2-(羟甲基)丁烷-1,2,3,4-四醇 | 89615-91-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-(羟甲基)丁烷-1,2,3,4-四醇
• 英文名称: 2-C-hydroxymethyltetritol
• 英文别名: Apiitol；2-(hydroxymethyl)butane-1,2,3,4-tetrol
• CAS: 89615-91-8
• 化学式: C₅H₁₂O₅
• 分子量: 152.147
• InChiKey: SDXWEZQDLHNYFR-UHFFFAOYSA-N

物化性质

• 沸点：
  467.2±40.0 °C(Predicted)
• 密度：
  1.536±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -3.2
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  101
• 氢给体数：
  5
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-[[(2R,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxymethyl]butane-1,2,3,4-tetrol 生成 2-(羟甲基)丁烷-1,2,3,4-四醇
  参考文献：
  名称：

  REDGWELL, ROBERT J.;BEEVER, ROSS E.;BIELESKI, RODERICK L.;LARACY, ELAINE +, CARBOHYDR. RES., 198,(1990) N, C. 39-48

  摘要：

  DOI：

文献信息

• Comparison of the stable products formed by fast atom bombardment and γ-irradiation of glycerol
  作者：T. Keough、F. S. Ezra、A. F. Russell、J. D. Pryne

  DOI：10.1002/oms.1210220503

  日期：1987.5

  AbstractThe major end‐products formed by fast atom bombardment (FAB) and γ‐irradiation of glycerol have been identified using capillary gas chromatography/mass spectrometry. The product distributions differ dramatically. Products resulting from the recombination of either carbon‐centered or oxygen‐centered radicals are evident for both sources of irradiation. However, the major FAB‐generated products are formed by the recombination of carbon‐centered [G – H]· radicals with other carbon‐centered radicals while the major γ‐radiolysis products result from the recombination of oxygen‐centered [G–H]· radicals with lower‐weight carbon‐centered species. γ‐Radiolysis of an N2O‐saturated aqueous solution of glycerol, experimental conditions that strongly favor the formation of carbon‐centered [G – H]· radicals at the expense of the oxygen‐centered species, yielded some products that were identical to those produced by FAB of neat glycerol. Finally, the free radicals produced by γ‐radiolysis of glycerol were investigated by electron spin resonance spectroscopy and spin trapping with 5,5‐dimethyl‐1‐pyrrolne‐TV‐oxide. The presence of only the carbon‐centered free radical was established by this technique. The implications of these results are discussed.
• Medevedeva, M. G.; Sukharevich, V. I.; Stanek, Ya. Ya., Journal of applied chemistry of the USSR, 1983, vol. 56, # 12, p. 2525 - 2527
  作者：Medevedeva, M. G.、Sukharevich, V. I.、Stanek, Ya. Ya.、Yakovlev, V. I.

  DOI：——

  日期：——