2-(三氟甲基)-3-乙氧基十二氟己烷 | 297730-93-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-(三氟甲基)-3-乙氧基十二氟己烷
• 中文别名: 电子氟化液NOVEC7500
• 英文名称: HFE-7500
• 英文别名: 2-trifluoromethyl-3-ethoxydodecafluorohexane；3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-(trifluoromethyl)hexane；3-Ethoxyperfluoro(2-methylhexane)；4-ethoxy-1,1,1,2,2,3,3,4,5,6,6,6-dodecafluoro-5-(trifluoromethyl)hexane
• CAS: 297730-93-9
• 化学式: C₉H₅F₁₅O
• 分子量: 414.114
• InChiKey: HHBBIOLEJRWIGU-UHFFFAOYSA-N

物化性质

• 熔点：
  -100°C
• 沸点：
  130°C
• 密度：
  1,61 g/cm3
• 溶解度：
  可溶于氯仿、甲醇（微量）
• LogP：
  6 at 23℃

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  16

安全信息

• TSCA：
  T
• 危险等级：
  IRRITANT
• 危险品标志：
  Xi
• 安全说明：
  S23,S24/25

文献信息

• [EN] FLUORINATED SILYLETHYNYL PENTACENE COMPOUNDS AND COMPOSITIONS AND METHODS OF MAKING AND USING THE SAME<br/>[FR] COMPOSÉS ET COMPOSITIONS DE PENTACÈNE DE SILYLÉTHYNYLE FLUORÉ ET LEURS PROCÉDÉS DE PRÉPARATION ET D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2010138807A1

  公开（公告）日：2010-12-02

  Fluorinated silylethynyl pentacenes and compositions containing fluorinated silylethynyl pentacenes are disclosed. Methods of making and using fluorinated silylethynyl pentacenes and compositions containing fluorinated silylethynyl pentacenes are also disclosed.

  本文揭示了氟硅基乙炔基五环戊二烯和含有氟硅基乙炔基五环戊二烯的组合物。还公开了制备和使用氟硅基乙炔基五环戊二烯以及含有氟硅基乙炔基五环戊二烯的组合物的方法。
• [EN] FLUORINATED COUMARINS<br/>[FR] COUMARINES FLUORÉES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2021124032A1

  公开（公告）日：2021-06-24

  Described herein is fluorinated dye comprising: a fluorescing coumarin-derived moiety connected to an oligomer of hexafluoropropylene oxide via a non-fluorinated divalent linking group. Such fluorinated dyes are soluble in fluorinated fluids and may be used to detect leaks in various systems such as refrigerant, air conditioning and/or heat transfer systems.

  本文描述了一种氟化染料，包括：通过非氟化双价连接基连接到六氟丙烯氧寡聚物的荧光香豆素衍生物。这种氟化染料在氟化流体中溶解，可用于检测各种系统中的泄漏，如制冷剂、空调和/或热传递系统。
• DIAZIRINE COMPOUNDS AND COMPOSITIONS DERIVED THEREFROM
  申请人：PROMERUS, LLC

  公开号：US20160083352A1

  公开（公告）日：2016-03-24

  A series of diazirine compounds of formula (I) having utility as photocrosslinkers are disclosed. Where, A, L, z, Ar x and R y are as defined herein. Also disclosed are the photodefinable compositions containing these compounds.

  揭示了一系列具有光交联剂作用的二氮烯化合物的化学式（I），其中A、L、z、Arx和Ry的定义如本文所述。还揭示了含有这些化合物的光可定义组合物。
• [EN] MICROFLUIDIC PRODUCTION OF BIOFUNCTIONALIZED GIANT UNILAMELLAR VESICLES FOR TARGETED CARGO DELIVERY<br/>[FR] PRODUCTION MICROFLUIDIQUE DE VÉSICULES UNILAMELLAIRES GÉANTES BIOFONCTIONNALISÉES POUR UNE DISTRIBUTION DE CHARGE CIBLÉE
  申请人：MAX PLANCK GESELLSCHAFT

  公开号：WO2021123399A1

  公开（公告）日：2021-06-24

  The present invention relates to a method for preparation of monodisperse cell- targeting giant unilamellar vesicles based on symmetrically division of a parent polymer shell-stabilized giant unilamellar vesicle into smaller polymer shell- stabilized giant unilamellar vesicles with a diameter between 1 µm and 10 µm using a microfluidic splitting device. The inventive method allows preparation of differently charged giant unilamellar vesicles as well as bioligand- and PEG-conjugated giant unilamellar vesicles, which are useful for targeted cellular delivery at high efficiency and specificity. A further advantage of the present invention is that the giant unilamellar vesicles can deliver huge cargos such as drug releasing porous microparticles, high amounts of in vivo imaging probes, viruses, or up-and-coming DNA origami robots.

  本发明涉及一种制备单分散细胞靶向巨大单层泡囊的方法，该方法基于将母体聚合物壳稳定的巨大单层泡囊对称分裂成直径在1微米至10微米之间的较小聚合物壳稳定的巨大单层泡囊，使用微流体分裂装置。这种创新的方法允许制备带有不同电荷的巨大单层泡囊，以及生物配体和PEG共轭的巨大单层泡囊，这对于高效和特异性的靶向细胞传递非常有用。本发明的另一个优点是，巨大单层泡囊可以传递大量的货物，例如释放药物的多孔微粒、大量体内成像探针、病毒或即将推出的DNA折纸机器人。
• Orthogonal Procesing of Organic Materials Used in Electronic and Electrical Devices
  申请人：Ober Christopher K.

  公开号：US20110159252A1

  公开（公告）日：2011-06-30

  An orthogonal process for photolithographic patterning organic structures is disclosed. The disclosed process utilizes fluorinated solvents or supercritical CO 2 as the solvent so that the performance of the organic conductors and semiconductors would not be adversely affected by other aggressive solvent. One disclosed method may also utilize a fluorinated photoresist together with the HFE solvent, but other fluorinated solvents can be used. In one embodiment, the fluorinated photoresist is a resorcinarene, but various fluorinated polymer photoresists and fluorinated molecular glass photoresists can be used as well. For example, a copolymer perfluorodecyl methacrylate (FDMA) and 2-nitrobenzyl methacrylate (NBMA) is a suitable orthogonal fluorinated photoresist for use with fluorinated solvents and supercritical carbon dioxide in a photolithography process. The combination of the fluorinated photoresist and the fluorinated solvent provides a robust, orthogonal process that is yet to be achieved by methods or devices known in the art.

  本文介绍了一种用于光刻有机结构的正交工艺。该工艺利用氟化溶剂或超临界CO2作为溶剂，以使有机导体和半导体的性能不受其他侵蚀性溶剂的不利影响。其中一种方法还可以使用氟化光阻与HFE溶剂结合使用，但也可以使用其他氟化溶剂。在一种实施例中，氟化光阻是一种二苯并呋喃酮，但也可以使用各种氟化聚合物光阻和氟化分子玻璃光阻。例如，一种共聚物全氟癸基甲基丙烯酸酯（FDMA）和2-硝基苯甲酸甲酯（NBMA）是用于与氟化溶剂和超临界二氧化碳在光刻工艺中使用的适用于正交的氟化光阻。氟化光阻和氟化溶剂的组合提供了一种强大的正交工艺，这种工艺尚未被已知的方法或设备实现。