1H,1H,11H-全氟十一烷基甲基丙烯酸盐 | 41123-44-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1H,1H,11H-全氟十一烷基甲基丙烯酸盐
• 中文别名: 1H,1H,11H-全氟甲基丙烯酸十一酯
• 英文名称: 1H,1H,11H-Perfluoroundecyl Methacrylate
• 英文别名: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11-icosafluoroundecyl 2-methylprop-2-enoate
• CAS: 41123-44-8
• 化学式: C₁₅H₈F₂₀O₂
• mdl: MFCD00042111
• 分子量: 600.195
• InChiKey: PUCOLQDJAFBFDR-UHFFFAOYSA-N

物化性质

• 熔点：
  36-38°C
• 沸点：
  110°C 0,05mm
• 密度：
  1.561±0.06 g/cm3(Predicted)
• 闪点：
  110°C/0.05mm
• 稳定性/保质期：
  常规情况下不会分解，也没有危险反应。

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  37
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  22

安全信息

• 危险等级：
  IRRITANT, KEEP COLD
• 危险品标志：
  F,Xi
• 危险类别码：
  R36/37/38
• 安全说明：
  S26,S36/37/39

反应信息

• 作为反应物：
  描述：

  1H,1H,11H-全氟十一烷基甲基丙烯酸盐 生成 poly(1,1,11-H-partialfluoroundecyl methacrylate)
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Functionalized Photoreactive Compounds
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20080274304A1

  公开（公告）日：2008-11-06

  The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式(I)的官能化光反应化合物，特别适用于液晶对准材料。由于在特定分子系统中的不饱和键直接连接到两个不饱和环系统上附加了一个电子受体基团，因此在包含本发明的这些官能化光反应化合物的材料中可以实现异常高的光敏性、优异的对准性能以及良好的机械稳健性。
• CYANOSTILBENES
  申请人：ROLIC AG

  公开号：US20160083655A1

  公开（公告）日：2016-03-24

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及新型化合物，特别适用于对从材料进行定向，尤其是光定向，特别是用于光学或电光应用的从材料，例如安全应用、液晶器件或光学或电光薄膜。
• Functionalized photoreactive compounds
  申请人：Rolic AG

  公开号：EP1764405A1

  公开（公告）日：2007-03-21

  The present invention concerns functionalized photoreactive compounds of formula (I) that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式 (I) 的官能化光活性化合物，这些化合物在液晶配向材料中特别有用。 由于在直接连接两个不饱和环体系的特定分子体系中加入了一个退电子基团，因此在包含本发明所述功能化光活性化合物的材料中，可以获得极高的光敏性、优异的配向性能以及良好的机械坚固性。
• CURABLE POLYSILOXANE COMPOSITIONS AND SLIPPERY MATERIALS AND COATINGS AND ARTICLES MADE THEREFROM
  申请人：ADAPTIVE SURFACE TECHNOLOGIES, INC.

  公开号：EP3489010A1

  公开（公告）日：2019-05-29

  The present teachings generally provide curable polysiloxane compositions including a base resin and a lubricating liquid. The curable polysiloxane compositions can create a slippery material or coating, where an overlayer of the lubricating liquid is spontaneously presented at an exposed surface of the cured base resin. Articles of manufacture including the curable polysiloxane compositions and slippery coatings and materials also are provided. Per some aspects of the invention addition and condensation based curable silicone coating composition is provided which may be used to to provide slippery, lubricious, or repellent materials and coatings against a fluid matter including water, oil, viscous fluids, slurries, complex fluid mixtures with or without solids in them, biological fluids and organisms, bodily fluids, ice, frost, and mixtures thereof; to reduce drag or friction; to enhance product performance by providing slippery feeling, by providing anti-fouling function, by providing application mechanism of payloads such as lubricants, personal care products, drug molecules, and biocides; to provide non-stick or easy-to-clean function; to provide anti-fouling or foul-release function on open surfaces, internal surfaces, membranes; to provide pinning free or low contact angle hysteresis surfaces; to provide homogeneous interface to suppress nucleation; to provide a barrier layer such as anti-corrosion; to provide anti-stain, anti-smudge, anti-fingerprint, anti-soil function. The curable silicone coating composition of the present invention comprises a stable thin liquid overlayer (LOL) leading to a slippery surface with very low roll-off angle for water typically seen as equal or greater than 15 degrees when a 15 uL water droplet is applied on said slippery surfaces. In addition, the curable polysiloxane compositons can further incorporate at least one or more surface active amphiphilic polymers leading to a self-lubricating amphiphilic slippery coating, and can incorporate optional biocides and/or biocidal effect boosters that can further impart anti-biofouling functions in both static and dynamic conditions.

