2-thia-3-tellurabutane | 762268-67-7

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: 2-thia-3-tellurabutane
• 英文别名: Dimethyl tellurenyl；methyltellanylsulfanylmethane
• CAS: 762268-67-7
• 化学式: C₂H₆STe
• 分子量: 189.736
• InChiKey: NSNCMNXZGXWXDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.02
• 重原子数：
  4
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二氯甲烷 、 二甲基二硫 在 氢氧化钾 、 一水合肼 、 碲化氢 作用下， 反应 5.0h， 以23.0%的产率得到二甲硫基甲烷
  参考文献：
  名称：

  Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system

  摘要：

  Methods of synthesis of compounds MeY(CH2Y)(n) Me (Y=S, Se, Te; n = 1-3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y2-) and dimethyl dichalcogenides (MeY-) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.

  DOI：

  10.1134/s1070363208090156

文献信息

• Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system
  作者：E. P. Levanova、V. Yu. Vshivtsev、E. N. Sukhomazova、V. A. Grabel’nykh、N. V. Russavskaya、E. R. Zhanchipova、L. V. Klyba、A. I. Albanov、N. A. Korchevin

  DOI：10.1134/s1070363208090156

  日期：2008.9

  Methods of synthesis of compounds MeY(CH2Y)(n) Me (Y=S, Se, Te; n = 1-3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y2-) and dimethyl dichalcogenides (MeY-) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.