2,5,8,11-四甲基-3,6,9,12-四氧杂十六烷-1-醇 | 90971-84-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2,5,8,11-四甲基-3,6,9,12-四氧杂十六烷-1-醇
• 英文名称: 4-methoxypentan-2-ol
• 英文别名: 4-methoxy-pentan-2-ol
• CAS: 90971-84-9
• 化学式: C₆H₁₄O₂
• 分子量: 118.176
• InChiKey: GXVDVJQTXFTVMP-UHFFFAOYSA-N

物化性质

• 沸点：
  169.4±8.0 °C(Predicted)
• 密度：
  0.893±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,5,8,11-四甲基-3,6,9,12-四氧杂十六烷-1-醇 在 四氯化碳 、 magnesium 、 1,2-二溴乙烷 、 三苯基膦 作用下， 反应 0.17h， 生成
  参考文献：
  名称：

  Diastereoselective reactions of a simple secondary grignard reagent

  摘要：

  The stereoselective reactions of a simple acyclic Grignard reagent CH3CH(OR)CH2CH(CH3)MgX, 2, with several electrophiles are described.

  DOI：

  10.1016/s0040-4039(00)74117-7
• 作为产物：
  描述：

  碘甲烷 、 2,4-戊二醇 在 四丁基碘化铵 、 sodium hydride 作用下， 生成 2,5,8,11-四甲基-3,6,9,12-四氧杂十六烷-1-醇
  参考文献：
  名称：

  Diastereoselective reactions of a simple secondary grignard reagent

  摘要：

  The stereoselective reactions of a simple acyclic Grignard reagent CH3CH(OR)CH2CH(CH3)MgX, 2, with several electrophiles are described.

  DOI：

  10.1016/s0040-4039(00)74117-7

文献信息

• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ORGANIQUES ÉLECTROLUMINESCENTS ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT LES COMPRENANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2015099486A1

  公开（公告）日：2015-07-02

  The present invention relates to a novel organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent compound according to the present invention can be used in a light-emitting layer and has excellent luminescent efficiency; and an organic electroluminescent device comprising the organic electroluminescent compounds of the present invention has long lifespan, and improved current efficiency and power efficiency.

  本发明涉及一种新型有机电致发光化合物以及包括该化合物的有机电致发光器件。根据本发明的有机电致发光化合物可用于发光层，并具有优异的发光效率；而包括本发明的有机电致发光化合物的有机电致发光器件具有长寿命、改善的电流效率和功率效率。
• [EN] AN ORGANIC ELECTROLUMINESCENT COMPOUND AND AN ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉ ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE COMPRENANT CE COMPOSÉ
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2015178731A1

  公开（公告）日：2015-11-26

  The present invention relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. By using the organic electroluminescent compound according to the present invention, it is possible to produce an organic electroluminescent device having low driving voltage, excellent current and power efficiencies, and noticeably improved driving lifespan.

  本发明涉及一种有机电致发光化合物和包括该化合物的有机电致发光器件。通过使用本发明的有机电致发光化合物，可以制备出具有低驱动电压、优异电流和功率效率以及明显改善的驱动寿命的有机电致发光器件。
• Iodine/iodide-containing hot melt coatable adhesive, methods and uses therefor
  申请人：Wang Danli

  公开号：US20050202070A1

  公开（公告）日：2005-09-15

  An iodine/iodide-containing hot melt coatable adhesive is provided. This adhesive is prepared by mixing iodine and an iodide salt, individually or in combination, with solubilizing liquids. The iodine and iodide salt are combined with a pre-adhesive composition in a hot melt mixer, with an iodine/iodide complexing agent being present in the mixture. The mixture is mixed at a temperature from about 130° C. to about 200° C. and sufficiently to form an iodine/iodide-containing hot melt coatable adhesive. Alternatively, the iodide may be generated in situ. The adhesive so prepared may be packaged for coating on a substrate at a later time, or may be immediately coated to form an adhesive composite. Adhesive composites, particularly surgical incise drapes, are provided incorporating this hot melt coatable adhesive.

  提供了一种含碘/碘化物的热熔涂层粘合剂。该粘合剂是通过将碘和碘化物单独或组合与溶解液混合而制备的。碘和碘化物与预粘合剂组合在热熔混合器中，其中碘/碘化物络合剂存在于混合物中。混合物在温度从约130℃到约200℃之间混合足够长的时间，从而形成含碘/碘化物的热熔涂层粘合剂。或者，碘化物可以在原位生成。这样制备的粘合剂可以打包，以便在以后涂覆在基材上，也可以立即涂覆以形成粘合剂复合材料。提供了包含这种热熔涂层粘合剂的粘合剂复合材料，特别是外科手术切口防护膜。
• [EN] CRYSTALLINE HIGH DEGREE OF CONDENSATION TITANIUM-BASED INORGANIC-ORGANIC HYBRID SOLID MOF MATERIAL, METHOD FOR PREPARING SAME AND USES THEREOF<br/>[FR] MATÉRIAU MOF SOLIDE HYBRIDÉ INORGANIQUE-ORGANIQUE À BASE DE TITANE, AVEC UN DEGRÉ ÉLEVÉ DE CONDENSATION CRISTALLINE , SON PROCÉDÉ DE PRÉPARATION ET SES UTILISATIONS
  申请人：CENTRE NAT RECH SCIENT

  公开号：WO2017211923A1

  公开（公告）日：2017-12-14

  The present invention relates to a water-stable Titanium-based metal-organic framework (MOF) material having a high degree of condensation, i.e. an oxo to Ti ratio (or oxo to metal ratio, in the case of doped Ti-based MOFs) > 1.0; a process of preparing same and uses thereof, particularly for heterogeneously catalyzed chemical reactions, for gas storage/separation/purification, for information storage, laser printing or as an oxygen indicator, or as proton conductive material (fuel cells), optoelectronic material (photovoltaic cells including Grätzel cells), as a matrix for encapsulating active principles (medicaments, cosmetics), or else as sensing material.

  本发明涉及一种具有高度缩合度的水稳定的基于钛的金属有机框架（MOF）材料，即氧与钛的比例（或掺杂的基于钛的MOF中的氧与金属的比例）> 1.0；其制备方法和用途，特别是用于异相催化化学反应，气体储存/分离/净化，信息存储，激光打印或作为氧指示剂，或作为质子导电材料（燃料电池），光电材料（包括Grätzel电池的光伏电池），作为包埋活性成分（药物，化妆品）的基质，或作为传感材料。
• Process for preparing particles having monodisperse particle size
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0275899A2

  公开（公告）日：1988-07-27

  Disclosed is a process for preparing polymer particles having monodisperse particle size comprising:     adding a dispersion stabilizer, a polymerizable monomer and a polymerization initiator to an organic solvent to conduct polymerization, wherein said organic solvent has a solubility parameter (SP value) higher than that of the resultant polymer by at least 1.0 and said dispersion stabilizer is soluble in said organic solvent and has a free radical reactive group of 10⁻³ to 1 mmol/g; and     removing said organic solvent.

  公开了一种制备具有单分散粒度的聚合物颗粒的工艺，包括 将分散稳定剂、可聚合单体和聚合引发剂加入到有机溶剂中进行聚合，其中所述有机溶剂的溶解度参数（SP 值）比所得聚合物的溶解度参数（SP 值）至少高 1.0，且所述分散稳定剂可溶于所述有机溶剂，并具有 10-³ 至 1 mmol/g 的自由基活性基团；以及 去除所述有机溶剂。