3-methyl-pentadec-1-yn-3-ol | 101433-91-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-methyl-pentadec-1-yn-3-ol
• 英文别名: 3-Methyl-pentadec-1-in-3-ol；3-Methylpentadec-1-yn-3-ol
• CAS: 101433-91-4
• 化学式: C₁₆H₃₀O
• 分子量: 238.414
• InChiKey: YWAZTRHBPXOSHC-UHFFFAOYSA-N

物化性质

• 沸点：
  270.4±8.0 °C(Predicted)
• 密度：
  0.870±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-methyl-pentadec-1-yn-3-ol 生成 3-甲基十五碳-1-烯-3-醇
  参考文献：
  名称：

  Weichet et al., Collection of Czechoslovak Chemical Communications, 1957, vol. 22, p. 587,591

  摘要：

  DOI：
• 作为产物：
  描述：

  十三酰氯 在 乙醚 、 氨 作用下， 生成 3-methyl-pentadec-1-yn-3-ol
  参考文献：
  名称：

  Weichet et al., Collection of Czechoslovak Chemical Communications, 1957, vol. 22, p. 587,591

  摘要：

  DOI：

文献信息

• METHOD OF HYDROSILYLATION IMPLEMENTING AN ORGANIC CATALYST DERIVED FROM GERMYLENE
  申请人：BLUESTAR SILICONES FRANCE SAS

  公开号：US20170313729A1

  公开（公告）日：2017-11-02

  The present invention concerns a method for the hydrosilylation of an unsaturated compound comprising at least one ketone function, one aldehyde function, one alkene function and/or one alkyne function, with a compound comprising at least one hydrogen-silyl function implementing an organic catalyst of tri-coordinated germanium.

  本发明涉及一种用于水硅烷基化不饱和化合物的方法，所述不饱和化合物包括至少一个酮基功能、一个醛基功能、一个烯烃功能和/或一个炔烃功能，与至少一个含有氢硅基功能的化合物反应，使用三配位的有机催化剂锗实施。
• NOVEL CATALYSTS HAVING A SILENE LIGAND
  申请人：BLUESTAR SILICONES FRANCE SAS

  公开号：US20160145283A1

  公开（公告）日：2016-05-26

  A subject matter of the present invention is the use as catalyst, in particular in hydrosilylation, of a metal complex including at least one metal atom chosen from the metals of Groups 8, 9 and 10 of the Periodic Table of the Elements and one or more ligands, characterized in that at least one ligand includes a silene structure.

  本发明的一个主题是将金属络合物用作催化剂，特别是在氢硅烷化反应中，所述金属络合物包括来自元素周期表第8、9和10族金属中至少一种金属原子和一个或多个配体，其特点在于至少一个配体包括硅烯结构。
• NOVEL CATALYSTS WITH A SILYLENE LIGAND
  申请人：BLUESTAR SILICONES FRANCE SAS

  公开号：US20160159830A1

  公开（公告）日：2016-06-09

  A metal complex including at least one metal atom chosen from the metals of Groups 8, 9 and 10 of the Periodic Table of the Elements and one or more ligands, wherein at least one ligand includes a cyclic silylene structure and a Lewis base which donates an electron pair to the silicon atom of the cyclic silylene structure.

  一个金属配合物，包括来自元素周期表第8、9和10族金属中至少一个金属原子和一个或多个配体，其中至少一个配体包括一个环状硅烯结构和一个路易斯碱，该碱向环状硅烯结构的硅原子捐赠一个电子对。
• COMPOSITION, APPARATUS, KIT AND METHOD AND USES THEREOF
  申请人：Smith & Nephew plc

  公开号：EP3574876A1

  公开（公告）日：2019-12-04

  A curable composition for use in wound care comprising, apportioned between at least one Part A and at least one Part B: one or more alkenyl-group containing polymers (i) having at least one alkenyl group or moiety per molecule, one or more SiH-containing polymers (ii) having at least one Si-H unit per molecule; and a catalyst (iii) for curing by addition of alkenyl-containing polymer (i) to SiH-containing polymer (ii), Part A and Part B independently having viscosity at 23°C in the range 5 - 300 Pa.s, preferably 10 - 100 Pa.s, at a shearing rate of 10 s-1, and when combined in one Part having cure time at 23° C in the range from 0.5 min to 25 min,, wherein when dispensed into a location about a wound dressing, said wound dressing overlying a wound site and skin thereabout, said dispensing being so as to intimately contact and overlie an edge of said dressing and skin about said edge, the composition cures in contact with said edge and skin at 32° C to an elastomer exhibiting zero or low tack at a time in the range from 0.5 to less than 30 minutes, apparatus for use with said composition comprising dispensing apparatus or wound dressing, a kit comprising the same, and methods of dispensing and curing the same and of using the same in sealing a wound dressing and in treating a wound site of a human in need thereof.

  一种用于伤口护理的可固化组合物，包括至少一个 A 部分和至少一个 B 部分： 一种或多种含烯基的聚合物(i)，每个分子中至少有一个烯基、 一种或多种含 SiH 的聚合物 (ii)，每个分子至少有一个 Si-H 单元；以及 催化剂 (iii)，用于将含烯基的聚合物 (i) 添加到含 SiH 的聚合物 (ii) 中进行固化，A 部分和 B 部分在 23°C，剪切速率为 10 s-1 时的粘度范围分别为 5 - 300 Pa.s，最好为 10 - 100 Pa.s，当合并为一个部分时，23°C 固化时间范围为 0.5 分钟至 25 分钟、 其中，当分配到伤口敷料周围的位置时，所述伤口敷料覆盖在伤口部位及其周围的皮肤上，所述分配是为了紧密接触和覆盖所述敷料的边缘和所述边缘周围的皮肤，所述组合物在 32° C 温度下与所述边缘和皮肤接触固化成弹性体，显示出零粘性或低粘性，固化时间在 0.5至小于30分钟的时间内固化为显示零粘性或低粘性的弹性体；与所述组合物一起使用的装置，包括分配装置或伤口敷料；包括上述组合物的套件；以及分配和固化上述组合物的方法，以及使用上述组合物密封伤口敷料和治疗有需要的人的伤口部位的方法。
• Method of hydrosilylation implementing an organic catalyst derived from germylene
  申请人：BLUESTAR SILICONES FRANCE SAS

  公开号：US10442825B2

  公开（公告）日：2019-10-15

  The present invention concerns a method for the hydrosilylation of an unsaturated compound comprising at least one ketone function, one aldehyde function, one alkene function and/or one alkyne function, with a compound comprising at least one hydrogen-silyl function implementing an organic catalyst of tri-coordinated germanium.

  本发明涉及一种不饱和化合物的氢硅烷化方法，该化合物包含至少一个酮官能团、一个醛官能团、一个烯官能团和/或一个炔官能团，通过三配位锗有机催化剂与包含至少一个氢硅烷官能团的化合物进行氢硅烷化。