2,2'-(2,2,3,3,4,4,5,5,6,6,7,7-十二氟辛烷-1,8-二基)双(环氧乙烷) | 74328-56-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 2,2'-(2,2,3,3,4,4,5,5,6,6,7,7-十二氟辛烷-1,8-二基)双(环氧乙烷)
• 英文名称: 1,2;11,12-Diepoxy-4,4,5,5,6,6,7,7,8,8,9,9-dodecafluorododecane
• 英文别名: 2,2'-(2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluorooctane-1,8-diyl)bis(oxirane)；2-[2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-8-(oxiran-2-yl)octyl]oxirane
• CAS: 74328-56-6
• 化学式: C₁₂H₁₀F₁₂O₂
• 分子量: 414.191
• InChiKey: BUCVATDLDBZNPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  26
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  2,2'-(2,2,3,3,4,4,5,5,6,6,7,7-十二氟辛烷-1,8-二基)双(环氧乙烷) 在 盐酸 、 三氟化硼乙醚 作用下， 以 甲醇 为溶剂， 反应 2.0h， 生成 4,4,5,5,6,6,7,7,8,8,9,9-Dodecafluorododecane-1,2,11,12-tetrol
  参考文献：
  名称：

  氟化环氧化物：5.由α，ω-二碘全氟烷烃高度选择性地合成二环氧化合物。亲核环氧化物开环和新的两亲化合物和单体的区域选择性

  摘要：

  将α，ω-二碘全氟烷烃I–（CF 2 CF 2）n – I（n  = 2、3）自由基加成到乙酸烯丙酯上的改进方法，得到相应的双加合物AcOCH 2 CHICH 2（CF 2 CF 2）ñ CH 2 CHI-CH 2 OAC（2A - 2B）已经研制成功。初级双加合物2a – 2b随后在加成混合物中发生重排，从而得到半重排的加合物AcOCH 2 CHICH 2 –（CF 2 CF2）n -CH 2 CH-（OAc）CH 2 I（3a - 3b）的量约为 相对收益率15％。在反应温度下。加合物2a – 2b和重排的加合物3a – 3b均被转换为具有高化学选择性的CH 2（–O–）CHCH 2（CF 2 CF 2）n CH 2 CH –（– O–）CH 2（4a – 4b）有两种方式：2a - 2b直接环氧化的选择性和/或3a – 3b中的氢氧化钾非常依赖于溶剂。第二种方法包括将2a – 2b和/或3a

  DOI：

  10.1016/s0022-1139(99)00301-2
• 作为产物：
  描述：

  (2,11-二碘-4,4,5,5,6,6,7,7,8,8,9,9-十二氟十二烷-1,12-二基)二乙酸酯 在 盐酸 、 氢氧化钾 作用下， 以 甲醇 、 乙醚 为溶剂， 反应 6.5h， 生成 2,2'-(2,2,3,3,4,4,5,5,6,6,7,7-十二氟辛烷-1,8-二基)双(环氧乙烷)
  参考文献：
  名称：

  氟化环氧化物：5.由α，ω-二碘全氟烷烃高度选择性地合成二环氧化合物。亲核环氧化物开环和新的两亲化合物和单体的区域选择性

  摘要：

  将α，ω-二碘全氟烷烃I–（CF 2 CF 2）n – I（n  = 2、3）自由基加成到乙酸烯丙酯上的改进方法，得到相应的双加合物AcOCH 2 CHICH 2（CF 2 CF 2）ñ CH 2 CHI-CH 2 OAC（2A - 2B）已经研制成功。初级双加合物2a – 2b随后在加成混合物中发生重排，从而得到半重排的加合物AcOCH 2 CHICH 2 –（CF 2 CF2）n -CH 2 CH-（OAc）CH 2 I（3a - 3b）的量约为 相对收益率15％。在反应温度下。加合物2a – 2b和重排的加合物3a – 3b均被转换为具有高化学选择性的CH 2（–O–）CHCH 2（CF 2 CF 2）n CH 2 CH –（– O–）CH 2（4a – 4b）有两种方式：2a - 2b直接环氧化的选择性和/或3a – 3b中的氢氧化钾非常依赖于溶剂。第二种方法包括将2a – 2b和/或3a

