4,5-dipentylpyridazine | 1613714-15-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 4,5-dipentylpyridazine
• 英文别名: 4,5-Dipentylpyridazine
• CAS: 1613714-15-0
• 化学式: C₁₄H₂₄N₂
• 分子量: 220.358
• InChiKey: DSSLFKLNRSJDCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  五羰基氯铼(I) 、 4,5-dipentylpyridazine 以 甲苯 为溶剂， 反应 2.0h， 生成 Re2(μ-Cl)₂(CO)₆(μ-4,5-dipentylpyridazine)
  参考文献：
  名称：

  Diazine bridged dinuclear rhenium complex: New molecular material for the CO2 conversion

  摘要：

  The conversion of carbon dioxide into chemical fuels is a topic of great interest and recently a lot of different approaches for the electrochemical reduction of this powerful greenhouse gas to more useful products have been reported. We report here for the first time the activity of a dinuclear Re(I) complex [Re-2(mu-Cl)(2)(CO)(6)(mu-diazine)] towards the electrocatalytic reduction of carbon dioxide. It is herein reported its electrochemical characterization in highly aprotic conditions (CH3CN) with a comparison with the analogue mononuclear Re(I) complex, [Re(bpy)(CO)(3)(Cl)]. The dinuclear complex exhibits good performances (TOF0 = 25 h (1)), two times higher than the analogous mononuclear one. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.12.023
• 作为产物：
  描述：

  1,2,4,5-四嗪 、 6-十二炔 以 1,4-二氧六环 为溶剂， 反应 24.0h， 生成 4,5-dipentylpyridazine
  参考文献：
  名称：

  Diazine bridged dinuclear rhenium complex: New molecular material for the CO2 conversion

  摘要：

  The conversion of carbon dioxide into chemical fuels is a topic of great interest and recently a lot of different approaches for the electrochemical reduction of this powerful greenhouse gas to more useful products have been reported. We report here for the first time the activity of a dinuclear Re(I) complex [Re-2(mu-Cl)(2)(CO)(6)(mu-diazine)] towards the electrocatalytic reduction of carbon dioxide. It is herein reported its electrochemical characterization in highly aprotic conditions (CH3CN) with a comparison with the analogue mononuclear Re(I) complex, [Re(bpy)(CO)(3)(Cl)]. The dinuclear complex exhibits good performances (TOF0 = 25 h (1)), two times higher than the analogous mononuclear one. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.12.023

文献信息

• Diazine bridged dinuclear rhenium complex: New molecular material for the CO2 conversion
  作者：Giovanni Valenti、Monica Panigati、Alessandro Boni、Giuseppe D’Alfonso、Francesco Paolucci、Luca Prodi

  DOI：10.1016/j.ica.2013.12.023

  日期：2014.6

  The conversion of carbon dioxide into chemical fuels is a topic of great interest and recently a lot of different approaches for the electrochemical reduction of this powerful greenhouse gas to more useful products have been reported. We report here for the first time the activity of a dinuclear Re(I) complex [Re-2(mu-Cl)(2)(CO)(6)(mu-diazine)] towards the electrocatalytic reduction of carbon dioxide. It is herein reported its electrochemical characterization in highly aprotic conditions (CH3CN) with a comparison with the analogue mononuclear Re(I) complex, [Re(bpy)(CO)(3)(Cl)]. The dinuclear complex exhibits good performances (TOF0 = 25 h (1)), two times higher than the analogous mononuclear one. (C) 2014 Elsevier B.V. All rights reserved.