trimethylolpropane tri(2-methylpropanoate) | 14253-02-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: trimethylolpropane tri(2-methylpropanoate)
• 英文别名: trimethylpropane triisobutyrate；EtC(iBu)3；2,2-Bis(2-methylpropanoyloxymethyl)butyl 2-methylpropanoate
• CAS: 14253-02-2
• 化学式: C₁₈H₃₂O₆
• 分子量: 344.448
• InChiKey: QZIYADTUCLUVIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  24
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  78.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  三甲基氯硅烷 、 trimethylolpropane tri(2-methylpropanoate) 在 正丁基锂 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 生成 1,1,1-tris[2-methyl-1-(trimethylsilyloxy)prop-1-enyloxymethyl]propane
  参考文献：
  名称：

  Core-First Synthesis of Three-, Four-, and Six-Armed Star-Shaped Poly(methyl methacrylate)s by Group Transfer Polymerization Using Phosphazene Base

  摘要：

  The core-first synthesis of three-, four-, and six-armed star-shaped poly(methyl methacrylate)s (PMMAs) with predicted molecular weights and narrow molecular weight distributions (M-w/M(n)s) was carried out by the t-BuP4-catalyzed group transfer polymerization (GTP) of methyl methacrylate (MMA) using the newly designed silyl enolates, such as 1,1,1-tris[2-methyl-1-(trimethylsilyloxy)prop-1-enyloxymethyl]propane (E(C(MTS)(3)), tetrakis{[2-niethyl-1-(trimethylsilyloxy)prop-1-enyloxy]methyl}methane (C(MTS)(4)), and bis{2,2,2-tris[2,methyl-1-(trimethylsilyloxy)prop-1-enyloxy]ethyl}ether (O-(C(MTS)(3))(2)), respectively. The absolute molecular weight (M-w(MALS)) of the obtained polymers proportionally increased with the increasing [MMA](0)/[initiator](0) ratio, and the highest molecular weight was ca. 132 kg mol(-1). Characterizations for the star-shaped PMMAs were conducted by cleavage and intrinsic viscosity [eta] experiments. Cleavage experiments of the star-shaped PMMAs provided the evidence for homogeneous growth of the each arm in the t-Bu-P-4-catalyzed GTP. The number of arm determined from the shrinking factors (g') of [eta] also supported the successful syntheses of the star-shaped polymers by the present core-first method. The versatility of this core-first method toward other methacrylic monomers was confirmed by the t-BuP4-catalyzed GTPs of allyl methacrylate (AMA), stearyl methacrylate (SMA), and 2-(dimethylamino)ethyl methacrylate (DMAEMA) using C(MTS)(4) as an initiator leading to well-defined star-shaped polymers.

  DOI：

  10.1021/ma202103d
• 作为产物：
  描述：

  2,2-二甲基丁烷 、 异丁酸 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以72%的产率得到trimethylolpropane tri(2-methylpropanoate)
  参考文献：
  名称：

  一种三羟甲基丙烷异丁酸酯增塑剂的制备及其在PVC中的应用

  摘要：

  本发明公开了一种三羟甲基丙烷异丁酸酯增塑剂及其制备方法，将该增塑剂应用于PVC中，在添加量为40%‑60%PVC重量的添加比例下制备的共混膜，相对于相同添加比例市售对苯二甲酸二辛酯制备的PVC共混膜，表现出优异的力学性能及在有机溶剂正己烷介质中低的迁移率。

  公开号：

  CN108395375A

文献信息

• Characteristics of retention and enthalpies of sorption from the gas phase of esters of trimethylolpropane and С2–С5 acids on DB-1 stationary phase
  作者：E. L. Krasnykh、A. Yu. Aleksandrov、A. A. Sokolova、S. V. Levanova

  DOI：10.1134/s0036024417020194

  日期：2017.2

  along with the thermodynamic characteristics of sorption on DB-1 nonpolar phase, are determined in the temperature range of 220–280°C for 21 mono-, di-, and trisubstituted esters of trimethylolpropane and monobasic acids with a variety of structures containing from 2 to 6 carbon atoms.

  在220–280°C的温度范围内，对21种三羟甲基丙烷和一元酸的单，二和三取代酯确定了保留特性及其温度依赖性以及DB-1非极性相上吸附的热力学特性。具有2至6个碳原子的各种结构。
• Stabilizer for thiol-ene compositions
  申请人：Allnex Belgium, S.A.

