gold(I)-bis-triphenylphosphino-perchlorate | 14853-97-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: gold(I)-bis-triphenylphosphino-perchlorate
• 英文别名: [Au(PPh3)2]ClO4；Gold(1+);triphenylphosphane;perchlorate
• CAS: 14853-97-5
• 化学式: C₃₆H₃₀AuP₂*ClO₄
• 分子量: 820.999
• InChiKey: YQCXEDSFHATLFQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.13
• 重原子数：
  44
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [N(PPh3)2][Au(C.tplbond.CH)2] 、 gold(I)-bis-triphenylphosphino-perchlorate 以 丙酮 为溶剂， 以80%的产率得到Au(-C*CH)(PPh3)
  参考文献：
  名称：

  Alkynyl gold(I) complexes. The first family of ethynyl gold (I) complexes

  摘要：

  Complexes [N(PPh(3))(2)][AU(C=CH)(2)] or [AU(C=CH)(PR(3))] (R = Ph or C(6)H(4)OMe-4) or [N(PPh(3))(2)] [AU(C=CH)X] (X = Cl or Br) have been prepared by reacting [N(PPh(3))(2)][Au(acac)(2)] or [Au(acac)(PR(3))] (Hacac = acetylacetone) with acetylene, respectively, or [N(PPh(3))(2)][AU(C=CH)(2)] with [N(PPh(3))(2)][AuX(2)].

  DOI：

  10.1039/dt9950000497
• 作为产物：
  描述：

  三苯基膦氯金 、 perchlorato(triphenylphosphane)silver(I) 以 二氯甲烷 为溶剂， 生成 gold(I)-bis-triphenylphosphino-perchlorate
  参考文献：
  名称：

  Asymmetrical monocationic or neutral gold(II) complexes: X-ray crystal structure of [(C6F5)Au(CH2PPh2CH2)2AuPPh3]C1O4·0.5CH2Cl2

  摘要：

  The reaction of [RAu(CH2PPh2CH2)2AuR] (R = C6F5 or 2,4,6-C6F3H2) with Au(ONO2)PPh3, [Au(PPh3)2]ClO4 or [Au(PPh3)tht]ClO4 (tht = tetrahydrothiophene) leads to neutral [(C6F5)Au(CH2-PPh2CH2)2AuONO2] 1 or monocationic derivatives [RAu(CH2PPh2CH2)2AuL]ClO4 [R = C6F5, L = PPh3(2) or tht(3); R = 2,4,6-C6F3H2, L = PPh3(4) or tht(5)]. Complexes 3 and 5 react with anionic or neutral reagents, giving new neutral or monocationic gold(II) compounds. The structure of [(C6F5)Au(CH2PPh2CH2)2AuPPh3]ClO4.0.5CH2Cl2 (2) was determined by single-crystal X-ray diffraction. Crystals are triclinic, space group P1BAR, a = 12.468(2), b = 13.493(2), c = 18.283(3) angstrom, alpha = 108.13(1)-degrees, beta = 91.09(1)-degrees gamma = 111.95(1)-degrees and Z=2. Final R is 0.0376 for 4906 unique observed reflections. The Au-Au bond length is 2.6612(8) angstrom.

  DOI：

  10.1016/0022-328x(92)83475-w

文献信息

• Synthesis of Acetimino Complexes of Pt(II) and Pt(IV) and the First Heteronuclear μ-Acetimido Complexes
  作者：José Vicente、María-Teresa Chicote、Rita Guerrero、Inmaculada Vicente-Hernández、Peter G. Jones、Delia Bautista

