N,N'-bis(2,6-diisopropylphenyl)-1-(p-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxydiimide | 1354570-11-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis(2,6-diisopropylphenyl)-1-(p-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxydiimide
• 英文别名: N,N'-bis(2,6-diisopropylphenyl)-1-p-tert-butylphenoxyperylene-3,4,9,10-tetracarboxydiimide；11-(4-Tert-butylphenoxy)-7,18-bis[2,6-di(propan-2-yl)phenyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone；11-(4-tert-butylphenoxy)-7,18-bis[2,6-di(propan-2-yl)phenyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 1354570-11-8
• 化学式: C₅₈H₅₄N₂O₅
• 分子量: 859.077
• InChiKey: XFZUVQNMPVQZGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.5
• 重原子数：
  65
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  84
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3,4,9,10-苝四羧酸二酐 在 硫酸 、 碘 、 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 140.0h， 生成 N,N'-bis(2,6-diisopropylphenyl)-1-(p-tert-butylphenoxy)perylene-3,4,9,10-tetracarboxydiimide
  参考文献：
  名称：

  Synthesis and characterization of some perylene dyes for dye-based LCD color filters

  摘要：

  Eight red perylene dyes were synthesized to improve the optical performance of LCD color filters. Among them, dyes with bulky functional substituents at the bay and terminal positions were highly soluble in cyclohexanone, the industrial solvent currently used in the pigment dispersion method. The spectral properties and thermal stability of the dye-based color filters with these dyes were examined by comparing them with pigment-based ones. The prepared color filters exhibited superior spectral properties due to the smaller particle size of the dyes, which led to less light scattering. However, their thermal stability varied with the dye structures, and only the dyes mono-substituted at the bay position had sufficient thermal stability. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.11.006

文献信息

• Synthesis and characterization of some perylene dyes for dye-based LCD color filters
  作者：Jun Choi、Chun Sakong、Jae-Hong Choi、Chun Yoon、Jae Pil Kim

  DOI：10.1016/j.dyepig.2010.11.006

  日期：2011.7

  Eight red perylene dyes were synthesized to improve the optical performance of LCD color filters. Among them, dyes with bulky functional substituents at the bay and terminal positions were highly soluble in cyclohexanone, the industrial solvent currently used in the pigment dispersion method. The spectral properties and thermal stability of the dye-based color filters with these dyes were examined by comparing them with pigment-based ones. The prepared color filters exhibited superior spectral properties due to the smaller particle size of the dyes, which led to less light scattering. However, their thermal stability varied with the dye structures, and only the dyes mono-substituted at the bay position had sufficient thermal stability. (C) 2010 Elsevier Ltd. All rights reserved.