1-cyclohexyl-2-hydroxy-2-methyl-propan-1-one | 1127-40-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-cyclohexyl-2-hydroxy-2-methyl-propan-1-one
• 英文别名: 1-Cyclohexyl-2-hydroxy-2-methyl-propan-1-on；1-Cyclohexyl-2-methyl-2-hydroxy-propanon-(1)；1-Cyclohexyl-2-hydroxy-2-methylpropan-1-one
• CAS: 1127-40-8
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: KTYOVFDWYUQIRA-UHFFFAOYSA-N

物化性质

• 沸点：
  97-98 °C(Press: 11 Torr)
• 密度：
  0.9764 g/cm3(Temp: 0 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-cyclohexyl-2-hydroxy-2-methyl-propan-1-one 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 生成 1-cyclohexyl-2-methylpropane-1,2-diol
  参考文献：
  名称：

  Rouzaud,J. et al., Bulletin de la Societe Chimique de France, 1964, p. 2908 - 2916

  摘要：

  DOI：
• 作为产物：
  描述：

  1-环己基-2-甲基丙烷-1-酮 在 氢氧化钾 、 磺酰氯 作用下， 以 乙醇 为溶剂， 生成 1-cyclohexyl-2-hydroxy-2-methyl-propan-1-one
  参考文献：
  名称：

  Rouzaud,J. et al., Bulletin de la Societe Chimique de France, 1964, p. 2908 - 2916

  摘要：

  DOI：

文献信息

• PROCESS FOR THE PRODUCTION OF LIVING (CO)POLYMERS AND USE OF THE (CO)POLYMERS
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1266910A1

  公开（公告）日：2002-12-18

  The purpose of the present invention is to provide polymerization catalyst which can produce quite efficiently (co)polymer having number average molecular weight and number of molecules which are accurately controlled in producing method of (co)polymer by the polymerization of polar unsaturated compound, and provide living polymerized (co)polymer obtained according to the producing method. For the purpose, polymerization catalyst composition which comprises the composition comprising organic oxysalt compound and hydroxycarbonyl compound having at least both an alcoholic hydroxyl group and a carbonyl group in the same molecule is provided and the polar unsaturated compound is polymerized by using the polymerization catalyst composition. The composition containing the obtained (co)polymer were able to provide thermosetting powder coating composition having particularly excellent characteristics.

  本发明的目的是提供一种聚合催化剂，该催化剂可在通过极性不饱和化合物聚合生产 （共）聚合物的方法中相当有效地生产具有精确控制的平均分子量数和分子数的（共）聚合 物，并提供根据该生产方法获得的活聚合（共）聚合物。为此，提供了聚合催化剂组合物，该组合物由有机草酸盐化合物和羟基羰基化合物组成，羟基羰基化合物在同一分子中至少具有醇羟基和羰基，使用该聚合催化剂组合物对极性不饱和化合物进行聚合。含有所获得的（共）聚合物的组合物能够提供具有特别优异特性的热固性粉末涂料组合物。
• CELLULOSE ACETATE FILM, AND POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY DEVICE WHICH ARE MADE USING SAME
  申请人：Konica Minolta Advanced Layers, Inc.

  公开号：EP2565228A1

  公开（公告）日：2013-03-06

  Provided is a cellulose acetate film which has excellent retardation properties and exhibits low haze even under high-temperature and high-humidity conditions and which, in an alkaline saponification step, causes little dissolution of the film itself or additives in a saponifying liquid. The cellulose acetate film is characterized by comprising: a cellulose acetate which has an acetyl substitution degree of 2.0 to 2.5; and 5 to 15% by mass (relative to the cellulose acetate) of a component which contains a compound represented by general formula (1) wherein m is 0 and a compound represented thereby wherein m is more than 0 at a ratio of 45:55 to 0:100. In general formula (1), G is a mono- or di-saccharide residue; X1 is -O-; R1 is -CO-R2; R2 is an aliphatic or aromatic group; m represents the total number of hydroxyl groups directly bonded to the mono- or di-saccharide residue; and n represents the total number of OR1 groups directly bonded to the mono- or di-saccharide residue, with the proviso that m and n satisfy the relationships: 3 ≤ m+n ≤ 8 and n is not 0.

  本发明提供了一种醋酸纤维素薄膜，它具有优异的缓凝性能，即使在高温高湿条件下也能表现出较低的雾度，而且在碱性皂化步骤中，薄膜本身或添加剂在皂化液中的溶解度很小。醋酸纤维素薄膜的特征在于：醋酸纤维素的乙酰取代度为 2.0 至 2.5；以及 5%至 15%（相对于醋酸纤维素质量）的组分，该组分包含通式（1）所代表的化合物，其中 m 为 0，以及通式（1）所代表的化合物，其中 m 大于 0，两者的比例为 45:55 至 0:100。在通式(1)中，G 是单糖或二糖残基；X1 是-O-；R1 是-CO-R2；R2 是脂肪族或芳香族基团；m 代表直接键合在单糖或二糖残基上的羟基总数；n 代表直接键合在单糖或二糖残基上的 OR1 基团总数，但 m 和 n 满足以下关系：3≤m+n≤8 且 n 不为 0。
• Process for the production of living (co)polymers and use of the (co)polymers
  申请人：——

  公开号：US20030023003A1

  公开（公告）日：2003-01-30

  The purpose of the present invention is to provide polymerization catalyst which can produce quite efficiently (co)polymer having number average molecular weight and number of molecules which are accurately controlled in producing method of (co)polymer by the polymerization of polar unsaturated compound, and provide living polymerized (co)polymer obtained according to the producing method. For the purpose, polymerization catalyst composition which comprises the composition comprising organic oxysalt compound and hydroxycarbonyl compound having at least both an alcoholic hydroxyl group and a carbonyl group in the same molecule is provided and the polar unsaturated compound is polymerized by using the polymerization catalyst composition. The composition containing the obtained (co)polymer were able to provide thermosetting powder coating composition having particularly excellent characteristics.

  本发明的目的是提供一种聚合催化剂，该催化剂可在通过极性不饱和化合物聚合生产 （共）聚合物的方法中相当有效地生产具有精确控制的平均分子量数和分子数的（共）聚合 物，并提供根据该生产方法获得的活聚合（共）聚合物。为此，提供了聚合催化剂组合物，该组合物由有机草酸盐化合物和羟基羰基化合物组成，羟基羰基化合物在同一分子中至少具有醇羟基和羰基，使用该聚合催化剂组合物对极性不饱和化合物进行聚合。含有所获得的（共）聚合物的组合物能够提供具有特别优异特性的热固性粉末涂料组合物。
• Elphimoff-Felkin,I.; Verrier,M., Bulletin de la Societe Chimique de France, 1967, p. 1047 - 1052
  作者：Elphimoff-Felkin,I.、Verrier,M.

  DOI：——

  日期：——
• Elphimoff-Felkin,I.; Verrier,M., Bulletin de la Societe Chimique de France, 1967, p. 1052 - 1057
  作者：Elphimoff-Felkin,I.、Verrier,M.

  DOI：——

  日期：——