  DOI：10.1021/ic060489i

  日期：2006.6.1

  [Ag(NH=CMe2)2]ClO4 with cis-[PtCl2L2] in a 1:1 molar ratio give cis-[PtCl(NH=CMe2)(PPh3)2]ClO4 (1cis) or cis-[PtCl(NH=CMe2)2(dmso)]ClO4 (2), and in 2:1 molar ratio, they produce [Pt(NH=CMe2)2L2](ClO4)2 [L = PPh3 (3), L2= tbbpy = 4,4'-di-tert-butyl-2,2'-dipyridyl (4)]. Complex 2 reacts with PPh3 (1:2) to give trans-[PtCl(NH=CMe2)(PPh3)2]ClO(4) (1trans). The two-step reaction of cis-[PtCl2(dmso)2], [Au(NH=CMe2)(PPh3)]ClO4

  [Ag（NH = CMe2）2] ClO4与顺式[PtCl2L2]的摩尔比为1：1的反应生成顺式[PtCl（NH = CMe2）（PPh3）2] ClO4（1cis）或顺式[PtCl （NH = CMe2）2（dmso）] ClO4（2），并以2：1摩尔比产生[Pt（NH = CMe2）2L2]（ClO4）2 [L = PPh3（3），L2 = tbbpy = 4,4'-二叔丁基-2,2'-二吡啶基（4）]。配合物2与PPh3（1：2）反应生成反式-[PtCl（NH = CMe2）（PPh3）2] ClO（4）（1trans）。顺式-[PtCl2（dmso）2]，[Au（NH = CMe2）（PPh3）] ClO4和PPh3（1：1：1）的两步反应得到[SP-4-3]-[PtCl（ NH ＝ CMe 2）（dmso）（PPh 3）] ClO 4（5）。配合物2和4与PhICl2的反应产生了
• Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes
  作者：R. Uson、L.A. Oro、M.A. Ciriano、M.T. Pinillos、J.A. Cabeza

  DOI：10.1016/s0022-328x(00)89059-2

  日期：1981.12

  Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az  imidazolate (Im) or pyrazolate (Pz) anions) as ligands. Attempts to prepare rhodium(I)—gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes [Y2Rh(μ-Pz)]2 and [Ph3PAu(μ-Pz)AuPPh32]ClO4, [Au(PPh3)2]ClO4 or AuClPPh3 as

  通过使用络合物ImAuPPh 3或（az）2 Pt（dpe）（咪唑咪唑盐（Im）或吡唑啉酸盐（Pz）阴离子）获得了几种阳离子型杂金属铑络合物。尝试制备含吡唑酸酯桥联配体的铑（I）-金（I）衍生物的尝试未获成功，重排产生了复合物[Y 2 Rh（μ-Pz）] 2和[Ph 3 PAu（μ-Pz）AuPPh 3 2 ]最终产物为ClO 4，[Au（PPh 3）2] ClO 4或AuClPPh 3。
• Bidentate ligand transfer reactions between gold(<scp>I</scp>) complexes
  作者：Manuel Bardají、Antonio Laguna、Mariano Laguna

  DOI：10.1039/dt9950001255

  日期：——

  Reactions of the cationic derivative [Au2(µ-Ph2PCH2PPh2)2][ClO4]2 with [AuX2]–(X = Cl or Br) in a 1 : 1 or a 1 : 2 molar ratio afforded tri- or di-nuclear derivatives, respectively. Neutral complexes [Au2(µ-L–L)2][L–L = S2CNR2(R = Me or CH2Ph)] or [Aun(µ-L–L)n][L–L = S2COR (R = Me or Et) or C5H4NS]react with the cationic [Au(PPh3)2]ClO4 in 1 : 2 molar ratio, to give open-ring complexes [Au(PPh3)}2(µ-L–L)]ClO4

