benzochrysen-10-boronic acid | 1152130-45-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: benzochrysen-10-boronic acid
• 英文别名: 10-benzothiopheneboric acid；benzo[g]chrysene-10-boronic acid；10-Benzo[g]chryseneboronic acid；21-pentacyclo[12.8.0.02,7.08,13.015,20]docosa-1(14),2,4,6,8,10,12,15,17,19,21-undecaenylboronic acid
• CAS: 1152130-45-4
• 化学式: C₂₂H₁₅BO₂
• 分子量: 322.171
• InChiKey: NVDQCFAMTMTVTJ-UHFFFAOYSA-N

物化性质

• 沸点：
  643.1±38.0 °C(Predicted)
• 密度：
  1.33±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.98
• 重原子数：
  25
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-二溴苯 、 benzochrysen-10-boronic acid 在 四(三苯基膦)钯 sodium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 8.0h， 生成 21-[4-(21-Pentacyclo[12.8.0.02,7.08,13.015,20]docosa-1(14),2,4,6,8,10,12,15,17,19,21-undecaenyl)phenyl]pentacyclo[12.8.0.02,7.08,13.015,20]docosa-1(14),2,4,6,8,10,12,15,17,19,21-undecaene
  参考文献：
  名称：

  BENZOCHRYSENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

  摘要：

  公开号：

  EP2216313B1
• 作为产物：
  描述：

  10-bromobenzo[g]chrysene 在 正丁基锂 、 硼酸三异丙酯 、 盐酸 作用下， 以 正己烷 、 甲苯 、 乙醚 、 水 为溶剂， 反应 1.0h， 以60%的产率得到benzochrysen-10-boronic acid
  参考文献：
  名称：

  BENZOCHRYSENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

  摘要：

  公开号：

  EP2216313B1

文献信息

• 化合物、有机电致发光元件用材料、有机电致 发光元件和电子设备
  申请人：出光兴产株式会社

  公开号：CN105473600B

  公开（公告）日：2019-03-15

  提供更高性能的、特别是驱动电压和外量子效率良好、且长寿命化的有机电致发光元件和具有该有机电致发光元件的电子设备。进而提供用于实现它们的化合物。具体地，提供具有三亚苯骨架的特定结构的化合物、使用了该化合物的有机电致发光元件、以及具有该有机电致发光元件的电子设备。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Kawamura Yuichiro

  公开号：US20120153268A1

  公开（公告）日：2012-06-21

  An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “E T b >E T h ” (where, E T h is the triplet energy of the host material, and E T b is the triplet energy of the barrier material).

  一种有机电致发光器件包括阳极、发光层、电子传输区和阴极，阳极、发光层、电子传输区和阴极依次堆叠，发光层包括主体材料和发射荧光的掺杂材料，其主峰波长为550nm或更低，电子传输区包括邻近发光层的阻挡层，该阻挡层包括具有电子传输结构部分和包括融合的多环芳香族碳化合物的三重态阻挡结构部分的阻挡材料，并满足“ETb>ETh”的关系（其中，ETh是主体材料的三重态能量，而ETb是阻挡材料的三重态能量）。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Takashima Yoriyuki

  公开号：US20110315965A1

  公开（公告）日：2011-12-29

  An organic electroluminescence device and a material for producing the organic electroluminescence device. The organic electroluminescence device includes an organic thin film layer between a cathode and an anode, the organic thin film layer including one or more layers, in which the organic thin film layer includes one or more light emitting layers and at least one of the light emitting layers includes a phosphorescent material and a host material. The host material has an essential structure in which a naphthalene ring is bonded to a fluorene skeleton, dibenzofuran skeleton, or dibenzothiophene skeleton. The organic electroluminescence device is a phosphorescent device having high efficiency and long lifetime.

  一种有机电致发光器件和制备该有机电致发光器件的材料。该有机电致发光器件包括在阴极和阳极之间的有机薄膜层，该有机薄膜层包括一个或多个层，其中有机薄膜层包括一个或多个发光层，至少一个发光层包括磷光材料和主体材料。主体材料具有一个必要的结构，其中萘环连接到芴骨架、二苯并呋喃骨架或二苯并噻吩骨架。该有机电致发光器件是一种具有高效率和长寿命的磷光器件。
• Benzochrysene derivative and organic electroluminescence device using the same
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US08222637B2

  公开（公告）日：2012-07-17

  A fused aromatic ring derivative shown by the following formula (1): wherein Ra and Rb are independently a hydrogen atom or a substituent, m and n are independently an integer of 1 to 13, and when m and n are two or more, Ras and Rbs may be independently the same or different, and L1 is a single bond or a substituted or unsubstituted divalent linking group, provided that the fused aromatic ring derivative shown by the formula (1) does not have an anthracene ring.

  以下是式子(1)所示的融合芳香环衍生物： 其中，Ra和Rb分别是氢原子或取代基，m和n分别是1到13的整数，当m和n是两个或更多时，Ras和Rbs可以独立地相同或不同，L1是单键或取代或未取代的二价连接基团，前提是式(1)所示的融合芳香环衍生物不具有蒽环。
• NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME
  申请人：Kawamura Masahiro

  公开号：US20120132899A1

  公开（公告）日：2012-05-31

  A nitrogen-containing heterocyclic derivative represented by the following formula (1): wherein any “12-a” groups of R 1 to R 12 are independently a hydrogen atom, a fluorine atom, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; any “a” groups of R 1 to R 12 are independently a single bond which is bonded to L 1 ; L 1 is a single bond, a “b+1” valent substituted or unsubstituted hydrocarbon ring group having 6 to 30 ring carbon atoms or a “b+1” valent substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; HAr is a substituted or unsubstituted nitrogen-containing heterocyclic group; and “a” and “b” are independently an integer of 1 to 4, and at least one of “a” and “b” is 1. Also disclosed is a nitrogen-containing heterocyclic derivative represented by the following formula (21) or (31):

  一种含氮杂环衍生物，由以下公式（1）表示：其中R1至R12中的任何“12-a”基团独立地是氢原子、氟原子、具有6至30个环碳原子的取代或未取代芳基基团或具有5至30个环原子的取代或未取代杂环基团；R1至R12中的任何“a”基团独立地是与L1相结合的单键；L1是单键、具有6至30个环碳原子的“b+1”价取代或未取代的碳氢环基团或具有5至30个环原子的“b+1”价取代或未取代的杂环基团；HAr是取代或未取代的含氮杂环基团；“a”和“b”分别是1至4的整数，且至少有一个“a”和“b”为1。还公开了一种由以下公式（21）或（31）表示的含氮杂环衍生物：