1H,1H,11H-二十氟十一烷丙烯酰酯 | 4998-38-3

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1H,1H,11H-二十氟十一烷丙烯酰酯
• 中文别名: 二十氟十一烷丙烯酰酯；1H,1H,11H-全氟十一烷基丙烯酸酯
• 英文名称: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11-icosafluoroundecyl acrylate
• 英文别名: 1H,1H,11H-eicosafluoroundecyl acrylate；1H,1H,11H-Perfluoroundecyl Acrylate；2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11-icosafluoroundecyl prop-2-enoate
• CAS: 4998-38-3
• 化学式: C₁₄H₆F₂₀O₂
• mdl: MFCD00042112
• 分子量: 586.168
• InChiKey: ASJLMYWCUSHRIW-UHFFFAOYSA-N

物化性质

• 熔点：
  44-45°C
• 沸点：
  115°C 1mm
• 密度：
  1.6468 (estimate)
• 闪点：
  115°C/1mm

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  36
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.785
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  22

安全信息

• 危险等级：
  IRRITANT, KEEP COLD
• 危险品标志：
  Xi
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38

反应信息

• 作为反应物：
  描述：

  1H,1H,11H-二十氟十一烷丙烯酰酯 生成 poly(1,1,11-H-partialfluoroundecyl acrylate)
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Functionalized Photoreactive Compounds
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20080274304A1

  公开（公告）日：2008-11-06

  The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式(I)的官能化光反应化合物，特别适用于液晶对准材料。由于在特定分子系统中的不饱和键直接连接到两个不饱和环系统上附加了一个电子受体基团，因此在包含本发明的这些官能化光反应化合物的材料中可以实现异常高的光敏性、优异的对准性能以及良好的机械稳健性。
• EXTERNAL PREPARATION FOR THE SKIN AND COPOLYMER TO BE USED THEREIN
  申请人：POLA CHEMICAL INDUSTRIES, INC.

  公开号：EP1452161A1

  公开（公告）日：2004-09-01

  An object of the present invention is to provide an external preparation for the skin, which shows an excellent effect of sufficiently protecting the living body against irritants that exist in the external environments, and a polymer material to be preferably used therein. Provided is an external preparation for the skin obtained mixing a copolymer which comprises constituent units derived from monomers of the general formula (I), (II) and, if necessary, (IV) with the content of units (I) ranging from 5 to 25 wt % based on the total amount of all the constituent units, preferably with the contents of units (I), (II) and (IV) being 5 to 9.8 wt %, 30.2 to 45 wt %, and 50 to 60 wt %respectively, with other optional components. In the formula, R1 is H or C1-3 alkyl; R2 is C5-12 alkyl having 8 to 21 fluorine atoms; R3 is H or C1-3 alkyl; R4 is optionally hydroxylated C2-4 alkylene; R5 is H, a C1-20 aromatic group, a C1-20 aliphatic hydrocarbon group, or C1-20 acyl; and n is 4 to 50.

  本发明的目的是提供一种外用制剂，该制剂表现出优异的效果，能够充分保护生物体免受存在于外部环境中的刺激物的侵害，并提供一种最好用于其中的聚合物材料。提供了一种外用制剂，该制剂通过将包含来自通式（I）、（II）和（必要时）（IV）单体的组分单元的共聚物与单体（I）的含量在所有组分单元的总量中占5至25重量％的范围内混合，最好是单体（I）、（II）和（IV）的含量分别为5至9.8重量％、30.2至45重量％和50至60重量％，并添加其他可选组分而获得。在通式中，R1是H或C1-3烷基；R2是具有8到21个氟原子的C5-12烷基；R3是H或C1-3烷基；R4是可选择羟基化的C2-4烷基；R5是H、C1-20芳香族基、C1-20脂肪族碳氢基或C1-20酰基；n为4至50。
• ANTIMICROBIAL COMPOSITIONS
  申请人：Chisholm Bret Ja

  公开号：US20110195041A1

  公开（公告）日：2011-08-11

  Provided are antimicrobial compositions including at least one biocide covalently bound to a polyurethane. The biocide moiety may comprise triclosan, a triclosan derivative, or a quaternary ammonium salt. Further provided are methods of reducing biofilm formation or microbial growth on a surface, the method including applying to the surface an antimicrobial composition including at least one biocide covalently attached to a polyurethane.

  提供了抗微生物组合物，其中至少包括一种生物杀灭剂共价结合到聚氨酯上。生物杀灭剂部分可以包括三氯生、三氯生衍生物或季铵盐。此外，还提供了一种减少生物膜形成或表面微生物生长的方法，该方法包括将至少一种生物杀灭剂共价连接到聚氨酯的抗微生物组合物涂布到表面。
• CYANOSTILBENES
  申请人：ROLIC AG

  公开号：US20160083655A1

  公开（公告）日：2016-03-24

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及新型化合物，特别适用于对从材料进行定向，尤其是光定向，特别是用于光学或电光应用的从材料，例如安全应用、液晶器件或光学或电光薄膜。
• Silyl 2-amidoacetate and silyl 3-amidopropionate compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0333361A2

  公开（公告）日：1989-09-20

  The present invention provides novel silyl 2-amidoacetates and silyl 3-amidopropionates which are the reaction products of azlactone and silanol reactants. The novel products result from nucleophilic addition of a soluble or insoluble, low or high molecular weight reactant containing one or more silanol groups and a soluble or insoluble, low or high molecular weight reactant containing one or more azlactone groups. The reaction products provide for high adhesion between the siliceous and azlactone reactants, as would be useful as protective coatings particularly on silicon-containing materials. It has been recognized in the present invention that silyl 2-amidoacetates and silyl 3-amidopropionates are useful linkages between silanol and azlactone derived materials.

  本发明提供了新型 2-氨基乙酸硅酯和 3-氨基丙酸硅酯，它们是偶氮内酯和硅烷醇反应物的反应产物。这些新型产品是由含有一个或多个硅烷醇基团的可溶性或不可溶性、低分子量或高分子量反应物与含有一个或多个氮内酯基团的可溶性或不可溶性、低分子量或高分子量反应物亲核加成而成。反应产物使硅质反应物和氮内酯反应物之间具有很高的附着力，可用作保护涂层，特别是在含硅材料上。本发明已认识到，2-氨基乙酸硅酯和 3-氨基丙酸硅酯是硅醇和氮内酯衍生材料之间的有用连接物。