1,2-Diphenyl-1-sulfido-2,3-dihydrophosphindol-1-ium | 1259008-83-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-Diphenyl-1-sulfido-2,3-dihydrophosphindol-1-ium
• 英文别名: 1,2-diphenyl-1-sulfido-2,3-dihydrophosphindol-1-ium
• CAS: 1259008-83-7
• 化学式: C₂₀H₁₇PS
• 分子量: 320.395
• InChiKey: PZFWVIMVXHVNIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  苯乙烯 、 苯基锂 、 苯基二氯化磷 在 二氯二茂锆 、 sulfur 作用下， 以 二丁醚 、 甲苯 为溶剂， 以62%的产率得到1,2-Diphenyl-1-sulfido-2,3-dihydrophosphindol-1-ium
  参考文献：
  名称：

  Preparation of 2-phospholene derivatives from zirconacyclopentenes

  摘要：

  Zirconacyclopentenes, which are easily prepared from alkynes, alkenes, and zirconocene compounds, reacted with dichlorophenylphosphine to give 2-phospholene in high yields. The reaction was performed conveniently in one-pot from an alkyne, alkene, dichlorophosphine, and zirconocene compounds. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.061

文献信息

• Preparation of 2-phospholene derivatives from zirconacyclopentenes
  作者：Yiqing Zhou、Xiaoyu Yan、Chanjuan Xi

  DOI：10.1016/j.tetlet.2010.09.061

  日期：2010.11

  Zirconacyclopentenes, which are easily prepared from alkynes, alkenes, and zirconocene compounds, reacted with dichlorophenylphosphine to give 2-phospholene in high yields. The reaction was performed conveniently in one-pot from an alkyne, alkene, dichlorophosphine, and zirconocene compounds. (C) 2010 Elsevier Ltd. All rights reserved.