3-(2H-Benzotriazol-2-yl)-5-(butan-2-yl)-4-hydroxybenzene-1-sulfonic acid

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-(2H-Benzotriazol-2-yl)-5-(butan-2-yl)-4-hydroxybenzene-1-sulfonic acid
• 英文别名: 3-(benzotriazol-2-yl)-5-butan-2-yl-4-hydroxybenzenesulfonic acid
• 化学式: C₁₆H₁₇N₃O₄S
• 分子量: 347.4
• InChiKey: RUFMFWSJTRYOPL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  114
• 氢给体数：
  2
• 氢受体数：
  6

文献信息

• STABILIZATION OF HOUSEHOLD, BODY-CARE AND FOOD PRODUCTS BY USING BENZOTROPOLONE CONTAINING PLANT EXTRACTS AND/OR RELATED BENZOTROPOLONE DERIVATIVES
  申请人：Wagner Barbara

  公开号：US20120230925A1

  公开（公告）日：2012-09-13

  Disclosed is the use of benzotropolone derivatives of formula (1), wherein R 1 , R 2 and R 7 independently from each other are hydrogen; C 1 -C 3 alkyl; or COR 8 ; R 3 is hydrogen; or COOR 9 R 4 is hydrogen; or C 1 -C 3 alkyl; R 5 is hydrogen; hydroxy; C 1 -C 3 -alkoxy; or -0-(CO)—R 10 ; R 6 is hydrogen; C 1 -C 3 alkyl; or COR 8 ; or R 5 and R 6 together may form a five or six membered ring; or R 6 and R 7 together form a five or six membered ring; and R 8 , R 9 , R 10 independently of each other are C 1 -C 30 alkyl; for protecting body-care and household products from photolytic and oxidative degradation.

  本发明涉及一种使用化学式（1）中的苯并三酮衍生物的方法，其中R1、R2和R7分别独立地为氢原子；C1-C3烷基；或COR8；R3为氢原子；或COOR9；R4为氢原子；或C1-C3烷基；R5为氢原子；羟基；C1-C3-烷氧基；或-0-(CO)—R10；R6为氢原子；C1-C3烷基；或COR8；或R5和R6可以共同形成五元或六元环；或R6和R7可以共同形成五元或六元环；且R8、R9、R10分别独立地为C1-C30烷基；用于保护身体护理和家用产品免受光解和氧化降解的方法。
• Inhibition of pulp and paper yellowing using hydroxylamines and other coadditives
  申请人：——

  公开号：US20020174964A1

  公开（公告）日：2002-11-28

  Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a N,N-dialkylhydroxylamine, an ester, amide or thio item substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine or an amminium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. N,N-Diethylhydroxylamine and N,N-dibenzylhydroxylamine and their acid salts are surprisingly effective for this purpose.

  含有木质素的纸浆或纸张，尤其是化学机械或热机械纸浆或纸张，如果它们含有有效稳定剂量的N,N-二烷基羟胺、酯、酰胺或硫代物取代的N,N-二烷基羟胺或N,N-二苄基羟胺或其铵盐，它们具有增强的抗黄变性能。当它们与紫外线吸收剂、聚合抑制剂、亚硝基化合物、荧光增白剂和金属螯合剂等共添加剂之一或多个存在时，这种性能通常会进一步增强。N,N-二乙基羟胺和N,N-二苄基羟胺及其酸盐对此具有惊人的有效性。羟胺或其盐、苯并三唑或苯并酚紫外线吸收剂和金属螯合剂的组合特别有效。
• Chlorohydrin and cationic compounds having high affinity for pulp or paper
  申请人：Cunkle T. Glen

  公开号：US20050092452A1

  公开（公告）日：2005-05-05

  Selected chlorohydrin and cationic compounds containing nitroxide or hydroxylamine moieties are effective in stabilizing pulp or paper, especially pulp or paper containing lignin, against yellowing and discoloration due to the adverse effects of light. These compounds are added at various points in the paper-making process, especially at the wet ends, making the need for water soluble or water dispersible materials having high affinity for pulp or paper essential. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective.

