10,12-二十九二炔酸 | 66990-34-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 10,12-二十九二炔酸
• 中文别名: 10,12-二十九碳二炔酸
• 英文名称: 10,12-nonacosadiynoic acid
• 英文别名: nonacosa-10,12-diynoic acid
• CAS: 66990-34-9
• 化学式: C₂₉H₅₀O₂
• mdl: MFCD00060119
• 分子量: 430.715
• InChiKey: LQESNAREESPTNY-UHFFFAOYSA-N

物化性质

• 熔点：
  72 °C
• 沸点：
  568.0±33.0 °C(Predicted)
• 密度：
  0.919±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  31
• 可旋转键数：
  23
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.827
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2916190090

反应信息

• 作为反应物：
  描述：

  10,12-二十九二炔酸 在 三乙胺 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 水 、 丙酮 为溶剂， 反应 5.0h， 生成 (S)-2-Amino-5-nonacosa-10,12-diynoylamino-pentanoic acid
  参考文献：
  名称：

  一系列新的两亲分子形成稳定的 Z 型（极性）Langmuir-Blodgett 薄膜

  摘要：

  一系列新的两亲分子在烃链上带有两个酰胺基团，通过 Langmuir-Blodgett (LB) 技术形成头对尾的 Z 型（极性）多层膜，这与倾向于沉积在头部的常见两亲分子形成对比-到头，尾到尾的Y型时尚。沿链具有一个酰胺基团的分子形成 Y 型或 Z 型结构，具体取决于酰胺沿链的位置。对硝基苯胺或部花青基团可以在极性意义上排列，通过将它们共价连接到此类两亲物，以产生显示二次谐波产生 (SHG) 的多层膜。这些薄膜通过椭偏仪、X 射线衍射、IR、UV 和 SHG 测量进行表征。Z 型沉积与观察到的薄膜的低水接触角相关，

  DOI：

  10.1021/ja00163a005

文献信息

• Face-on and Columnar Porphyrin Assemblies at Solid/Liquid Interface on HOPG
  作者：Joe Otsuki、Kazuhiko Namiki、Yuki Arai、Makoto Amano、Hirokazu Sawai、Arata Tsukamoto、Toshiki Hagiwara

  DOI：10.1246/cl.2009.570

  日期：2009.6.5

  Porphyrins having alkyl chains, each of which contains a diacetylene unit, were prepared to examine their self-assembled structures at the liquid/solid interface on graphite. The porphyrins with the longest alkyl chains form a face-on arrangement on the surface, while those with shorter alkyl chains form highly ordered one-dimensional columns. This work demonstrates that introducing a structural perturbation in the alkyl chain is a useful strategy to obtain novel surface assemblies.

  我们制备了含有烷基链的卟啉，每个烷基链都包含一个二炔单元，以研究它们在石墨的液/固界面的自组装结构。具有最长烷基链的卟啉在表面形成面朝上的排列，而具有较短烷基链的卟啉则形成高度有序的一维柱状结构。这项工作表明，在烷基链中引入结构扰动是一种获得新型表面组装的有效策略。
• ALL-SOLID SECONDARY BATTERY, SOLID ELECTROLYTE COMPOSITION AND ELECTRODE SHEET FOR BATTERY USED THEREIN, AND METHODS OF MANUFACTURING ELECTRODE SHEET FOR BATTERY AND ALL-SOLID SECONDARY BATTERY
  申请人：Fujifilm Corporation

  公开号：EP3258530A1

  公开（公告）日：2017-12-20

  Provided are an all solid state secondary battery having a positive electrode active material layer, an inorganic solid electrolyte layer, and a negative electrode active material layer in this order, in which at least one layer of the positive electrode active material layer, the inorganic solid electrolyte layer, or the negative electrode active material layer includes an electrolytic polymerizable compound and an inorganic solid electrolyte, in which the electrolytic polymerizable compound is an electrolytic polymerizable compound having a molecular weight of less than 1,000 which is represented by any one of Formulae (1) to (5) below, and the inorganic solid electrolyte contains a metal belonging to Group I or II of the periodic table and has an ion conductivity of the metal being contained, an electrode sheet for a battery, and method for manufacturing an electrode sheet for a battery and an all solid state secondary battery. Reference signs each independently represent a specific atom, substituent, or linking group.

