2,5-双(氯甲基)-1,3-二硝基苯 | 177537-18-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,5-双(氯甲基)-1,3-二硝基苯
• 英文名称: 2,6-dinitro-1,4-di(chloromethyl)benzene
• 英文别名: 2,6-DINITRO 1,4-BIS(CHLOROMETHYL)BENZENE；Benzene, 2,5-bis(chloromethyl)-1,3-dinitro-；2,5-bis(chloromethyl)-1,3-dinitrobenzene
• CAS: 177537-18-7
• 化学式: C₈H₆Cl₂N₂O₄
• 分子量: 265.053
• InChiKey: UGYQECCNWCGABC-UHFFFAOYSA-N

物化性质

• 沸点：
  407.4±40.0 °C(Predicted)
• 密度：
  1.572±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  91.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,5-双(氯甲基)-1,3-二硝基苯 在 甲酸 、 水 、 potassium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以58%的产率得到(2,6-二硝基-1,4-亚苯基)二甲醇
  参考文献：
  名称：

  Synthesis and properties of new photosensitive triazene and o-nitrobenzene methacrylates

  摘要：

  New photoactive polymerizable monomers were synthesized in order to photomodulate the mechanical properties of photocurable materials. These monomers are end-capped by at least two polymerizable units (using irradiation wavelength lambda 1) connected by a spacer including at least one photocleavable unit (irradiation wavelength lambda 2 not equal lambda 1) i.e. aryltriazene or 2-nitrobenzyl core. The photochemical behaviour of these systems was studied in solution and in resin formulations. Their ability to promote the hardening and crosslinking of a curable resin at lambda 1, then the subsequent degradation or modification of crosslinked resins under an actinic light (lambda 2) was evaluated by DMA for formulations including these new monomers.These new monomers were shown, in resin formulation, to readily rigidify the material upon lambda 1 irradiation and for most of them the subsequent photolysis of their internal linkers at lambda 2 irradiation was followed by a decrease of the hardness at low temperature (-20 degrees C). For one of them (compound 6) lambda 2 illumination at room temperature provoked the decrease of the mechanical properties of the solid material making it of interest for dental applications. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2012.04.014
• 作为产物：
  描述：

  1,4-对二氯苄 在 硫酸 、 硝酸 作用下， 以 水 为溶剂， 反应 2.83h， 以70%的产率得到2,5-双(氯甲基)-1,3-二硝基苯
  参考文献：
  名称：

  Synthesis and properties of new photosensitive triazene and o-nitrobenzene methacrylates

  摘要：

  New photoactive polymerizable monomers were synthesized in order to photomodulate the mechanical properties of photocurable materials. These monomers are end-capped by at least two polymerizable units (using irradiation wavelength lambda 1) connected by a spacer including at least one photocleavable unit (irradiation wavelength lambda 2 not equal lambda 1) i.e. aryltriazene or 2-nitrobenzyl core. The photochemical behaviour of these systems was studied in solution and in resin formulations. Their ability to promote the hardening and crosslinking of a curable resin at lambda 1, then the subsequent degradation or modification of crosslinked resins under an actinic light (lambda 2) was evaluated by DMA for formulations including these new monomers.These new monomers were shown, in resin formulation, to readily rigidify the material upon lambda 1 irradiation and for most of them the subsequent photolysis of their internal linkers at lambda 2 irradiation was followed by a decrease of the hardness at low temperature (-20 degrees C). For one of them (compound 6) lambda 2 illumination at room temperature provoked the decrease of the mechanical properties of the solid material making it of interest for dental applications. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2012.04.014

文献信息

• Positive photoactive compounds based on 2,6-dinitro benzyl groups and
  申请人：PPG Industries, Inc.

  公开号：US05600035A1

  公开（公告）日：1997-02-04

  Photoreactive compounds are synthesized from 2,5- or 2,6-dintrobenzyl groups. Also disclosed are methods of synthesizing reactive monomers containing 2,5- or 2,6-dintrobenzyl groups.

  光敏化合物是由2,5-或2,6-二硝基苯基基团合成的。还公开了含有2,5-或2,6-二硝基苯基基团的反应单体的合成方法。
• POSITIVE PHOTOACTIVE COMPOUNDS BASED ON 2,6-DINITROBENZYL GROUPS
  申请人：PPG Industries Ohio, Inc.

  公开号：EP0770053B1

  公开（公告）日：1999-08-18
• US5600035A
  申请人：——

  公开号：US5600035A

  公开（公告）日：1997-02-04
• US5733479A
  申请人：——

  公开号：US5733479A

  公开（公告）日：1998-03-31
• US6100008A
  申请人：——

  公开号：US6100008A

  公开（公告）日：2000-08-08