2-(2H-苯并三唑-2-基)-4,6-二-叔-辛基苯酚 | 70693-49-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 2-(2H-苯并三唑-2-基)-4,6-二-叔-辛基苯酚
• 英文名称: 2-(2-hydroxy-3,5-di-tert-octylphenyl)-2H-benzotriazole
• 英文别名: Phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1,3,3-tetramethylbutyl)-；2-(benzotriazol-2-yl)-4,6-bis(2,4,4-trimethylpentan-2-yl)phenol
• CAS: 70693-49-1
• 化学式: C₂₈H₄₁N₃O
• 分子量: 435.653
• InChiKey: XDNLOGRBAYJSMQ-UHFFFAOYSA-N

物化性质

• 沸点：
  525.4±60.0 °C(Predicted)
• 密度：
  1.01±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  50.9
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  Phenol, 2-((2-nitrophenyl)azo)-4,6-bis(1,1,3,3-tetramethylbutyl)- 、 甲苯 、 sodium hydroxide 、 盐酸 在 锌 氮气 作用下， 以 水 、 异丙醇 为溶剂， 反应 21.0h， 生成 2-(2H-苯并三唑-2-基)-4,6-二-叔-辛基苯酚
  参考文献：
  名称：

  2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole stabilized

  摘要：

  2-[2-羟基-3,5-二叔丁基苯基]-2H-苯并三唑在保护有机基质免受光引起的恶化方面表现出卓越的功效，同时在稳定组合物高温加工过程中具有良好的耐挥发或渗出性能。

  公开号：

  US04477614A1

文献信息

• Processes for the preparation of benzotriazole UV absorbers
  申请人：——

  公开号：US20020035175A1

  公开（公告）日：2002-03-21

  Provided is a process for preparing 2H-benzotriazole UV absorbers containing a perfluoroalkyl moiety at the 5-position of the benzo ring, for example a trifluoromethyl group, which involves diazotizing the perfluoroalkyl substituted o-nitroaniline using concentrated sulfuric acid plus sodium nitrite or nitrosylsulfuric acid to form the corresponding monoazobenzene intermediate via the diazonium salt intermediate which is reduced to the corresponding 5-perfluoroalkyl substituted 2H-benzotriazole UV absorber compound by conventional reduction means. Also provided is a novel one-pot, multiphase reaction for the preparation of 2(2-nitrophenylazo) substituted phenols, which are precursors for 2H-benzotriazole UV absorbers.

  提供了一种制备在苯环的5位含有全氟烷基基团（例如三氟甲基基团）的2H-苯并三唑紫外吸收剂的方法，该方法涉及使用浓硫酸加硝酸钠或亚硝基硫酸制备全氟烷基取代的邻硝基苯胺，以形成相应的单氮偶联苯中间体，通过传统还原手段将二氮盐中间体还原为相应的5-全氟烷基取代的2H-苯并三唑紫外吸收剂化合物。还提供了一种用于制备2(2-硝基苯基偶氮)取代酚的新型一锅多相反应，这些化合物是2H-苯并三唑紫外吸收剂的前体。
• Ultraviolet light absorbing ketones of 2-(2-Hydroxyphenyl) benzotriazole
  申请人：Chang Chia-Hu

  公开号：US20100086500A1

  公开（公告）日：2010-04-08

  The invention relates to ultraviolet light absorbing compounds, their preparation and uses as protective agents and stabilizers in coatings, plastics and topically applied products. The compounds are ketone derivatives of 2-(2-hydroxyphenol) benzotriazole of formula I, where R 1 is hydrogen atom, or a halogen atom, or a straight-chain or branched lower alkyl or lower alkoxy of 1 to 4 carbon atoms; R 2 is an unsubtituted or substituted aryl group or an unsubstituted or substituted straight-chain or branched alkyl having 1 to 18 carbon atoms or a cycloaliphatic group having 5 to 6 carbon atoms; and R 3 is a straight-chain or branched alkyl or alkylaryl group or alkoxyl or phenyl or phenyl substituted with alkyl, cycloalkyl, carboalkoxy, chlorine or arylalkyl groups.

  本发明涉及紫外线吸收化合物，它们的制备以及在涂料、塑料和局部应用产品中作为保护剂和稳定剂的用途。该化合物是式I中的2-(2-羟基苯基)苯并三唑的酮衍生物，其中R1是氢原子、卤素原子、1至4个碳原子的直链或支链低级烷基或低级烷氧基；R2是未取代或取代的芳基基团或未取代或取代的1至18个碳原子的直链或支链烷基或5至6个碳原子的环烷基团；R3是直链或支链烷基或烷基芳基基团或烷氧基或苯基或被烷基、环烷基、羧基烷氧基、氯或芳基烷基基团取代的苯基。
• 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole stabilized
  申请人：Ciba-Geigy Corporation

  公开号：US04477614A1

  公开（公告）日：1984-10-16

  2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions.

  2-[2-羟基-3,5-二叔丁基苯基]-2H-苯并三唑在保护有机基质免受光引起的恶化方面表现出卓越的功效，同时在稳定组合物高温加工过程中具有良好的耐挥发或渗出性能。
• 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-Benzotriazole and stabilized
  申请人：Ciba-Geigy Corporation

  公开号：US04278590A1

  公开（公告）日：1981-07-14

  2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions. The combination of the benzotriazole UV absorber with a hindered amine light stabilizer is particularly efficacious in protecting thermoset and thermoplastic acrylic resin automotive finishes and enamels.

  2-[2-羟基-3,5-二叔丁基苯基]-2H-苯并三唑在保护有机基质免受光引起的恶化方面表现出杰出的功效，同时在稳定组合物高温处理期间具有良好的抗挥发或渗出性能。苯并三唑紫外线吸收剂与受阻胺类光稳定剂的组合特别有效，可保护热固性和热塑性丙烯酸树脂汽车涂料和珐琅的表面。
• 2-(2-Hydroxy-3,5-di-tert-octylphenyl)-2H-benzotriazole stabilized
  申请人：Ciba-Geigy Corporation

  公开号：US04283327A1

  公开（公告）日：1981-08-11

  2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole exhibits outstanding efficacy in protecting organic substrates from light induced deterioration as well as good resistance to loss by volatilization or exudation during the high temperature processing of stabilized compositions.

  2-[2-羟基-3,5-二叔丁基苯基]-2H-苯并三唑在保护有机基质免受光诱导劣化方面表现出卓越的功效，同时在稳定组合物高温加工过程中具有良好的抗挥发或渗出损失能力。