  本发明提供了一种全固态二次电池，该电池依次具有正极活性材料层、无机固体电解质层和负极活性材料层，其中正极活性材料层、无机固体电解质层或负极活性材料层中至少有一层包括电解可聚合化合物和无机固体电解质、其中，电解可聚合化合物是分子量小于 1,000 的电解可聚合化合物，由下式（1）至（5）中的任一个表示，无机固体电解质含有属于元素周期表第 I 组或第 II 组的金属，并具有所含金属的离子电导率，电池电极片，以及电池电极片和全固态二次电池的制造方法。 参考符号各自独立地代表一个特定的原子、取代基或连接基团。
• COATING COMPOSITION FOR FOOD AND BEVERAGE CONTAINER
  申请人：SWIMC LLC

  公开号：EP3473684A1

  公开（公告）日：2019-04-24

  Food and beverage containers and methods of coating are provided. The food and beverage containers include a metal substrate that is at least partially coated with a coating composition that includes a water-dispersible resin system and an aqueous carrier. The resin system includes an epoxy component and an acrylic component. In a preferred embodiment, the coating composition is at least minimally retortable when cured.

  本文提供了食品和饮料容器以及涂层方法。食品和饮料容器包括至少部分涂有涂料组合物的金属基材，涂料组合物包括水分散性树脂体系和水性载体。树脂体系包括环氧组分和丙烯酸组分。在一个优选的实施方案中，涂层组合物在固化时至少具有最小程度的耐蒸煮性。
• Plastics colouration
  申请人：Jarvis Anthony

  公开号：US10246562B2

  公开（公告）日：2019-04-02

  A method of imparting color to a plastic substrate comprising applying to the substrate, or incorporating within the substrate, a diacetylene compound of general formula (I) wherein n=1 to 20; R1=an optionally substituted C1-20 alkyl group which may contain heteroatoms; T=H, an optionally substituted C1-20 alkyl group which may contain heteroatoms or —(CH2)m—C(═O)-Q2R2; Q1=NH, CO, NHCONH, OCONH, COS, NHCSNH or NR3, wherein m, Q2 and R2 are independently selected from the same groups as n, Q1 and R1 respectively; R3 is an optionally substituted C1-20 alkyl group which may contain heteroatoms; and irradiating the substrate to impart color to the substrate is described.

  一种使塑料基材着色的方法，包括将通式(I)的二乙炔化合物涂敷于基材上或掺入基材中，其中n=1至20；R1=可含有杂原子的任选取代的C1-20烷基；T=H、可含有杂原子的任选取代的C1-20烷基或-(CH2)m-C(═O)-Q2R2；Q1=NH、CO、NHCONH、OCONH、COS、NHCSNH 或 NR3，其中 m、Q2 和 R2 分别独立地选自与 n、Q1 和 R1 相同的基团；R3 是可含有杂原子的任选取代的 C1-20 烷基；以及辐照底物以赋予底物颜色的描述。
• All solid state secondary battery, solid electrolyte composition used therefor, electrode sheet for battery, and method for manufacturing electrode sheet for battery and all solid state secondary battery
  申请人：FUJIFILM Corporation

  公开号：US10411292B2

  公开（公告）日：2019-09-10

  Provided are an all solid state secondary battery having a positive electrode active material layer, an inorganic solid electrolyte layer, and a negative electrode active material layer in this order, in which at least one layer of the positive electrode active material layer, the inorganic solid electrolyte layer, or the negative electrode active material layer includes an electrolytic polymerizable compound and an inorganic solid electrolyte, in which the electrolytic polymerizable compound is an electrolytic polymerizable compound having a molecular weight of less than 1,000 which is represented by any one of Formulae (1) to (5) below, and the inorganic solid electrolyte contains a metal belonging to Group I or II of the periodic table and has an ion conductivity of the metal being contained, an electrode sheet for a battery, and method for manufacturing an electrode sheet for a battery and an all solid state secondary battery. Reference signals each independently represent a specific atom, substituent, or linking group.

  本发明提供了一种全固态二次电池，该电池依次具有正极活性材料层、无机固体电解质层和负极活性材料层，其中正极活性材料层、无机固体电解质层或负极活性材料层中至少有一层包括电解可聚合化合物和无机固体电解质、其中，电解可聚合化合物是分子量小于 1,000 的电解可聚合化合物，由下式（1）至（5）中的任一个表示，无机固体电解质含有属于元素周期表第 I 组或第 II 组的金属，并具有所含金属的离子电导率，电池电极片，以及电池电极片和全固态二次电池的制造方法。 参考信号各自独立地代表一个特定的原子、取代基或连接基团。