5,6,9,10-tetrakis(heptyloxy)-1,3-diphenyl-2H-cyclopenta[l]phenanthren-2-one | 1426954-31-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 5,6,9,10-tetrakis(heptyloxy)-1,3-diphenyl-2H-cyclopenta[l]phenanthren-2-one
• 英文别名: 5,6,9,10-Tetraheptoxy-1,3-diphenylcyclopenta[l]phenanthren-2-one；5,6,9,10-tetraheptoxy-1,3-diphenylcyclopenta[l]phenanthren-2-one
• CAS: 1426954-31-5
• 化学式: C₅₇H₇₄O₅
• 分子量: 839.212
• InChiKey: WTZXIGAGKULQAU-UHFFFAOYSA-N

物化性质

• 沸点：
  914.3±65.0 °C(predicted)
• 密度：
  1.09±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  17.5
• 重原子数：
  62
• 可旋转键数：
  30
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.49
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-己基-1H-吡咯-2,5-二酮 、 5,6,9,10-tetrakis(heptyloxy)-1,3-diphenyl-2H-cyclopenta[l]phenanthren-2-one 以 二氯甲烷 为溶剂， 反应 0.5h， 以83%的产率得到
  参考文献：
  名称：

  Fluorogenic Diels–Alder reactions of novel phencyclone derivatives

  摘要：

  With the aim of obtaining fluorogenic Diels-Alder reactions, novel phencyclone derivatives were synthesized. In a short time and under convenient reaction conditions, the formation of Diels-Alder adducts was observed by color-change and up to 33-fold enhancement of fluorescence. The modification of thymidine and deoxycytidine derivatives with a maleimide side chain and their usage in fluorogenic Diels-Alder reaction is also reported. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.01.095
• 作为产物：
  描述：

  1,2-bis-(3,4-diheptoxyphenyl)ethanedione 在 三氟代氧化钒(V) 、 三氟化硼乙醚 、 potassium hydroxide 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 2.0h， 生成 5,6,9,10-tetrakis(heptyloxy)-1,3-diphenyl-2H-cyclopenta[l]phenanthren-2-one
  参考文献：
  名称：

  Fluorogenic Diels–Alder reactions of novel phencyclone derivatives

  摘要：

  With the aim of obtaining fluorogenic Diels-Alder reactions, novel phencyclone derivatives were synthesized. In a short time and under convenient reaction conditions, the formation of Diels-Alder adducts was observed by color-change and up to 33-fold enhancement of fluorescence. The modification of thymidine and deoxycytidine derivatives with a maleimide side chain and their usage in fluorogenic Diels-Alder reaction is also reported. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.01.095

文献信息

• Fluorogenic Diels–Alder reactions of novel phencyclone derivatives
  作者：Engin Aytac Aydin、Hans-Josef Altenbach

  DOI：10.1016/j.tetlet.2013.01.095

  日期：2013.4

  With the aim of obtaining fluorogenic Diels-Alder reactions, novel phencyclone derivatives were synthesized. In a short time and under convenient reaction conditions, the formation of Diels-Alder adducts was observed by color-change and up to 33-fold enhancement of fluorescence. The modification of thymidine and deoxycytidine derivatives with a maleimide side chain and their usage in fluorogenic Diels-Alder reaction is also reported. (C) 2013 Elsevier Ltd. All rights reserved.