2,4-二甲基-3-氟苯甲醛 | 363134-36-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4-二甲基-3-氟苯甲醛
• 英文名称: 2,4-Dimethyl-3-fluorobenzaldehyde
• 英文别名: 3-fluoro-2,4-dimethylbenzaldehyde
• CAS: 363134-36-5
• 化学式: C₉H₉FO
• mdl: MFCD04972838
• 分子量: 152.16
• InChiKey: URYIONJXXXXOCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.222
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三氯化铝 、 邻二氯苯 、 2,6-二甲基氟苯 、 、 4-氟-3,5-二甲基苯甲醛 在 盐酸 一氧化碳 、 ice water 、 环己烷 、 水 、 magnesium sulfate 、 2,6-二甲基氟苯 、 邻二氯苯 、 苯甲醛 作用下， 以 Parr®-brand 4522 为溶剂， 50.0 ℃ 、91.92 MPa 条件下， 反应 16.0h， 生成 2,4-二甲基-3-氟苯甲醛
  参考文献：
  名称：

  Method of producing fluorinated and chlorinated benzaldehydes and compositions thereof

  摘要：

  本发明涉及一种制备含氟芳香醛的方法，更具体地说，涉及一种在相对较低的压力、低温度和至多催化量的酸（例如水盐酸）存在下，通过氟化苯与一氧化碳和氯化铝反应的甲酰化过程。所得的氟化苯甲醛可用作形成多种不同化合物的前体，例如染料、调味料、香料、除草剂化合物、成核剂、聚合物添加剂等。该创新方法提供了一种非常经济、安全的方法，以非常高的产率生产这种氟化苯甲醛。

  公开号：

  US06300525B1

文献信息

• Novel fluorinated and alkylated alditol derivatives and compositions and polyolefin articles containing same
  申请人：——

  公开号：US20020062034A1

  公开（公告）日：2002-05-23

  Plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials are provided. More particularly, this invention relates to certain alkyl (or alkoxy) substituted fluorobenzylidene sorbitol acetals and polymer compositions thereof which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive fluorinated and alkylated benzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.

  本发明提供了一种作为成核剂有用的塑料添加剂，特别是用于改善聚合材料的光学性能。更具体地说，本发明涉及某些烷基（或烷氧基）取代的氟苯基丙烯醇山梨醇缩醛及其聚合物组成物，可以用于食品或化妆品容器和包装等领域。这些创新的氟化和烷基化苯基丙烯醇山梨醇缩醛也可用作水和有机溶剂的凝胶剂，特别是用于制备止汗凝胶棒的溶剂。
• Fluorinated and chlorinated benzaldehydes
  申请人：Milliken & Company

  公开号：US06297405B1

  公开（公告）日：2001-10-02

  A process for the preparation of aromatic aldehydes containing fluorine, and more particularly, to a formylation process for fluorinated aromatic derivatives through the reaction of fluorinated benzenes with carbon monoxide and aluminum chloride at a relatively low pressure, a low temperature, and in the presence of at most a catalytic amount of an acid (such as aqueous hydrochloric acid) is herein disclosed. The resultant fluorinated benzaldehydes are useful as precursors to the formation of a number of different compounds, such as dyestuffs, flavorings, fragrances, herbicidal compounds, nucleating agents, polymer additives, and the like. The inventive method provides a very cost effective and safe procedure for producing such fluorinated benzaldehydes in very high yields. The particular novel multi-substituted benzaldehydes are also encompassed within this invention.

  本发明涉及一种含氟芳香醛的制备方法，更具体地说，本发明涉及一种通过氟代苯与一氧化碳和氯化铝在相对较低的压力、低温和存在最多催化量的酸（如水盐酸）反应的甲酰化方法，得到的含氟苯甲醛可用作多种化合物（如染料、调味剂、香料、除草剂、成核剂、聚合物添加剂等）的前体。该创新方法提供了一种非常经济、安全的程序，可高产地生产这种含氟苯甲醛。此外，本发明还包括特定的新型多取代苯甲醛。
• Novel asymmetric halogen-alkyl alditol derivatives as nucleators and clarifiers for polyolefins, and polyolefin plastic compositions containing same
  申请人：——

  公开号：US20030013786A1

  公开（公告）日：2003-01-16

  This invention relates to plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials. More particularly, this invention relates to certain bis-halogen-alkyl-benzylidene alditol acetals and polymer compositions thereof which are useful as materials for food or cosmetic containers and packaging. These bis-halogen-alkylbenzylidene alditol acetals are also useful as gelling agents for organic solvents, particularly those used in the preparation of antiperspirant gel sticks.

  本发明涉及可用作成核剂的塑料添加剂，特别适用于改善聚合材料的光学性能。更具体地说，本发明涉及某些双卤素-烷基-亚苄基醛醇缩醛及其聚合物组合物，它们可用作食品或化妆品容器和包装的材料。这些双卤代烷基亚苄基醛糖醇乙缩醛还可用作有机溶剂的胶凝剂，特别是用于制备止汗剂凝胶棒的胶凝剂。
• Polyolefin compositions and articles comprising novel fluorinated and alkylated alditol derivatives
  申请人：——

  公开号：US20030171462A1

  公开（公告）日：2003-09-11

  Plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials are provided. More particularly, this invention relates to certain alkyl (or alkoxy) substituted fluoro-benzylidene sorbitol acetals and polymer compositions thereof which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive fluorinated and alkylated benzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.

  本发明提供了可用作成核剂的塑料添加剂，特别适用于改善聚合材料的光学性能。更具体地说，本发明涉及某些烷基（或烷氧基）取代的氟亚苄基山梨醇乙缩醛及其聚合物组合物，仅举几例，它们可用于食品或化妆品容器和包装。这些本发明的氟化和烷基化亚苄基山梨醇乙缩醛还可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的胶凝剂。
• Polymer additive compositions and articles comprising novel fluorinated and alkylated alditol derivatives
  申请人：——

  公开号：US20030181552A1

  公开（公告）日：2003-09-25

  Plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials are provided. More particularly, this invention relates to certain alkyl (or alkoxy) substituted fluorobenzylidene sorbitol acetals and polymer compositions thereof which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive fluorinated and alkylated benzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.

  本发明提供了可用作成核剂的塑料添加剂，特别适用于改善聚合材料的光学性能。更具体地说，本发明涉及某些烷基（或烷氧基）取代的氟亚苄基山梨醇缩醛及其聚合物组合物，仅举几例，这些聚合物组合物可用于食品或化妆品容器和包装。这些本发明的氟化和烷基化亚苄基山梨醇乙缩醛还可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的胶凝剂。