  DOI：

  10.1016/s0022-1139(99)00301-2

文献信息

• FLUORINATED POLYFUNCTIONAL (METH)ACRYLIC ESTERS, FLUOROMONOMER COMPOSITION, MATERIAL WITH LOW REFRACTIVE INDEX, AND LOWLY REFLECTIVE FILM
  申请人：NOF CORPORATION

  公开号：EP0820980B1

  公开（公告）日：2001-07-11
• CURABLE COMPOSITION AND NOVEL ADAMANTANE COMPOUND
  申请人：SUGIYAMA Norihide

  公开号：US20080071033A1

  公开（公告）日：2008-03-20

  To provide a curable composition to form a cured fluorinated product excellent in light resistance, transparency, moisture resistance and adhesive properties, and a novel adamantane compound. A liquid curable composition which comprises a fluoropolymer having a group capable of reacting with an epoxy group or an acid anhydride and containing polymerized units based on a fluoroolefin and polymerized units based on a hydrocarbon monomer, a fluorinated compound having an epoxy group, and an acid anhydride. An adamantane compound having from one to four of hydrogen atoms in the adamantine ring substituted by a glycidyl ether group and at least six of the remaining hydrogen atoms substituted by a fluorine atom.
• Antireflection film, polarizing plate and image display device
  申请人：Takada Katsuyuki

  公开号：US20110026126A1

  公开（公告）日：2011-02-03

  An antireflection film includes a support and a low refractive index layer formed from a composition for low refractive index layer containing (A) a polyfunctional fluorine-containing monomer having a polymerizable group and (B) a hydrophobilized conductive polymer composition containing a π-conjugated system conductive polymer and an anion group-containing polymer dopant, and a common logarithm log(SR) of a surface resistivity SR (Ω/sq) of a surface of the antireflection film on a side at which the low refractive index layer is provided is not more than 13.0.
• PRODUCTION METHOD OF ANTIREFLECTION FILM, ANTIREFLECTION FILM AND COATING COMPOSITION
  申请人：AKUTAGAWA Nobuyuki

  公开号：US20120207990A1

  公开（公告）日：2012-08-16

  A production method of an antireflection film comprises, in order, a step of applying a coating composition obtained by mixing the following components (A) to (D) on a base material to form a coating film, a step of drying the coating film to volatilize the solvent therefrom, and a step of curing the coating film to form a cured layer, wherein a multilayer structure having different refractive indexes is formed from the coating composition: (A) a compound having at least one structure selected from a fluorine-containing hydrocarbon structure and a polysiloxane structure and at least one isocyanate group; (B) an inorganic fine particle; (C) a curable binder containing no fluorine atom in the molecule; and (D) a solvent; provided that the mass ratio of [component (A)+component (B)]/[component (C)] is from 1/199 to 60/40.
• METHOD FOR PRODUCING ANTIREFLECTION FILM, ANTIREFLECTION FILM, AND COATING COMPOSITION
  申请人：AKUTAGAWA Nobuyuki

  公开号：US20120270021A1

  公开（公告）日：2012-10-25

  The method for producing an antireflection film is provided. The method includes, a step of coating a coating composition including the following components (A) to (D) on a base material to form a coating film, a step of volatilizing the solvent from the coating film for drying the coating film, and a step of curing the coating film to form a cured layer, in which a multilayer structure having different refractive indices from the coating composition is formed: (A) a fluorine-containing polymer with a specific structure, having a polyalkylene oxide group in the molecule, (B) non-surface-modified inorganic fine particles, or inorganic fine particles that are surface-treated with a silane coupling agent having a molecular weight of 600 or less, (C) a curable binder having no fluorine atom in the molecule, and (D) a solvent, provided that the mass ratio of [component (A)+component (B)]/[component (C)] is from 1/199 to 60/40.