vinyl ether of propylcellosolve | 18854-26-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: vinyl ether of propylcellosolve
• 英文别名: 1-vinyloxy-2-propoxyethane；1-Vinyloxy-2-propoxy-ethan；(2-propoxy-ethoxy)-ethene；1-(2-Ethenoxyethoxy)propane
• CAS: 18854-26-7
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: DSCPDECZHTVJOJ-UHFFFAOYSA-N

物化性质

• 沸点：
  140 °C
• 密度：
  0.8665 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  9
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-乙烯氧基乙醇 、 溴丙烷 在 苄基三乙基氯化铵 sodium hydroxide 作用下， 以 水 为溶剂， 反应 7.0h， 以86.1%的产率得到vinyl ether of propylcellosolve
  参考文献：
  名称：

  Trofimov, B. A.; Lavrov, V. I.; Parshina, L. N., Journal of applied chemistry of the USSR, 1981, vol. 54, # 8, p. 1671 - 1673

  摘要：

  DOI：

文献信息

• METHOD FOR REMOVING OR COLLECTING 2-ALKOXYETHANOL, AND METHOD FOR PRODUCING (2-ALKOXYETHYL) VINYL ETHER
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20190210949A1

  公开（公告）日：2019-07-11

  To provide a method capable of easily and efficiently removing a 2-alkoxyethanol from a mixture containing the 2-alkoxyethanol and a (2-alkoxyethyl) vinyl ether while suppressing a decrease in the yield of (2-alkoxyethyl) vinyl ether. A method for removing a 2-alkoxyethanol, including the step of adding one or more azeotropic solvents selected from the group consisting of alkanes having 7 to 8 carbon atoms and cycloalkanes having 7 to 8 carbon atoms to a mixture containing the 2-alkoxyethanol represented by the following formula (1) R—O—CH 2 CH 2 OH  (1) where R represents an alkyl group having 1 to 4 carbon atoms, and a (2-alkoxyethyl) vinyl ether represented by the following formula (2) R—O—CH 2 CH 2 O—CH═CH 2 (2) where R has the same meaning as R in the formula (1), and subjecting the resulting mixture to azeotropic distillation.

  提供一种能够轻松高效地从含有2-烷氧基乙醇和(2-烷氧基乙基)乙烯醚的混合物中去除2-烷氧基乙醇且抑制(2-烷氧基乙基)乙烯醚收率下降的方法。该方法包括以下步骤：向含有2-烷氧基乙醇（化学式（1））和(2-烷氧基乙基)乙烯醚（化学式（2））的混合物中添加从以下组中选择的一种或多种共沸溶剂，所述组包括碳原子数为7到8的烷烃和环烷烃，然后将得到的混合物进行共沸蒸馏。 其中，化学式（1）中，R表示具有1到4个碳原子的烷基；化学式（2）中，R与化学式（1）中的R具有相同的含义。
• Reactive diluent and curable resin composition
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：US20030199655A1

  公开（公告）日：2003-10-23

  The present invention provides a reactive diluent composition which overcomes drawbacks of both the radical-cure and the cationic-cure reactive diluents and can be applied in a broad variety of uses such as paints, inks, adhesives, pressure sensitive adhesives, surface-modifiers, and molding materials; a curable resin composition containing the same; an activated energy ray-curable resin composition; and an activated energy ray-curable ink composition for ink-jet printing. A reactive diluent composition comprising a vinyl ether group-containing (meth)acrylic ester represented by the following general formula (1): CH 2 ═CR 1 —COO—R 2 —O—CH═CH—R 3 (1) wherein R 1 represents a hydrogen atom or a methyl group; R 2 represents an organic residue of 2 to 20 carbon atoms; R 3 represents a hydrogen atom or an organic residue of 1 to 11 carbon atoms and a hydroxyl group-containing polymerizable compound and/or divinyl ether.

  本发明提供了一种反应性稀释剂组合物，克服了自由基固化和阳离子固化反应性稀释剂的缺点，并可广泛应用于涂料、油墨、粘合剂、压敏粘合剂、表面改性剂和模塑材料等各种用途；一种可固化树脂组合物，其中包含该反应性稀释剂组合物；一种活性能量射线可固化的树脂组合物；以及适用于喷墨打印的活性能量射线可固化的油墨组合物。所述反应性稀释剂组合物包括以下通式（1）所表示的含乙烯基醚基的（甲）丙烯酸酯：CH2═CR1—COO—R2—O—CH═CH—R3(1)，其中R1表示氢原子或甲基基团；R2表示2至20个碳原子的有机残基；R3表示氢原子或1至11个碳原子的有机残基和一个含羟基的可聚合化合物和/或二乙烯醚。
• TREATMENT OF HELICOBACTER PYLORI INFECTIONS
  申请人：Schramm Vern L.

