N,N,N'N'-Tetrakis<2-(diphenylarsino)ethyl>ethane-1,2-diamine | 139339-54-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N,N'N'-Tetrakis<2-(diphenylarsino)ethyl>ethane-1,2-diamine
• 英文别名: α,α'-bis(bis{2-(diphenylarsino)ethyl}amino)ethane；N~1~,N~1~,N~2~,N~2~-Tetrakis[2-(diphenylarsanyl)ethyl]ethane-1,2-diamine；N,N,N',N'-tetrakis(2-diphenylarsanylethyl)ethane-1,2-diamine
• CAS: 139339-54-1
• 化学式: C₅₈H₆₀As₄N₂
• 分子量: 1084.81
• InChiKey: GKLMGZSAFRUFMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.83
• 重原子数：
  64
• 可旋转键数：
  23
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N,N'N'-Tetrakis<2-(diphenylarsino)ethyl>ethane-1,2-diamine 在 lithium chloride 作用下， 以 丙酮 、 苯 为溶剂， 生成 {Cu2(α,α'-bis(bis{2-(diphenylarsino)ethyl}amino)ethane)Cl2}
  参考文献：
  名称：

  Reactions of a dinuclear copper(I) complex derived from a hexadentate ligand having N2As4 donor sites. Crystal structure of [Cu2(BDAE)(PPh3)2cl2]

  摘要：

  The reactions of a tri-coordinate dinuclear copper(I) complex of the composition [Cu2(BDAE)](ClO4)2 (Where BDAE = alpha,alpha'-bis{bis[2-(diphenylarsino)ethyl]amino}ethane) with some mono- and bidentate species having different donor atoms were studied. The reaction of the complex with anionic species such as LiCl, NaN3, NH4NCS and NaBH4 resulted in the formation of tetra-coordinate complexes of compositions [Cu2(BDAE)Cl2], [Cu2(BDAE)(N3)](ClO4), [Cu2(BDAE)(NCS)](ClO4) and [Cu2(BDAE)(BH4)2], respectively. The reactions of CS2 and thiourea gave the products [Cu2(BDAE)(CS2)2](ClO4)2 and [Cu2(BDAE)(H2NCSNH2)2](ClO2)2, respectively. The reactions of monodentate neutral molecules B (B = PPh3, AsPh3 and imidazole) yielded complexes of the composition [Cu2(BDAE)(B)2](ClO4)2. The reaction with pyridine in a 1:4 molar ratio gave a complex of composition [Cu2(BDAE)(C5H5N)4](ClO4)2. The bidentate ligands 1,2-bis(diphenylphosphino)methane/ethane (dppm/dppe) react with the complex to yield complexes of the composition [Cu2(BDAE)(dppm)](ClO4)2/[Cu2(BDAE)(dppe)](ClO4)2, in which dppm/dppe acts as a bridge between two metal centres. The reaction with bipyridine gave a tetra-coordinate complex of the composition [Cu2(BDAE)(C10H8N2)2](ClO4)2. The molecular structure of the complex [Cu2(BDAE)(PPh3)2Cl2] was established by single-crystal X-ray diffraction. The cyclic voltammetric behaviour of all of these complexes was investigated.

  DOI：

  10.1016/s0277-5387(00)81766-0
• 作为产物：
  描述：

  N,N,N’,N’-四羟乙基乙二胺 在 氯化亚砜 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 氯仿 为溶剂， 反应 6.0h， 生成 N,N,N'N'-Tetrakis<2-(diphenylarsino)ethyl>ethane-1,2-diamine
  参考文献：
  名称：

  三种具有N 2 P 4或N 2 As 4供体位点的新的双核六齿配体的双核铜（I）配合物的合成，表征，结构和反应活性

  摘要：

  具有N 2 P 4或N 2 As 4供体位点的三个新的双核六齿配体，即。N，N，N '，N'-四-[2-（二苯基膦基）乙基]乙烷-1,2-二胺（L 1），其a类似物（L 2）和1,3-bis {bis [2-已经制备了（二苯基膦基）乙基]氨基甲基}苯（L 3）。配体与[Cu（PPh 3）3 Cl]反应，得到双核四配位铜（I）络合物[Cu 2（L 1）（PPh 3）2 Cl 2 ]，[Cu 2（L 2）（PPh 3） 2 Cl 2 ]和[Cu 2（L 3）Cl 2 ]。用[Cu（NCMe） 4 ] [ClO 4 ]配体产生三坐标双核络合物[Cu 2 L] [ClO 4 ] 2（L = L 1，L 2或L 3），用NaN 3。NH 4 NCS，KOH或NaBH 4（L = L 1或L 3）通过消除高氯酸盐和X的配位得到双核四配位铜（I）配合物[Cu 2 L（X）2 ]（X = N 3，NCS，OH或BH

  DOI：

  10.1039/dt9910003405

文献信息

• Dinuclear ruthenium(III) complexes and their reactions with CO and NOCl: synthesis, characterization and electrochemical studies
  作者：Parimal Paul

  DOI：10.1016/s0277-5387(00)81481-3

  日期：1993.8

  A series of dinuclear ruthenium(III) complexes was synthesized by the reaction of RuCl3(AsPh3)2MeOH with the hexadentate ligands BDPE, BDAE and BDPX, with N2P4/N2As4 donor sites [BDPE = α,α′-bis(bis(2-(diphenylphosphino)ethyl)amino)ethane, BDAE = α,α′-bis(bis(2-(diphenylarsino)ethyl)amino)ethane and BDPX = α,α′-bis(bis(2-(diphenylphosphino)ethyl)amino)-m-xylene). In some cases the mixture of products

