2-(4-溴-4-联苯基)萘 | 861212-66-0

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-(4-溴-4-联苯基)萘
• 英文名称: 2-(4'-bromo-1,1'-biphenyl-4-yl)naphthalene
• 英文别名: 2-(4′-bromo-[1,1′]biphenyl-4-yl)naphthalene；2-(4′-bromobiphenyl-4-yl)naphthalene；2-(4'-bromo-biphenyl-4-yl)naphthalene；2-[4-(4-Bromophenyl)phenyl]naphthalene
• CAS: 861212-66-0
• 化学式: C₂₂H₁₅Br
• 分子量: 359.265
• InChiKey: KWCQSYNZPAMUOW-UHFFFAOYSA-N

物化性质

• 熔点：
  232-237 °C
• 沸点：
  512.3±19.0 °C(Predicted)
• 密度：
  1.329±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-(4-溴-4-联苯基)萘 、 4-氨基联苯 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以60%的产率得到4,4'-bis[4-(2-naphthyl)phenyl]-4''-phenyltriphenylamine
  参考文献：
  名称：

  覆盖层用有机化合物及包含其的有机发光器件

  摘要：

  本发明涉及覆盖层用化合物及包含其的有机发光器件，本发明的一实例的覆盖层用化合物适用于有机发光器件，可提高有机发光器件的外部发光效率、色坐标及寿命。

  公开号：

  CN111995530A
• 作为产物：
  描述：

  2-溴萘 、 4,4'-二溴联苯 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 叔丁基锂 、 indium(III) chloride 作用下， 以 正戊烷 、 四氢呋喃 、 乙醚 为溶剂， 反应 19.0h， 以68%的产率得到2-(4-溴-4-联苯基)萘
  参考文献：
  名称：

  Synthesis and Characterization of Polyaromatic Compounds Using Tri(naphthyl)indium

  摘要：

  A variety of polyaromatic compounds beating 1- and 2-naphthyl groups were prepared from the reactions of corresponding halides with tri(1- and 2-naphthyl)indium in good to excellent yields. Thermal, photophysical and electrochemical behaviors of carbazoles having naphthyl groups were studied. They have shown to be promising host and hole transporting materials in organic electroluminescence due to their high thermal stability, electrochemical reversibility and wide band gap.

  DOI：

  10.1021/jo800438n

文献信息

• COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20210253546A1

  公开（公告）日：2021-08-19

  Provided is an organic electroluminescent element comprising a compound that is represented by formula (1) and having a more improved lifetime. (In the formula, X, R1-R8, R11-R17, R21-R30, L1, L2, n, and Ar1-Ar3 are as defined in the description.)

  提供的是一种有机电致发光元件，包括一个由式（1）表示的化合物，并具有更长的寿命。（在该式中，X、R1-R8、R11-R17、R21-R30、L1、L2、n 和 Ar1-Ar3 的定义如描述中所定义。）
• NAPHTHALENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE, AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kawamura Masahiro

  公开号：US20090008607A1

  公开（公告）日：2009-01-08

  A naphthalene derivative represented by the following formula (1) is provided. In the formula (1), Ar 1 and Ar 2 each represent an aromatic hydrocarbon cyclic group having 6 to 18 carbon atoms forming a ring. The aromatic hydrocarbon cyclic group has none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. Ar 3 represents a benzene skeleton or a naphthalene skeleton. R 1 and R 2 each represent an alkyl group, a cycloalkyl group, an alkoxy group, a cyano group, a silyl group or a halogen atom. a and b each represent an integer in a range of 0 to 4. m and n each represent an integer in a range of 1 to 4.