  阳离子衍生物[Au 2（µ-Ph 2 PCH 2 PPh 2）2 ] [ClO 4 ] 2与[AuX 2 ] –（X = Cl或Br）的摩尔比为1：1分别提供三核或二核衍生物。中性络合物[Au 2（µ-L–L）2 ] [L–L = S 2 CNR 2（R = Me或CH 2 Ph）]或[Au n（µ-L–L）n ] [L–L = S 2 COR（R = Me或Et）或C 5 H 4 NS]与阳离子[Au（PPh 3）2：ClO 4摩尔比为1：2，得到开环络合物[Au（PPh 3）} 2（µ-L–L）] ClO 4。中性络合物[Au 2（µ-S 2 CNR 2）2 ]（R = Me或CH 2 Ph）与阳离子[Au 2（µ-P–P）2 ] [ClO 4 ] 2（P–P = Ph 2 PCH 2 PPh 2或Ph 2 PCH 2 CH 2 PPh 2）导致杂桥双核络合物[Au 2（μ-S 2 CNR
• Mononuclear gold(I) and heteronuclear gold(I)-palladium(II) bibenzimidazolate complexes with new coordination modes of the ligand
  作者：R. Uson、J. Gimeno、J. Fornies、F. Martinez、C. Fernandez

  DOI：10.1016/s0020-1693(00)81897-6

  日期：1982.1

  Abstract Metathetic reactions of gold(I) halide complexes and the potassium salt of 2,2′-bibenzimidazol afford binuclear bibenzimidazolate gold(I) complexes with the general formula Au 2 L 2 }(μ-BiBzIm) L = PPh 3 , PBu n 3 , P(OMe) 3 ; L 2 = 1,1-bis(diphenylphosphine)-methane (dppm), 1,2-bis(diphenylphosphine)ethane (dppe). These complexes are Lewis bases and can be used as precursors for the synthesis

  摘要卤化金（I）配合物与2,2'-联苯并咪唑钾盐的易位反应提供了通式为Au 2 L 2}（μ-BiBzIm）L = PPh 3，PBu的双核联苯并咪唑酸盐金（I）配合物n 3，P（OMe）3；L 2 ＝ 1，1-双（二苯基膦）-甲烷（dppm），1，2-双（二苯基膦）乙烷（dppe）。这些络合物是路易斯碱，可用作合成三核和四核阳离子金（I）络合物或三核金（I）和钯（II）络合物的前体，其中联苯并咪唑酸根阴离子起桥联四核配体的作用。还描述了六核金（I）-钯（II）配合物。
• (Polyhalophenyl)silver(I) complexes as arylating agents: Crystal structure of [(μ-2,4,6-C6F3H2)(AuPPh3)2]ClO4
  作者：Rafael Usón、Antonio Laguna、Eduardo J. Fernández、Aranzazu Mendia、Peter G. Jones

  DOI：10.1016/0022-328x(88)80367-x

  日期：1988.8

  chlorogold(I) precursors [AuCl(tht), AuCl(PPh3), ClAu(dppm)AuCl (tht = tetrahydrothiophene, dppm = bis(diphenylphosphino)methane], to give the corresponding arylgold complexes in good yield. With gold precursors in higher oxidation state, AgC6Cl5 either causes reduction to gold(I) or gives no reaction, whereas AgC6F5 and AgC6F3H2 lead to gold(II) complexes (R2Au(dppm)AuR2) or gold (III) complexes [Au(C

  所述arylsilver衍生物AGR（R = C 6 ˚F 5，2,4,6--C 6 ˚F 3 ħ 2或C 6氯5）与chlorogold反应（I）的前体[AUCL（THT），AUCL（PPH 3），ClAu （dppm）AuCl（tht =四氢噻吩，dppm =双（二苯基膦基）甲烷]，得到的芳基金配合物收率良好。在金前体处于较高氧化态的情况下，AgC 6 Cl 5会导致金（I）还原或生成没有反应，而AgC 6 F 5和AgC 6 F 3 H 2生成金（II）络合物（R 2Au（dppm）AuR 2）或金（III）络合物[Au（C 6 F 3 H 2）（C 6 F 5）2（PPh 3）；Au（C 6 F 3 H 2）2（C 6 F 5）（tht）; Au（C 6 F 5）3（tht）; Au（C 6 F 3 H 2）3（tht）]。