9-[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-9H-carbazole | 1425657-06-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-9H-carbazole
• 英文别名: 9-[3-(9-Phenylfluoren-9-yl)phenyl]carbazole；9-[3-(9-phenylfluoren-9-yl)phenyl]carbazole
• CAS: 1425657-06-2
• 化学式: C₃₇H₂₅N
• 分子量: 483.612
• InChiKey: YEDHTLQJDBFDHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  38
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-(3-溴苯基)-9-苯基-9H-芴 、 咔唑 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 、 正己烷 为溶剂， 反应 5.0h， 以46%的产率得到9-[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-9H-carbazole
  参考文献：
  名称：

  Phosphorescent organometallic iridium complex, light-emitting element, light-emitting device, electronic device, and lighting device

  摘要：

  作为一种具有新颖骨架的新型物质，提供了一种新型磷光有机金属铱配合物，可以在蓝绿至红色波长区域发射磷光，并具有高发射效率。该磷光有机金属铱配合物具有具有吡啶基嘧啶骨架的配体，即该磷光有机金属铱配合物具有由以下一般式（G0）表示的结构的配体。请注意，在该式中，R1和R4至R6分别表示氢或具有1至6个碳原子的烷基基团；R2和R3分别表示氢、具有1至6个碳原子的烷基基团、可能具有取代基的苯基团和可能具有取代基的吡啶基团中的任何一个。

  公开号：

  US08889858B2

文献信息

• Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Novel Organic Compound
  申请人：Takeda Kyoko

  公开号：US20130048964A1

  公开（公告）日：2013-02-28

  A light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a LUMO level of greater than or equal to −3.5 eV and less than or equal to −2.5 eV, and the second compound is an organic compound having a pyrimidine skeleton. The light-emitting element includes an EL layer between a pair of electrodes. The EL layer contains a first compound and a second compound. The first compound is a phosphorescent iridium metal complex having a diazine skeleton, and the second compound is an organic compound having a pyrimidine skeleton.

  一种发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是一种具有大于或等于-3.5电子伏特且小于或等于-2.5电子伏特的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。发光元件包括两个电极之间的EL层。EL层包含第一化合物和第二化合物。第一化合物是具有嘧啶骨架的荧光铱金属配合物，第二化合物是具有嘧啶骨架的有机化合物。
• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20160254461A1

  公开（公告）日：2016-09-01

  An organometallic complex that has high emission efficiency and high heat resistance and emits blue light is provided as a novel substance. In a light-emitting element including a light-emitting layer between a pair of electrodes, the light-emitting layer includes an organometallic complex, and the organometallic complex includes a central metal and two types of ligands coordinated to the central metal. One of the two types of ligands includes a triazole skeleton including nitrogen bonded to the central metal, and the other includes a nitrogen-containing five-membered heterocyclic skeleton including carbene carbon bonded to the central metal and nitrogen bonded to carbene carbon.

  提供一种具有高发射效率和高耐热性并发出蓝光的有机金属配合物作为一种新型物质。在包括在一对电极之间的发光层的发光元件中，该发光层包括一种有机金属配合物，该有机金属配合物包括一个中心金属和两种与中心金属配位的配体。这两种配体中的一种包括一个三唑骨架，其中氮与中心金属键合，另一种包括一个含氮的五元杂环骨架，其中碳卡宾与中心金属键合，碳卡宾上的氮与中心金属键合。
• Phosphorescent organometallic iridium complex, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US08889858B2

  公开（公告）日：2014-11-18

  As a novel substance having a novel skeleton, provided is a novel phosphorescent organometallic iridium complex that can emit phosphorescence in a blue green to red wavelength region and has high emission efficiency. The phosphorescent organometallic iridium complex has a ligand having a pyridyl pyrimidine skeleton, i.e., the phosphorescent organometallic iridium complex has a ligand having a structure represented by the following general formula (G0). Note that in the formula, R1 and R4 to R6 separately represent hydrogen or an alkyl group having 1 to 6 carbon atoms; and R2 and R3 separately represent any of hydrogen, an alkyl group having 1 to 6 carbon atoms, a phenyl group that may have a substituent, and a pyridyl group that may have a substituent.

  作为一种具有新颖骨架的新型物质，提供了一种新型磷光有机金属铱配合物，可以在蓝绿至红色波长区域发射磷光，并具有高发射效率。该磷光有机金属铱配合物具有具有吡啶基嘧啶骨架的配体，即该磷光有机金属铱配合物具有由以下一般式（G0）表示的结构的配体。请注意，在该式中，R1和R4至R6分别表示氢或具有1至6个碳原子的烷基基团；R2和R3分别表示氢、具有1至6个碳原子的烷基基团、可能具有取代基的苯基团和可能具有取代基的吡啶基团中的任何一个。
• COMPOUND, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210061753A1

  公开（公告）日：2021-03-04

  A novel compound represented by formula (G1) is provided. In formula (G1), A represents a substituted or unsubstituted condensed aromatic ring having 10 to 30 carbon atoms or a substituted or unsubstituted condensed heteroaromatic ring having 10 to 30 carbon atoms, and Z 1 to Z 3 each independently have a structure represented by formula (Z-1) or (Z-2). In formula (Z-1), X 1 and X 2 each independently represent any one of an alkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a cycloalkyl group having a bridge structure and having 7 to 10 carbon atoms, and a trialkylsilyl group having 3 to 12 carbon atoms. In addition, Ar 1 to Ar 4 each independently represent a substituted or unsubstituted aromatic hydrocarbon group having 6 to 13 carbon atoms, and at least one of Ar 1 to Ar 4 has the same substituent as X 1 or X 2 .

  提供了一种由公式（G1）表示的新化合物。在公式（G1）中，A代表具有10到30个碳原子的取代或未取代的紧缩芳香环或具有10到30个碳原子的取代或未取代的紧缩杂环，Z1至Z3各自独立具有由公式（Z-1）或（Z-2）表示的结构。在公式（Z-1）中，X1和X2各自独立地表示具有3到10个碳原子的烷基，具有3到10个碳原子的取代或未取代的环烷基，具有7到10个碳原子的桥式环烷基和具有3到12个碳原子的三烷基硅基中的任何一种。此外，Ar1到Ar4各自独立地表示具有6到13个碳原子的取代或未取代的芳香烃基，并且Ar1到Ar4中至少有一个具有与X1或X2相同的取代基。
• Light-Emitting Element, Display Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20170092890A1

  公开（公告）日：2017-03-30

  To provide a light-emitting element with high emission efficiency and low driving voltage. The light-emitting element includes a guest material and a host material. A HOMO level of the guest material is higher than a HOMO level of the host material. An energy difference between the LUMO level and a HOMO level of the guest material is larger than an energy difference between the LUMO level and a HOMO level of the host material. The guest material has a function of converting triplet excitation energy into light emission. An energy difference between the LUMO level of the host material and the HOMO level of the guest material is larger than or equal to energy of light emission of the guest material.

  提供一种具有高发射效率和低驱动电压的发光元件。该发光元件包括客体材料和主体材料。客体材料的HOMO能级高于主体材料的HOMO能级。客体材料的LUMO能级和HOMO能级之间的能量差大于主体材料的LUMO能级和HOMO能级之间的能量差。客体材料具有将三重激发能转化为光发射的功能。主体材料的LUMO能级和客体材料的HOMO能级之间的能量差大于或等于客体材料的光发射能量。