  通过RuCl 3（AsPh 3）2 MeOH与六齿配体BDPE，BDAE和BDPX的反应，合成了一系列双核钌（III）配合物，其中N 2 P 4 / N 2作为4个供体位点[BDPE =α， α'-双（双（2-（二苯基膦基）乙基）氨基）乙烷，BDAE =α，α'-双（双（2-（二苯基phenyl基）乙基）氨基）乙烷，BDPX =α，α'-双（双） （2-（二苯基膦基）乙基）氨基）-m-二甲苯）。在某些情况下，通过柱色谱法分离产物混合物并进行表征。通过使CO通过上述络合物的二氯甲烷溶液20小时，形成了CO加合物，其中钌（III）还原为钌（II）。NOCl与钌（III）配合物的反应导致NO置换每种金属一种Cl或AsPh 3，而钌（III）还原为钌（II）。通过31 P 1 H} NMR光谱数据确定了配合物的几何形状。还报道了这些络合物的循环伏安行为。
• Synthesis and characterization of mono and dinuclear Ru(II) complexes with hexadentate ligands having N2P4 and N2As4 donor atoms
  作者：M.M. Taqui Khan、Parimal Paul、Sapna Purohit

  DOI：10.1016/s0020-1693(00)80185-1

  日期：1991.11
• Synthesis, characterization, structures and reactivities of dinuclear copper(I) complexes of three new binucleating hexadentate ligands having N2P4 or N2As4 donor sites
  作者：Mirza Mohammed Taqui Khan、Parimal Paul、Krishnan Venkatasubramanian、Sapna Purohit

  DOI：10.1039/dt9910003405

  日期：——

  and 31P-1H} NMR spectral data. The molecular structures of [Cu2(L1)(PPh3)2Cl2]1 and [Cu2(L3)Cl2]3 were established by single-crystal X-ray diffraction [crystal data: 1, C94H90Cl2Cu2N2P6, triclinic, space group P, a= 11.711(2), b= 18.731(3), c= 10.080(1)Å, α= 91.22(1), β= 107.45(1), γ= 78.11(1)°, Z= 1, final R factor 0.040 (R′= 0.046) for 3715 observed reflections; 3, C64H64Cl2Cu2N2P4, triclinic, space

  具有N 2 P 4或N 2 As 4供体位点的三个新的双核六齿配体，即。N，N，N '，N'-四-[2-（二苯基膦基）乙基]乙烷-1,2-二胺（L 1），其a类似物（L 2）和1,3-bis bis [2-已经制备了（二苯基膦基）乙基]氨基甲基}苯（L 3）。配体与[Cu（PPh 3）3 Cl]反应，得到双核四配位铜（I）络合物[Cu 2（L 1）（PPh 3）2 Cl 2 ]，[Cu 2（L 2）（PPh 3） 2 Cl 2 ]和[Cu 2（L 3）Cl 2 ]。用[Cu（NCMe） 4 ] [ClO 4 ]配体产生三坐标双核络合物[Cu 2 L] [ClO 4 ] 2（L = L 1，L 2或L 3），用NaN 3。NH 4 NCS，KOH或NaBH 4（L = L 1或L 3）通过消除高氯酸盐和X的配位得到双核四配位铜（I）配合物[Cu 2 L（X）2 ]（X = N 3，NCS，OH或BH
• Reactions of a dinuclear copper(I) complex derived from a hexadentate ligand having N2As4 donor sites. Crystal structure of [Cu2(BDAE)(PPh3)2cl2]
  作者：Parimal Paul、K. Venkatasubramanian

  DOI：10.1016/s0277-5387(00)81766-0

  日期：1993.4

  The reactions of a tri-coordinate dinuclear copper(I) complex of the composition [Cu2(BDAE)](ClO4)2 (Where BDAE = alpha,alpha'-bisbis[2-(diphenylarsino)ethyl]amino}ethane) with some mono- and bidentate species having different donor atoms were studied. The reaction of the complex with anionic species such as LiCl, NaN3, NH4NCS and NaBH4 resulted in the formation of tetra-coordinate complexes of compositions [Cu2(BDAE)Cl2], [Cu2(BDAE)(N3)](ClO4), [Cu2(BDAE)(NCS)](ClO4) and [Cu2(BDAE)(BH4)2], respectively. The reactions of CS2 and thiourea gave the products [Cu2(BDAE)(CS2)2](ClO4)2 and [Cu2(BDAE)(H2NCSNH2)2](ClO2)2, respectively. The reactions of monodentate neutral molecules B (B = PPh3, AsPh3 and imidazole) yielded complexes of the composition [Cu2(BDAE)(B)2](ClO4)2. The reaction with pyridine in a 1:4 molar ratio gave a complex of composition [Cu2(BDAE)(C5H5N)4](ClO4)2. The bidentate ligands 1,2-bis(diphenylphosphino)methane/ethane (dppm/dppe) react with the complex to yield complexes of the composition [Cu2(BDAE)(dppm)](ClO4)2/[Cu2(BDAE)(dppe)](ClO4)2, in which dppm/dppe acts as a bridge between two metal centres. The reaction with bipyridine gave a tetra-coordinate complex of the composition [Cu2(BDAE)(C10H8N2)2](ClO4)2. The molecular structure of the complex [Cu2(BDAE)(PPh3)2Cl2] was established by single-crystal X-ray diffraction. The cyclic voltammetric behaviour of all of these complexes was investigated.