{Cu2(α,α'-bis(bis{2-(diphenylarsino)ethyl}amino)ethane)Cl2} | 148632-53-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {Cu2(α,α'-bis(bis{2-(diphenylarsino)ethyl}amino)ethane)Cl2}
• CAS: 148632-53-5
• 化学式: C₅₈H₆₀As₄Cl₂Cu₂N₂
• 分子量: 1282.81
• InChiKey: GHEZBTQSKYNUNQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  {Cu2(α,α'-bis(bis{2-(diphenylarsino)ethyl}amino)ethane)}(ClO4)2 在 lithium chloride 作用下， 以 丙酮 为溶剂， 以70-80的产率得到{Cu2(α,α'-bis(bis{2-(diphenylarsino)ethyl}amino)ethane)Cl2}
  参考文献：
  名称：

  Reactions of a dinuclear copper(I) complex derived from a hexadentate ligand having N2As4 donor sites. Crystal structure of [Cu2(BDAE)(PPh3)2cl2]

  摘要：

  The reactions of a tri-coordinate dinuclear copper(I) complex of the composition [Cu2(BDAE)](ClO4)2 (Where BDAE = alpha,alpha'-bis{bis[2-(diphenylarsino)ethyl]amino}ethane) with some mono- and bidentate species having different donor atoms were studied. The reaction of the complex with anionic species such as LiCl, NaN3, NH4NCS and NaBH4 resulted in the formation of tetra-coordinate complexes of compositions [Cu2(BDAE)Cl2], [Cu2(BDAE)(N3)](ClO4), [Cu2(BDAE)(NCS)](ClO4) and [Cu2(BDAE)(BH4)2], respectively. The reactions of CS2 and thiourea gave the products [Cu2(BDAE)(CS2)2](ClO4)2 and [Cu2(BDAE)(H2NCSNH2)2](ClO2)2, respectively. The reactions of monodentate neutral molecules B (B = PPh3, AsPh3 and imidazole) yielded complexes of the composition [Cu2(BDAE)(B)2](ClO4)2. The reaction with pyridine in a 1:4 molar ratio gave a complex of composition [Cu2(BDAE)(C5H5N)4](ClO4)2. The bidentate ligands 1,2-bis(diphenylphosphino)methane/ethane (dppm/dppe) react with the complex to yield complexes of the composition [Cu2(BDAE)(dppm)](ClO4)2/[Cu2(BDAE)(dppe)](ClO4)2, in which dppm/dppe acts as a bridge between two metal centres. The reaction with bipyridine gave a tetra-coordinate complex of the composition [Cu2(BDAE)(C10H8N2)2](ClO4)2. The molecular structure of the complex [Cu2(BDAE)(PPh3)2Cl2] was established by single-crystal X-ray diffraction. The cyclic voltammetric behaviour of all of these complexes was investigated.

  DOI：

  10.1016/s0277-5387(00)81766-0