  公开号：EP2878613A1

  公开（公告）日：2015-06-03

  The present invention relates to stabilizers for thiol-ene compositions and to radiation curable thiol-ene compositions based thereon. Such radiation curable compositions can advantageously be used in inks, coatings, adhesives, for the making of 3D objects and for the making of solder resist and gel nails. Provided in particular is an inhibitor system (I) for thiol-ene compositions based on - at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, - at least one acidic compound (ii) having a pKa between 1 and 3, and - at least one compound (iii) selected from the group consisting of phosphites and phosphonites, with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring. Also provided is an inhibitor system (II) for thiol-ene compositions based on that is based on - at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, - at least one compound (iv) selected from the group consisting of spirophosphites, and - optionally, at least one acidic compound (ii) having a pKa between 1 and 3, and with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring.

  本发明涉及硫醇-烯组合物的稳定剂以及以其为基础的辐射固化硫醇-烯组合物。这种可辐射固化的组合物可以很好地用于油墨、涂料、粘合剂、三维物体的制造以及阻焊剂和凝胶钉的制造。 本发明特别提供了一种用于硫醇-烯组合物的抑制剂体系 (I)，该体系基于 - 至少一种抑制剂化合物 (i)，其 DPPH 自由基清除活性至少为 90%，该抑制剂化合物 (i) 选自取代的苯化合物或取代的萘化合物，其中至少含有两个取代基，这两个取代基选自由羟基和 C1-C3 烷氧基组成的组，直接与苯环或萘环键合、 - 至少一种酸性化合物 (ii)，其 pKa 值介于 1 和 3 之间，以及 - 至少一种选自亚磷酸盐和亚膦酸盐的化合物 (iii) 膦酸盐、 但如果抑制剂化合物 (i) 是取代苯，则至少含有两个直接键合在苯环上的羟基。 还提供了一种用于硫醇-烯组合物的抑制剂体系 (II)，该体系基于以下条件 - 至少一种抑制剂化合物 (i)，其 DPPH 自由基清除活性至少为 90%，该抑制剂化合物 (i) 选自取代的苯化合物或取代的萘化合物，其中至少含有两个取代基，这两个取代基选自由羟基和直接与苯环或萘环键合的 C1-C3 烷氧基组成的组、 - 至少一种选自由亚硫基膦组成的组的化合物 (iv)，以及 - 可选地，至少一种 pKa 在 1 和 3 之间的酸性化合物 (ii)，以及 但如果抑制剂化合物 (i) 是取代苯，则至少含有两个直接与苯环键合的羟基。
• REFRIGERATION MACHINE OIL, COMPOSITION FOR REFRIGERATION MACHINES, AND COMPRESSION-TYPE REFRIGERATION MACHINE
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP3351611A1

  公开（公告）日：2018-07-25

  The refrigerator oil of the present invention contains an oxygen-containing base oil and a viscosity index improver, and has a viscosity index (VI) of 200 or more and a volume resistivity of 1 × 109 Ω·m or more.

  本发明的冷冻机油含有含氧基础油和粘度指数改进剂，其粘度指数（VI）为 200 或以上，体积电阻率为 1 × 109 Ω-m 或以上。
• HIGHLY FUNCTIONALIZED RESIN BLENDS
  申请人：HENKEL US IP LLC

  公开号：US20140221573A1

  公开（公告）日：2014-08-07

  The present invention relates to multi-functional polymeric resin blends which have a defined average molecular weight distribution. Additionally each polymeric component of the blend has a polydispersity of from about 1.01 to about 2.50, The average functionality of the blend is from about 1.8 to about 4.0. More particularly, the present invention relates to poly(meth)acrylates having three or more functional groups. These highly functionalized resin blends are desirably prepared using controlled free radical polymerization techniques, such as single electron transfer living radical polymerization (SET-LRP) processes to produce a variety of blended resin systems which have tailored and enhanced properties.
• STABILIZER FOR THIOL-ENE COMPOSITIONS
  申请人：Allnex Belgium S.A.

  公开号：US20170022414A1

  公开（公告）日：2017-01-26

  The present invention relates to stabilizers for thiol-ene compositions and to radiation curable thiol-ene compositions based thereon. Such radiation curable compositions can advantageously be used in inks, overprint varnishes, coatings, adhesives, for the making of 3D objects and for the making of solder resist and gel nails. Provided in particular is an inhibitor system (I) for thiol-ene compositions based on —at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, —at least one acidic compound (ii) having a pKa between 1 and 3, and —at least one compound (iii) selected from the group consisting of phosphites and phosphonites, with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring. Also provided is an inhibitor system (II) for thiol-ene compositions based on that is based on —at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, —at least one compound (iv) selected from the group consisting of spirophosphites, and —optionally, at least one acidic compound (ii) having a pKa between 1 and 3, and with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring.