1-(3-bromo-3-phenylpropyl)-4-nitrobenzene | 1283268-59-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 1-(3-bromo-3-phenylpropyl)-4-nitrobenzene
• CAS: 1283268-59-6
• 化学式: C₁₅H₁₄BrNO₂
• mdl: MFCD19499313
• 分子量: 320.186
• InChiKey: WXELHEFAZQLSTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲醇 、 1-(3-bromo-3-phenylpropyl)-4-nitrobenzene 反应 2.0h， 以74%的产率得到1-(3-methoxy-3-phenylpropyl)-4-nitrobenzene
  参考文献：
  名称：

  可见光诱导卤化苄向烯烃的分子间原子转移自由基加成反应：四氢喹啉的简便合成

  摘要：

  摘要 Cu（dap）2 Cl已被用作可见光的氧化还原催化剂，用于将卤代苄基原子转移到苯乙烯和甲硅烷基烯醇醚中。所得的ATRA产物可以容易地转化为四氢喹啉。 Cu（dap）2 Cl已被用作可见光的氧化还原催化剂，用于将卤代苄基原子转移到苯乙烯和甲硅烷基烯醇醚中。所得的ATRA产物可以容易地转化为四氢喹啉。

  DOI：

  10.1055/s-0033-1338910
• 作为产物：
  描述：

  对硝基溴化苄 生成 1-(3-bromo-3-phenylpropyl)-4-nitrobenzene
  参考文献：
  名称：

  MULTICYCLIC CARBOCATION AND CARBORADICAL COMPOUNDS AND METHODS OF USE

  摘要：

  The present invention provides a compound comprising a moiety of the formula: (I) where said moiety of formula I is a radical, a cation, or a radical dication; Y 1 , Y 2 , Y 3 , R 1a , R 1b , R 1c , R 1d , R 2a , R 2b , R 2c , R 2d , R 3a , R 3b , R 3c , and R 3d are as defined herein. Compounds containing a moiety of Formula I are useful in a wide variety of applications including, but not limited to, as photocatalysts, use in OLEDs, in electronic components, etc. As an organic-based photocatalysts, compounds containing a moiety of Formula I are activated by a relatively low energy electromagnetic wavelength, e.g., wavelength of 600 nm or greater. Furthermore, compounds of the invention can be used as both photoreduction catalysts and photooxidation catalysts.

  公开号：

  US20230095372A1

文献信息

• [Copper(phenanthroline)(bisisonitrile)]⁺-Complexes for the Visible-Light-Mediated Atom Transfer Radical Addition and Allylation Reactions
  作者：Matthias Knorn、Thomas Rawner、Rafał Czerwieniec、Oliver Reiser

  DOI：10.1021/acscatal.5b01071

  日期：2015.9.4

  series of heteroleptic [Cu(phenantroline)(bisisonitrile)]+-complexes was synthesized, and their structural, spectroscopic, and electrochemical properties were investigated. The new copper(I) complexes were employed as photoredox-catalysts in the visible-light-mediated atom transfer radical addition (ATRA). Especially, [Cu(dpp)(binc)]BF4 (6a-BF4)(dpp = 2,9-diphenyl-1,10-phenanthroline; binc = bis(2-isocyanophenyl)

  合成了一系列杂合[Cu（菲咯啉）（双异腈）] +-配合物，并对其结构，光谱和电化学性质进行了研究。新的铜（I）配合物被用作可见光介导的原子转移自由基加成（ATRA）中的光氧化还原催化剂。特别地，由于[Cu（dpp）（binc）] BF 4（6a-BF 4）（dpp = 2,9-二苯基-1,10-菲咯啉； binc =双（2-异氰基苯基）苯基膦酸酯）被证明具有高活性与常用的[Cu（dap）2 ] Cl（1-Cl）（dap = 2,9-di（p-茴香基）-1,10-菲咯啉）。此外，该催化剂可用于在温和的可见光光氧化还原条件下与三甲基烯丙基硅烷进行烯丙基化反应。
• Making Copper Photocatalysis Even More Robust and Economic: Photoredox Catalysis with [Cu ^II (dmp) ₂ Cl]Cl
  作者：Sebastian Engl、Oliver Reiser

  DOI：10.1002/ejoc.201900839

  日期：2020.3.15

  complex [Cu(dmp)2Cl]Cl is introduced to visible‐light photocatalysis, being efficient but considerable more cost‐effective compared to previously established CuI photocatalysts within a broad scope of different reactions. Furthermore, this study provides UV/Vis evidence for the visible light activation of CuII complexes, suggesting an LMCT process resulting in the visible light homolysis of CuII‐Cl to give

  Cu II络合物[Cu（dmp）2 Cl] Cl被引入可见光光催化，与先前建立的Cu I光催化剂相比，Cu II络合物在多种不同的反应中效率高，但具有更高的成本效益。此外，这项研究为Cu II配合物的可见光活化提供了UV / Vis证据，表明LMCT过程导致Cu II- Cl的可见光均质化，从而产生了催化活性的Cu I物种。
• Helical Carbenium Ion: A Versatile Organic Photoredox Catalyst for Red-Light-Mediated Reactions
  作者：Liangyong Mei、José M. Veleta、Thomas L. Gianetti

  DOI：10.1021/jacs.0c05507

  日期：2020.7.15

  m (nPr-DMQA+) tetrafluoroborate) has been used as an organic photoredox catalyst for photoreductions and photooxidations in the presence of red light (λmax = 640 nm). It has catalyzed red-light-mediated dual transition-metal/photoredox-catalyzed C-H arylation and intermolecular atom transfer radical addition through oxidative quenching. Moreover, its potential in photooxidation catalysis has also been

  红光具有能量低、健康风险小、通过各种介质穿透深度高等优点。在此，螺旋碳鎓离子（N,N'-二正丙基-1,13-二甲氧基喹吖啶鎓（nPr-DMQA+）四氟硼酸盐）已被用作有机光氧化还原催化剂，用于在红光（λmax = 640 纳米）。它通过氧化猝灭催化红光介导的双过渡金属/光氧化还原催化的 CH 芳基化和分子间原子转移自由基加成。此外，其在红光诱导的芳基硼酸有氧氧化羟基化和通过还原淬灭的苄基 C(sp3)-H 氧化中的成功应用也证明了其在光氧化催化中的潜力。因此，
• [EN] MULTICYCLIC CARBOCATION AND CARBORADICAL COMPOUNDS AND METHODS OF USE<br/>[FR] COMPOSÉS MULTICYCLIQUES À CARBOCATION ET À RADICAL CARBONÉ ET PROCÉDÉS D'UTILISATION
  申请人：UNIV ARIZONA

  公开号：WO2021155331A1

  公开（公告）日：2021-08-05

  The present invention provides a compound comprising a moiety of the formula: (I) where said moiety of formula I is a radical, a cation, or a radical dication; Y1, Y2, Y3, R1a, R1b, R1c, R1d, R2a, R2b, R2c, R2d, R3a, R3b, R3c, and R3d are as defined herein. Compounds containing a moiety of Formula I are useful in a wide variety of applications including, but not limited to, as photocatalysts, use in OLEDs, in electronic components, etc. As an organic-based photocatalysts, compounds containing a moiety of Formula I are activated by a relatively low energy electromagnetic wavelength, e.g., wavelength of 600 nm or greater. Furthermore, compounds of the invention can be used as both photoreduction catalysts and photooxidation catalysts.