  本教导一般提供可固化的聚硅氧烷组合物，包括基底树脂和润滑液体。可固化的聚硅氧烷组合物可以制成滑爽的材料或涂层，其中润滑液体的覆盖层会自发地呈现在固化的基础树脂的暴露表面。本发明还提供了包括可固化聚硅氧烷组合物和滑爽涂层及材料的制造物品。根据本发明的某些方面，本发明提供了基于添加和缩合的可固化有机硅涂料组合物，可用于提供防滑、润滑或排斥流体物质的材料和涂料，这些流体物质包括水、油、粘性流体、泥浆、含有或不含固体的复杂流体混合物、生物流体和有机体、体液、冰、霜及其混合物；以减少阻力或摩擦；通过提供滑爽感、防污功能、提供有效载荷（如润滑剂、个人护理产品、药物分子和杀菌剂）的应用机制来提高产品性能；提供不粘性或易清洁功能；在开放表面、内表面、膜上提供防污或除污功能；提供无针刺或低接触角滞后表面；提供均匀界面以抑制成核；提供阻挡层，如防腐蚀；提供防污、防污迹、防指纹、防污功能。本发明的可固化有机硅涂料组合物包括一个稳定的薄液体覆盖层（LOL），可形成滑爽的表面，当 15 uL 的水滴在所述滑爽表面上时，水的滚落角非常低，通常等于或大于 15 度。此外，可固化的聚硅氧烷复合物还可进一步加入至少一种或多种表面活性两性聚合物，形成自润滑的两性滑爽涂层，并可加入任选的杀菌剂和/或杀菌效果增强剂，进一步增强静态和动态条件下的防生物污染功能。
• Curable polysiloxane compositions and slippery materials and coatings and articles made therefrom
  申请人：Adaptive Surface Technologies, Inc.

  公开号：US10240067B2

  公开（公告）日：2019-03-26

  The present teachings generally provide curable polysiloxane compositions including a base resin including a MQ vinyl siloxane. Articles of manufacture including the curable polysiloxane compositions and slippery coatings and materials also are provided. The compositions may be used to provide slippery, lubricious, or repellent materials and coatings and may provide anti-fouling function. The compositions can provide anti-fouling or foul-release function on open surfaces, internal surfaces, membranes; to provide pinning free or low contact angle hysteresis surfaces; to provide homogeneous interface to suppress nucleation; to provide a barrier layer such as anti-corrosion; to provide anti-stain, anti-smudge, anti-fingerprint, anti-soil function.

  本教导一般提供可固化的聚硅氧烷组合物，包括一种包括 MQ 乙烯基硅氧烷的基础树脂。还提供了包括可固化聚硅氧烷组合物和防滑涂层及材料的制造物品。这些组合物可用于提供防滑、润滑或驱避材料和涂层，并可提供防污功能。这些组合物可在开放表面、内表面、膜上提供防污或除污功能；提供无针刺或低接触角滞后表面；提供均匀界面以抑制成核；提供屏障层，如防腐蚀；提供防污、防污迹、防指纹、防污功能。