub.2, --NHR wherein R is an alkyl group having from 1 to 4 carbon atoms or a phenyl group, --NHCOCH.sub.3, --NHCOC.sub.6 H.sub.5, --NO.sub.2, a halogen, --OH, --O--C.sub.6 H.sub.5 and --S--C.sub.6 H.sub.5 ; n is a number selected from 3, 4 and 5; W is selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms and a phenyl group; Y is an alkoxy group having from 1 to 4 carbon atoms; q is a number selected from 0 and 1; X is 3 and m is a number selected from 0, 1, 2 and 3 when q is 0; x is 2 and m is a number selected from 0, 1 and 2 when q is 1. The composite pigments obtained from said dyes are employed in the painting products, air enamels and stoving enamels, in the pigmentation of plastic materials, in the inks and in the printing of fabrics.

  本发明涉及含有硅烷基的有机染料；通过将该染料嫁接到无机基质上获得的复合颜料；以及制备该染料和复合颜料的相应过程。该染料具有通式：##STR1## 其中R.sub.1和R.sub.2（可以相等或不同）选自包括H，--NH.sub.2，--NHR（其中R是具有1到4个碳原子的烷基或苯基），--NHCOCH.sub.3，--NHCOC.sub.6 H.sub.5，--NO.sub.2，卤素，--OH，--O--C.sub.6 H.sub.5和--S--C.sub.6 H.sub.5的群；n是选自3、4和5的数字；W选自具有1到4个碳原子的烷基和苯基的群；Y是具有1到4个碳原子的烷氧基；q是选自0和1的数字；当q为0时，X为3，m是选自0、1、2和3的数字；当q为1时，x为2，m是选自0、1和2的数字。从该染料获得的复合颜料用于涂料产品、空气漆和烘烤漆中、塑料材料的着色、油墨和织物印刷中。

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