2-(全氟-7-甲基辛基)甲基丙烯酸乙酯 | 15166-00-4

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-(全氟-7-甲基辛基)甲基丙烯酸乙酯
• 中文别名: 1H,1H,2H,2H-全氟-9-甲基癸烷羟丙酯
• 英文名称: 3,3,4,4,5,5,6,6,7,7,8,8,9,10,10,10-Hexadecafluoro-9-(trifluoromethyl)decyl methacrylate
• 英文别名: [3,3,4,4,5,5,6,6,7,7,8,8,9,10,10,10-hexadecafluoro-9-(trifluoromethyl)decyl] 2-methylprop-2-enoate
• CAS: 15166-00-4
• 化学式: C₁₅H₉F₁₉O₂
• 分子量: 582.2
• InChiKey: KTPONRIHDUNNPD-UHFFFAOYSA-N

物化性质

• 沸点：
  116 °C6 mm Hg(lit.)
• 密度：
  1.629 g/mL at 25 °C(lit.)
• 闪点：
  >230 °F

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  36
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  21

安全信息

• 危险品标志：
  F,Xi
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 安全说明：
  S26,S36

文献信息

• Functionalized Photoreactive Compounds
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20080274304A1

  公开（公告）日：2008-11-06

  The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式(I)的官能化光反应化合物，特别适用于液晶对准材料。由于在特定分子系统中的不饱和键直接连接到两个不饱和环系统上附加了一个电子受体基团，因此在包含本发明的这些官能化光反应化合物的材料中可以实现异常高的光敏性、优异的对准性能以及良好的机械稳健性。
• [EN] CYANOSTILBENES<br/>[FR] CYANOSTILBÈNES
  申请人：ROLIC AG

  公开号：WO2014191292A1

  公开（公告）日：2014-12-04

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及一种新型化合物，特别适用于用于光学或电光应用的从材料，尤其是液晶的定向，特别是光定向，如安全应用、液晶器件或光学或电光薄膜。
• Telechelic polymers containing reactive functional groups
  申请人：Chung Tze-Chiang

  公开号：US20050182208A1

  公开（公告）日：2005-08-18

  Telechelic polymers having two reactive functional groups at the same polymer chain end are disclosed. These polymers can be prepared by combining a cycloborane initiator, at least one free radical polymerizable monomer and oxygen to form a polymer segment having a borane residue at one end of the polymer segment resulting from the cycloborane initiator; and converting the borane residue to at least two functional groups to form the telechelic polymer.

  公开了具有两个反应性功能基团的末端聚合物的电荷。这些聚合物可以通过将环硼烷引发剂，至少一个自由基聚合单体和氧气组合形成具有硼烷残基的聚合物片段的一端，从而在聚合物片段的一端形成硼烷残基；并将硼烷残基转化为至少两个功能基团以形成电荷末端聚合物。
• CYANOSTILBENES
  申请人：ROLIC AG

  公开号：US20160083655A1

  公开（公告）日：2016-03-24

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及新型化合物，特别适用于对从材料进行定向，尤其是光定向，特别是用于光学或电光应用的从材料，例如安全应用、液晶器件或光学或电光薄膜。
• Photosensitive material
  申请人：Daikin Kogyo Co., Ltd.

  公开号：EP0040841A1

  公开（公告）日：1981-12-02

  A copolymer comprising (a) a monomer having a C7 to C21 perfluoralkyl or perfluoralkenyl group at one end of the molecule and an ethylenically unsaturated group at the other end of the molecule, and (b( a monomer having a photosensitive group, e.g. an azidobenzoyloxy group, cinnamoyloxy group, benzoylphenyl group or a,#- unsaturated ketone group. The copolymer has an excellent photosensitivity and excellent water and oil repellent properties, and is useful for various purposes, e.g. as a photosensitive material for dry offset printing plate or resist and as a photo-curable, water and oil repelling coating material.

  一种共聚物，包括(a)分子一端为 C7 至 C21 全氟烷基或全氟烯基，分子另一端为乙烯基不饱和基团的单体，以及(b)具有感光基团（如叠氮苯甲酰氧基、肉桂酰氧基、苯甲酰苯基或 a,#-不饱和酮基）的单体。这种共聚物具有极佳的感光性和优异的防水防油性能，可用于多种用途，例如用作干胶印印版或抗蚀剂的感光材料，以及用作光固化防水防油涂层材料。