  公开号：US20150210701A1

  公开（公告）日：2015-07-30

  Methods of treating infections due to Helicobacter pylori ( H. pylori ), in particular in subjects having a peptic ulcer, are disclosed where the methods comprise administering inhibitors of H. pylori MTAN (5′-methylthioadenosine nucleosidase) to the subject.

  本发明公开了一种治疗幽门螺杆菌（H. pylori）感染的方法，特别是针对患有消化性溃疡的个体，其中该方法包括向该个体投与H. pylori MTAN（5'-甲基硫腺苷核苷酸酶）的抑制剂。
• FUMARIC ACID DIESTER-CINNAMIC ACID ESTER-BASED COPOLYMER, PRODUCTION METHOD THEREOF AND FILM USING THE SAME
  申请人：TOSOH CORPORATION

  公开号：US20150291751A1

  公开（公告）日：2015-10-15

  To provide a novel fumaric acid diester-cinnamic acid ester-based copolymer having a high molecular weight, which is expected to maintain excellent strength or ensures excellent toughness even when formed into a film, a method for efficiently producing the copolymer, and a film using the same. The fumaric acid diester-cinnamic acid ester-based copolymer contains a fumaric acid diester residue unit, a cinnamic acid ester residue unit having an alkyl group with a carbon number of 1 to 6, and a residue unit of a polyfunctional monomer having two or more radical polymerizable functional groups.

  提供一种具有高分子量的新型顺丁烯二酸二酯-肉桂酸酯共聚物，预计即使形成薄膜也能保持优异的强度或确保出色的韧性，以及一种高效生产该共聚物的方法和使用该共聚物的薄膜。该顺丁烯二酸二酯-肉桂酸酯共聚物包含顺丁烯二酸二酯残基单元、具有碳数为1至6的烷基的肉桂酸酯残基单元和具有两个或更多自由基聚合官能团的多官能单体残基单元。
• Anti-microbic agent
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0891708A1

  公开（公告）日：1999-01-20

  The invention relates to the use of a copolymer comprising at least two different ethylenically unsaturated monomers A and B or a derivative of said copolymer as an anti-bacterial, an anti-mycotic agent or both wherein monomer A is according to the formula:R1-CH=CH-R2 and wherein monomer B is according to the formula:R3-C(R1)=C(R2)-R4 wherein R1 and R2 are independently selected from hydrogen; hydroxy; halogen; carboxy, sulfo, phenyl, phenoxy, C1-6 alkyl, C1-6 alkoxy, C1-6 aminoalkyl, C1-6 haloalkyl wherein the halogen is selected from chlorine, bromine, iodine, and fluorine, preferably chlorine; C1-6 alkylphenyl; amino and C1-6 alkylamino, R3 is an acidic group or a derivative thereof and R4 is a group selected from any of the definitions given hereinbefore for R1, R2 or R3, with the proviso that neither monomer A nor monomer B is an ester having a quaternary ammonium compound.

  本发明涉及一种由至少两种不同的乙烯基不饱和单体 A 和 B 或上述共聚物的衍生物组成的共聚物作为抗菌剂、抗霉菌剂或二者兼用的用途，其中单体 A 的结构式为：R1-CH=CH-R2，单体 B 的结构式为：R3-C(R1)=C(R2)-R4，其中 R1 和 R2 独立地选自氢、羟基、卤素、羧基、磺基、苯基、苯氧基、C1-CH=CH-R2：R3-C(R1)=C(R2)-R4 其中 R1 和 R2 独立选自氢；羟基；卤素；羧基、磺基、苯基、苯氧基、C1-6 烷基、C1-6 烷氧基、C1-6 氨基烷基、C1-6 卤代烷基，其中卤素选自氯、溴、碘和氟，优选氯；C1-6烷基苯基；氨基和 C1-6 烷基氨基，R3 是酸性基团或其衍生物，R4 是选自 R1、R2 或 R3 前述定义中的任一基团，但单体 A 和单体 B 都不是具有季铵盐化合物的酯。