11-癸基二十一烷 | 55320-06-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 中文名称: 11-癸基二十一烷
• 英文名称: 11-decyl-heneicosane
• 英文别名: 11-decylheneicosane；11-Decyl-heneicosan；11-n-Decylheneikosan；Tridecylmethan；tris-decyl-methane；Heneicosane, 11-decyl-；11-decylhenicosane
• CAS: 55320-06-4
• 化学式: C₃₁H₆₄
• 分子量: 436.849
• InChiKey: BCWYKEQUGMQGAP-UHFFFAOYSA-N

物化性质

• 熔点：
  9.19°C
• 沸点：
  447.65°C (estimate)
• 密度：
  0.8980 (estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  16.7
• 重原子数：
  31
• 可旋转键数：
  27
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2901100000

反应信息

• 作为产物：
  描述：

  11-decyl-heneicos-10-ene 在 溶剂黄146 、 铂 作用下， 生成 11-癸基二十一烷
  参考文献：
  名称：

  Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite

  摘要：

  Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales.We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.

  DOI：

  10.1111/j.1945-5100.2002.tb00852.x

文献信息

• Dissolving metal reduction with crown ether — reductive decyanation
  作者：Tomihiko Ohsawa、Takao Kobayashi、Yuko Mizuguchi、Takayo Saitoh、Takeshi Oishi

  DOI：10.1016/s0040-4039(00)95137-2

  日期：1985.1

  Toluene radical anion generated from potassium metal/dicyclohexano-18-crown-6/toluene system has been proved to be highly effective for reductive decyanation reaction of primary, secondary and tertiary cyanides.

  由钾金属/二环己基-18-冠-6 /甲苯系统产生的甲苯自由基阴离子已被证明对伯，仲和叔氰化物的还原性脱氰反应非常有效。
• The Heat Capacity, Heat of Fusion and Entropy of 11-n-Decylheneicosane
  作者：F. B. Fischl、B. F. Naylor、C. W. Ziemer、G. S. Parks、J. G. Aston

  DOI：10.1021/ja01228a007

  日期：1945.12
• OHSAWA, TOMIHIKO;KOBAYASHI, TAKAO;MIZUGUCHI, YUKO;SAITOH, TAKAYO;OISHI, T+, TETRAHEDRON LETT., 1985, 26, N 49, 6103-6106
  作者：OHSAWA, TOMIHIKO、KOBAYASHI, TAKAO、MIZUGUCHI, YUKO、SAITOH, TAKAYO、OISHI, T+

  DOI：——

  日期：——
• Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite
  作者：M. E. Zolensky、K. Nakamura、M. Gounelle、T. Mikouchi、T. Kasama、O. Tachikawa、E. Tonui

  DOI：10.1111/j.1945-5100.2002.tb00852.x

  日期：2002.5

  Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales.We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.

表征谱图