9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde | 888031-87-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde
• 英文别名: poly(9-(2,3-epoxypropyl)-3-formylcarbazole)；9-(Oxiran-2-ylmethyl)carbazole-3-carbaldehyde
• CAS: 888031-87-6
• 化学式: C₁₆H₁₃NO₂
• 分子量: 251.285
• InChiKey: YQSRRYRLQCWPQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde 在 sodium acetate 、 三乙胺 作用下， 以 甲醇 、 丁酮 为溶剂， 反应 26.0h， 生成 4,4'-di({3-[(2,2-diphenylhydrazine-1-ylidene)methyl]carbazole-9-yl}-2-hydroxypropylsulfanyl)diphenylsulfane
  参考文献：
  名称：

  Glass-forming hole-transporting carbazole-based hydrazone monomers, polymers, and twin compounds

  摘要：

  The synthesis, optical. thermal, and photoelectrical properties of new carbazole-based hydrazone monomers, polymers, and twin compounds are reported. All the synthesized materials are capable of glass formation. Their glass transition temperatures range from 27 to 90 degrees C. The ionization potentials of the films of carbazole-based hydrazones measured by the electron photoemission technique range from 5.18 to 5.48 eV. Hole-drift mobilities in the amorphous films of the synthesized hydrazone monomers measured by the time-of-flight technique at room temperature reach 10(-4) cm(2)/(V s) at high applied electric fields. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2009.10.008
• 作为产物：
  描述：

  9-(环氧-2-甲基)-9H-咔唑 在 盐酸 、 copper(ll) sulfate pentahydrate 、 四丁基硫酸氢铵 、 potassium hydroxide 、 三氯氧磷 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 91.0h， 生成 9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde
  参考文献：
  名称：

  Glass-forming hole-transporting carbazole-based hydrazone monomers, polymers, and twin compounds

  摘要：

  The synthesis, optical. thermal, and photoelectrical properties of new carbazole-based hydrazone monomers, polymers, and twin compounds are reported. All the synthesized materials are capable of glass formation. Their glass transition temperatures range from 27 to 90 degrees C. The ionization potentials of the films of carbazole-based hydrazones measured by the electron photoemission technique range from 5.18 to 5.48 eV. Hole-drift mobilities in the amorphous films of the synthesized hydrazone monomers measured by the time-of-flight technique at room temperature reach 10(-4) cm(2)/(V s) at high applied electric fields. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2009.10.008

文献信息

• Charge transport materials having a nitrogen-containing-heterocycle hydrazone group
  申请人：Lygaitis Ramunas

  公开号：US20060177750A1

  公开（公告）日：2006-08-10

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula: where E comprises a functional group selected from the group consisting of a reactive ring group, an ethylenically unsaturated group, a hydrazone group, and an azine group; R 1 , R 2 , and R 3 comprise, each independently, H or an organic group; X is a bond or a linking group, with the proviso that when E comprises a reactive ring group, X is a linking group; and Y is a nitrogen-containing aromatic heterocyclic group; and (b) a charge generating compound.

  改进的有机光感受器包括一个电导基底和位于电导基底上的光电导元件，该光电导元件包括：(a) 具有以下化学式的电荷传输材料：其中 E 包括从反应性环基团、乙烯不饱和基团、腙基团和偶氮基团中选择的官能团；R1、R2 和 R3 分别独立地表示 H 或有机基团；X 是键或连接基团，但当 E 包括反应性环基团时，X 是连接基团；Y 是含氮芳香杂环基团；以及 (b) 一个电荷生成化合物。
• Poly(hydrazone)-based charge transport materials
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：EP1584987B1

  公开（公告）日：2007-06-20
• US7291433B2
  申请人：——

  公开号：US7291433B2

  公开（公告）日：2007-11-06
• US7364825B2
  申请人：——

  公开号：US7364825B2

  公开（公告）日：2008-04-29
• Glass-forming hole-transporting carbazole-based hydrazone monomers, polymers, and twin compounds
  作者：Egle Juskelyte、Ramunas Lygaitis、Gintaras Buika、Jolita Ostrauskaite、Dalius Gudeika、Juozas Vidas Grazulevicius、Vygintas Jankauskas

  DOI：10.1016/j.reactfunctpolym.2009.10.008

  日期：2010.2

  The synthesis, optical. thermal, and photoelectrical properties of new carbazole-based hydrazone monomers, polymers, and twin compounds are reported. All the synthesized materials are capable of glass formation. Their glass transition temperatures range from 27 to 90 degrees C. The ionization potentials of the films of carbazole-based hydrazones measured by the electron photoemission technique range from 5.18 to 5.48 eV. Hole-drift mobilities in the amorphous films of the synthesized hydrazone monomers measured by the time-of-flight technique at room temperature reach 10(-4) cm(2)/(V s) at high applied electric fields. (C) 2009 Elsevier Ltd. All rights reserved.