  选择的含氮氧自由基或羟胺基团的氯水合物和阳离子化合物对于稳定纸浆或纸张，特别是含有木质素的纸浆或纸张，抵御光的不良影响导致的黄变和变色非常有效。这些化合物在造纸过程的各个阶段添加，特别是在湿端，需要具有高亲和力的水溶性或水分散材料是必不可少的。这种性能通常通过存在于紫外线吸收剂、聚合物抑制剂、亚硝基、荧光增白剂和金属螯合剂等组中选择一个或多个共添加剂来进一步增强。羟胺或其盐、苯并三唑或苯并酮紫外线吸收剂和金属螯合剂的组合特别有效。
• Ink jet ink and recording material
  申请人：——

  公开号：US20040126510A1

  公开（公告）日：2004-07-01

  The present invention relates to an ink jet ink, an ink jet recording material or an ink jet system comprising at least one sterically hindered N-hydroxylamine strong acid salt, for example 1-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium chloride or bis(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate dihydrochloride; or comprising at least one dialkyl N-hydroxylamine salt, for example chloride, bisulfate, sulfate, phosphate, nitrate, ascorbate, formate, acetate, benzoate, oxalate, citrate, a carboxylate of ethylenediaminetetraacetic acid or of diethylenetriaminepentaacetic acid or polyacrylate salts of N,N-diethylhydroxylamine, N,N-bis(2-hydroxypropyl)hydroxylamine, N,N-bis(3-hydroxypropyl)hydroxylamine, N,N-dibenzylhydroxylamine or the N,N-di(alkyl)hydroxylamine produced by the direct oxidation of N,N-di(hydrogenated tallow)amine.

  本发明涉及一种喷墨墨水、喷墨记录材料或喷墨系统，其包含至少一种立体位阻的N-羟胺强酸盐，例如1-羟基-2,2,6,6-四甲基-4-羟基哌啶盐酸盐或双(1-羟基-2,2,6,6-四甲基哌啶-4-基)癸二酸二盐酸盐；或包含至少一种双烷基N-羟胺盐，例如氯化物、硫酸氢盐、硫酸盐、磷酸盐、硝酸盐、抗坏血酸盐、甲酸盐、乙酸盐、苯甲酸盐、草酸盐、柠檬酸盐、乙二胺四乙酸或二乙三胺五乙酸的羧酸盐或N,N-二乙基羟胺、N,N-双(2-羟基丙基)羟胺、N,N-双(3-羟基丙基)羟胺、N,N-二苄基羟胺或通过N,N-二(氢化牛脂)胺的直接氧化产生的N,N-二(烷基)羟胺。
• INHIBITION OF PULP AND PAPER YELLOWING USING HYDROXYLAMINES AND OTHER COADDITIVES
  申请人：——

  公开号：US20020088574A1

  公开（公告）日：2002-07-11

  Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a N,N-dialkylhydroxylamine, an ester, amide or thio substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine or an amminium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. N,N-Diethylhydroxylamine and N,N-dibenzylhydroxylamine and their acid salts are surprisingly effective for this purpose.

  含有木质素的纸浆或纸张，特别是化学机械或热机械纸浆或纸张，如果它们含有有效稳定量的N,N-二烷基羟胺，酯，酰胺或硫代取代的N,N-二烷基羟胺或N,N-二苄基羟胺或其铵盐，则具有增强的抗黄变性能。当其中还存在来自紫外线吸收剂，聚合抑制剂，亚硝基，荧光增白剂和金属螯合剂的一种或多种辅助剂时，这种性能通常会进一步增强。羟胺或其盐，苯并三唑或苯并酚紫外线吸收剂和金属螯合剂的组合特别有效。N,N-二乙基羟胺和N,N-二苄基羟胺及其酸盐出人意料地有效。