  提供以下式子（1）所表示的萘衍生物。在式子（1）中，Ar1和Ar2分别代表具有6到18个碳原子形成环的芳香族碳氢循环基团。芳香族碳氢循环基团中不含蒽骨架、芘骨架、乙烯基蒽骨架和萘并蒽骨架。Ar3代表苯骨架或萘骨架。R1和R2分别代表烷基、环烷基、烷氧基、氰基、硅烷基或卤素原子。a和b分别代表0到4范围内的整数。m和n分别代表1到4范围内的整数。
• Naphthalene derivative, material for organic electroluminescence device, and organic electroluminescence device using the same
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US08034256B2

  公开（公告）日：2011-10-11

  A naphthalene derivative represented by the following formula (1) is provided. In the formula (1), Ar1 and Ar2 each represent an aromatic hydrocarbon cyclic group having 6 to 18 carbon atoms forming a ring. The aromatic hydrocarbon cyclic group has none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. Ar3 represents a benzene skeleton or a naphthalene skeleton. R1 and R2 each represent an alkyl group, a cycloalkyl group, an alkoxy group, a cyano group, a silyl group or a halogen atom. a and b each represent an integer in a range of 0 to 4. m and n each represent an integer in a range of 1 to 4.

  提供一种由以下公式（1）表示的萘衍生物。在公式（1）中，Ar1和Ar2分别表示具有6到18个碳原子形成环的芳香族碳氢循环基团。 芳香族碳氢循环基团不包含蒽骨架，芘骨架，苯并蒽骨架和萘并蒽骨架。Ar3表示苯骨架或萘骨架。R1和R2分别表示烷基，环烷基，烷氧基，氰基，硅烷基或卤素原子。a和b分别表示0到4范围内的整数。m和n分别表示1到4范围内的整数。
• PHENANTHRENE DERIVATIVE, AND MATERIAL FOR ORGANIC EL ELEMENT
  申请人：Kawamura Masahiro

  公开号：US20100327230A1

  公开（公告）日：2010-12-30

  A phenanthrene derivative is represented by a formula (1) below. In the formula (1), Ar 1 to Ar 4 each represent an aromatic hydrocarbon ring group having 6 to 18 carbon atoms for forming the ring. The aromatic hydrocarbon ring group contains none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. L represents a single bond, a substituted or unsubstituted benzene skeleton, naphthalene skeleton, biphenylene skeleton, fluorene skeleton, phenanthrene skeleton, fluoranthene skeleton, triphenylene skeleton, chrysene skeleton, phenyl-naphthalene skeleton or binaphthalene skeleton. R 1 and R 2 each represent a substituent, the number of which may be 0, 1 or more. R 1 and R 2 may be bonded in any positions of the phenanthrene skeleton. m, n, l and p each represent 0 or 1 while satisfying m+n+l+p≧1 (m,n≧l,p). a and b each represent an integer of 0 to 8.

  一个菲咯烷衍生物由下式（1）表示。在式（1）中，Ar1到Ar4分别表示具有6到18个碳原子的芳香族碳氢环基团，用于形成环。芳香族碳氢环基团不包含蒽醌骨架、芘骨架、蝰蛇醌骨架和萘醌骨架。L表示单键，取代或未取代的苯骨架、萘骨架、联苯骨架、芴骨架、菲咯烷骨架、芴芘骨架、三联苯骨架、花菖蒲骨架、苯基-萘骨架或二萘骨架。R1和R2各表示一个取代基，其数量可以为0、1或更多。R1和R2可以连接在菲咯烷骨架的任何位置。m、n、l和p各表示0或1，同时满足m+n+l+p≥1（m，n≥l，p）。a和b各表示0到8的整数。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING THE SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1950194A1

  公开（公告）日：2008-07-30

  Provided are: a novel aromatic amine derivative having an asymmetric structure; and an organic electroluminescence device having one or multiple organic thin film layers including at least a light emitting layer, the one or multiple organic thin film layers being interposed between a cathode and an anode. The aromatic amine derivative realizes the organic EL device capable of suppressing the crystallization of a molecule, improving yields upon production of the organic EL device, and having a long lifetime when at least one layer of the one or more multiple organic thin film layers contains the aromatic amine derivative alone or as a component of a mixture.

  本发明提供了：一种具有不对称结构的新型芳香胺衍生物；以及一种有机电致发光器件，该器件具有一个或多个有机薄膜层，其中至少包括一个发光层，该一个或多个有机薄膜层位于阴极和阳极之间。芳香胺衍生物使有机电致发光器件能够抑制分子结晶，提高有机电致发光器件的产量，并且当一个或多个有机薄膜层中的至少一层单独含有芳香胺衍生物或作为混合物的成分时，具有较长的使用寿命。