2-(全氟-9-甲基癸基)丙烯酸乙酯 | 52956-81-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-(全氟-9-甲基癸基)丙烯酸乙酯
• 英文名称: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,12,12,12-Icosafluoro-11-(trifluoromethyl)dodecyl acrylate
• 英文别名: [3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,12,12,12-icosafluoro-11-(trifluoromethyl)dodecyl] prop-2-enoate
• CAS: 52956-81-7
• 化学式: C₁₆H₇F₂₃O₂
• 分子量: 668.19
• InChiKey: SFACOKSPHOGYDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  41
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  25

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38

文献信息

• Functionalized Photoreactive Compounds
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20080274304A1

  公开（公告）日：2008-11-06

  The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式(I)的官能化光反应化合物，特别适用于液晶对准材料。由于在特定分子系统中的不饱和键直接连接到两个不饱和环系统上附加了一个电子受体基团，因此在包含本发明的这些官能化光反应化合物的材料中可以实现异常高的光敏性、优异的对准性能以及良好的机械稳健性。
• [EN] CYANOSTILBENES<br/>[FR] CYANOSTILBÈNES
  申请人：ROLIC AG

  公开号：WO2014191292A1

  公开（公告）日：2014-12-04

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及一种新型化合物，特别适用于用于光学或电光应用的从材料，尤其是液晶的定向，特别是光定向，如安全应用、液晶器件或光学或电光薄膜。
• CYANOSTILBENES
  申请人：ROLIC AG

  公开号：US20160083655A1

  公开（公告）日：2016-03-24

  The present invention relates to novel compounds that are particularly useful for the alignment, especially photoalignment, of slave material, especially liquid crystals for optical or electro-optical applications, such as security applications, liquid crystal devices or optical or electro-optical films.

  本发明涉及新型化合物，特别适用于对从材料进行定向，尤其是光定向，特别是用于光学或电光应用的从材料，例如安全应用、液晶器件或光学或电光薄膜。
• Interpenetrating networks from unsaturated monomers and thermosetting resins
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0632059A2

  公开（公告）日：1995-01-04

  A cured resin product obtained by mixing (A) a compound having an addition-polymerizable group and capable of yielding a thermoplastic resin by its polymerization and (B) a thermosetting resin to form a uniform solution or dispersion and then curing the component (B) while simultaneously polymerizing the component (A), a process for producing the same, a resin composition, and the use of the same. As compound A olefinically unsaturated monomers like styrene, acrylonitrile or (meth)acrylates, particularly perfluoroalkyl(meth)acrylates, are preferred. The thermosetting resin is for example a cyanate, maleimide, phenolic or preferably epoxy resin in combination with a suitable curing agent. The compositions are used for water repellent coatings or for sealing semiconductor elements.

  将(A)具有可加成聚合基团并能通过聚合生成热塑性树脂的化合物与(B)热固性树脂混合形成均匀溶液或分散液，然后在使组分(A)聚合的同时固化组分(B)而得到的固化树脂产品、生产该产品的工艺、树脂组合物以及该产品的用途。 化合物 A 首选烯烃不饱和单体，如苯乙烯、丙烯腈或（甲基）丙烯酸酯，特别是全氟烷基（甲基）丙烯酸酯。 热固性树脂可以是氰酸酯树脂、马来酰亚胺树脂、酚醛树脂，最好是环氧树脂，再加上适当的固化剂。这种组合物可用于防水涂层或密封半导体元件。
• Functionalized photoreactive compounds
  申请人：Rolic AG

  公开号：EP1764405A1

  公开（公告）日：2007-03-21

  The present invention concerns functionalized photoreactive compounds of formula (I) that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式 (I) 的官能化光活性化合物，这些化合物在液晶配向材料中特别有用。 由于在直接连接两个不饱和环体系的特定分子体系中加入了一个退电子基团，因此在包含本发明所述功能化光活性化合物的材料中，可以获得极高的光敏性、优异的配向性能以及良好的机械坚固性。