2-[(2-甲基-2-丙基)氨基]乙基丙烯酸酯 | 14206-21-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-[(2-甲基-2-丙基)氨基]乙基丙烯酸酯
• 中文别名: 2-丙烯酸,2-[(1,1-二甲基乙基)氨基]乙基酯
• 英文名称: Acrylsaeure-(2--aethyl)-ester
• 英文别名: acrylic acid-(2-tert-butylamino-ethyl ester)；Acrylsaeure-(2-tert-butylamino-aethylester)；1-Acryloyloxy-2-tert-butylamino-aethan；2-tert-butylaminoethyl acrylate；N-t-butylamino ethyl acrylate；N-t-Butylaminoethyl acrylate；2-(tert-butylamino)ethyl prop-2-enoate
• CAS: 14206-21-4
• 化学式: C₉H₁₇NO₂
• 分子量: 171.239
• InChiKey: KDAKDBASXBEFFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2922199090

反应信息

• 作为反应物：
  描述：

  2-[(2-甲基-2-丙基)氨基]乙基丙烯酸酯 、 氯化氰 在 potassium carbonate 、 甲苯 作用下， 生成 1-acryloyloxy-2-(tert-butyl-cyano-amino)-ethane
  参考文献：
  名称：

  N-cyano-n-alkylaminoalkyl esters

  摘要：

  公开号：

  US02834765A1
• 作为产物：
  描述：

  叔丁基乙醇胺 、 丙烯酸甲酯（MA） 在 tetrabutoxytitanium 、 N,N'-二苯基-1,4-苯二胺 作用下， 生成 2-[(2-甲基-2-丙基)氨基]乙基丙烯酸酯
  参考文献：
  名称：

  Korshunov,M.A. et al., Journal of Organic Chemistry USSR (English Translation), 1969, vol. 5, # 2, p. 244 - 251

  摘要：

  DOI：

文献信息

• COMPOSITION INCLUDING DIALKYL TIN OXIDE AND USE THEREOF AS A TRANSESTERIFICATION CATALYST FOR THE SYNTHESIS OF (METH) ACRYLIC ESTERS
  申请人：Paul Jean-Michel

  公开号：US20120123148A1

  公开（公告）日：2012-05-17

  The present invention relates to a composition including a dialkyl tin oxide, such as DBTO, which can be used as a transesterification catalyst for the synthesis of (meth)acrylic esters. The invention also relates to a method for the synthesis of (meth)acrylic esters by transesterification in the presence of said composition.

  本发明涉及一种包括二烷基锡氧化物（如DBTO）的组合物，可用作合成（甲）丙烯酸酯的酯交换催化剂。该发明还涉及在该组合物存在下通过酯交换合成（甲）丙烯酸酯的方法。
• Hydroxylamine esters as polymerization initiators
  申请人：——

  公开号：US20030216494A1

  公开（公告）日：2003-11-20

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  该发明涉及新型环状和开链羟胺酯以及包括这些羟胺酯和乙烯基不饱和单体或寡聚物的可聚合组合物。该发明还涉及用作聚合引发剂以及用于控制聚丙烯降解和实现聚乙烯分子量控制增加的已知羟胺酯，所述羟胺酯来自HALS化合物和新颖羟胺酯的组合。
• Optically active high-molecular compounds
  申请人：Nakano Tamaki

  公开号：US20050234267A1

  公开（公告）日：2005-10-20

  This invention relates to optically active high-molecular-weight compounds represented by the structural formula and stationary-phase materials containing the same. The high-molecular-weight compounds exhibit optical activity by virtue of their stacking helical structure wherein the aromatic groups are aligned in a twisted arrangement, thus being useful as optically active stationary phases for HPLC or polarized-light absorbers. In the formula 1 Ar in the formula is an aromatic ring, R 1 , and R 2 are hydrogen atoms or organic groups, R 3 and R 4 are substituents, n is an integer of 2 or more, X is a group selected from among —(CH 2 ) m —, an aromatic group, a vinyl group, a hetero atom and a group containing a hetero atom, and m is an integer of 0 or more. R 3 and R 4 may be introduced 2-4 times respectively, wherein these may be identical or different, and R is a hydrogen atom, a hetero atom or an organic group.

  这项发明涉及光学活性高分子量化合物，其结构式和含有相同化合物的固定相材料。这些高分子量化合物由于其堆积螺旋结构而表现出光学活性，在这种结构中，芳香基以扭曲排列方式排列，因此可用作HPLC的光学活性固定相或偏光吸收剂。在公式1中，公式中的Ar是芳香环，R1和R2是氢原子或有机基团，R3和R4是取代基，n是大于或等于2的整数，X是从—(CH2)m—、芳香基、乙烯基、杂原子和含有杂原子的基团中选择的基团，m是大于或等于0的整数。R3和R4可以分别引入2-4次，这些基团可以相同也可以不同，R是氢原子、杂原子或有机基团。
• [EN] DERIVATIVES OF FATTY ESTERS, FATTY ACIDS AND ROSINS<br/>[FR] DÉRIVÉS D'ESTERS D'ACIDE GRAS, ACIDES GRAS ET ROSINES
  申请人：UNIV WASHINGTON STATE RES FDN

  公开号：WO2014116996A1

  公开（公告）日：2014-07-31

  Provided is a compound of Formula (I); where R1, R2, L1 and L2 are as described herein. The compound of Formula I and copolymers thereof can be used as epoxy resins, curing agents, flame retardants, UV curable agents and the like. A process for preparing the compound of Formula (I) is also provided.

  提供的是化合物的化学式（I）；其中R1、R2、L1和L2如本文所述。化合物的化学式I及其共聚物可用作环氧树脂、固化剂、阻燃剂、紫外光固化剂等。还提供了一种制备化合物的化学式（I）的方法。
• METHOD FOR THE SYNTHESIS OF (METH)ACRYLIC ESTERS CATALYSED BY A POLYOL TITANATE
  申请人：Paul Jean-Michel

  公开号：US20100145092A1

  公开（公告）日：2010-06-10

  The subject of the invention is a method for the synthesis of (meth)acrylic esters by transesterification in the presence of a catalyst corresponding to the formula [(R′O) 3 TiO] x R″ in which R′ is a linear or branched alkyl radical having from 2 to 8 carbon atoms which may contain heteroatoms or R′ is a phenyl radical, R′ is a polyfunctional radical, originating from a polyol R′(OH) x comprising x alcohol functional groups and x is an integer ranging from 2 to 6. The method according to the invention is particularly well suited to the synthesis of dialkylaminoalkyl (meth)acrylates from methyl (meth)acrylate and a dialkylaminoalcohol.

  本发明的主题是一种合成（甲基）丙烯酸酯的方法，通过在存在与下列式相对应的催化剂下进行酯交换反应合成，其中R′是具有2至8个碳原子的直链或支链烷基基团，可能含有杂原子，或者R′是苯基基团，R′是来自具有x个醇官能团的多羟基R′（OH）x的多功能基团，x为2至6之间的整数。根据本发明的方法特别适用于从甲基（甲基）丙烯酸酯和二烷基氨基醇合成二烷基氨基丙烯酸酯。