6-methacryloyloxyhexanoic acid | 111720-19-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 6-methacryloyloxyhexanoic acid
• 英文别名: Hexanoic acid, 6-[(2-methyl-1-oxo-2-propenyl)oxy]-；6-(2-methylprop-2-enoyloxy)hexanoic acid
• CAS: 111720-19-5
• 化学式: C₁₀H₁₆O₄
• 分子量: 200.235
• InChiKey: TUOVQJGQJXCCGF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-methacryloyloxyhexanoic acid 在 草酰氯 、 N,N-二甲基甲酰胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以97%的产率得到6-methacryloyloxyhexanoic acid chloride
  参考文献：
  名称：

  基于可聚合硫脲衍生物的牙科材料

  摘要：

  可自由基聚合的牙科材料，其包含氢过氧化物和根据下式(I)的硫脲衍生物的组合作为用于自由基聚合的引发剂体系： 其中R不存在或为(n+1)价的芳族、脂族、直链或支链C1‑C50烃基，其可被一个或多个醚、硫醚、酯、酰胺或氨基甲酸酯基团间隔；PG为可自由基聚合的(甲基)丙烯酸酯、(甲基)丙烯酰胺或乙烯基基团；并且n为1、2或3。

  公开号：

  CN114848503A
• 作为产物：
  描述：

  6-羟基己酸叔丁酯 在 4-二甲氨基吡啶 、 三乙胺 、 三氟乙酸 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 20.0h， 生成 6-methacryloyloxyhexanoic acid
  参考文献：
  名称：

  基于可聚合硫脲衍生物的牙科材料

  摘要：

  可自由基聚合的牙科材料，其包含氢过氧化物和根据下式(I)的硫脲衍生物的组合作为用于自由基聚合的引发剂体系： 其中R不存在或为(n+1)价的芳族、脂族、直链或支链C1‑C50烃基，其可被一个或多个醚、硫醚、酯、酰胺或氨基甲酸酯基团间隔；PG为可自由基聚合的(甲基)丙烯酸酯、(甲基)丙烯酰胺或乙烯基基团；并且n为1、2或3。

  公开号：

  CN114848503A

文献信息

• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• GRADIENT OPTICAL POLYMER NANOCOMPOSITES
  申请人：State of Oregon acting by and through the State Board of Higher Education on behalf of the Univers

  公开号：US20150023643A1

  公开（公告）日：2015-01-22

  Gradient index optical materials are formed by drop by drop dispensing of nanoparticle/monomer suspensions. Refractive index variations are defined by nanoparticle concentrations that can vary in three dimensions. Droplets of differing compositions can be mixed, and droplets or layers or droplets are partially cross-linked by exposure to ultraviolet radiation prior to dispensing additional droplets. Gradient index optical elements such as lenses, prisms, and waveguides can be formed in flexible polymer layers.

  渐变折射率光学材料是通过滴滴分配纳米颗粒/单体悬浮液形成的。折射率变化由纳米颗粒浓度在三个维度上变化定义。不同成分的液滴可以混合，液滴或液滴层可以在分配额外液滴之前通过紫外线辐射部分交联。可以在柔性聚合物层中形成渐变折射率光学元件，如透镜、棱镜和波导。
• Anti-fouling Paints and Coatings
  申请人：Reactive Surfaces LTD

  公开号：US20150191607A1

  公开（公告）日：2015-07-09

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peptide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文披露了聚合材料，例如涂层、塑料、层压材料、复合材料、弹性体、粘合剂或密封剂；表面处理，例如纺织品整理或蜡；填充剂，用于这种聚合材料或表面处理，包括酯酶（例如脂肪水解酶、硫酸酯水解酶、有机磷化合物降解酶）的酶，降解细胞壁和/或细胞膜成分的酶（例如溶菌酶、裂解转葡糖苷酶），生物杀菌或生物稳定肽，和/或肽酶。本文还披露了通过将酶并入能够通过脂肪水解酶、水解酶和/或脲酶的活性进行化学交联的材料中，改变材料性能（例如使用寿命、柔韧性或刚度）的方法。
• Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheets using the composition
  申请人：NITTO DENKO CORPORATION

  公开号：EP0704509A1

  公开（公告）日：1996-04-03

  A pressure-sensitive adhesive composition showing the adhesive force and the cohesive force with a good stability is disclosed. The composition comprises a copolymer of a (meth)acrylic acid alkyl ester (a) having an alkyl group having from 2 to 14 carbon atoms and a (meth)acrylic acid alkyl ester (b) having a carboxyl group or a hydroxyl group at the terminal and having an alkyl group having from 3 to 14 total carbon atoms as the ester side chain. In particular, when the carbon atom number of the alkyl group of the monomer (b) is less by one than or not less than the same number as the carbon atom number of the alkyl group of the monomer (a), the effect of the functional group can be most effectively exhibited. A pressure-sensitive adhesive tape or sheet is also disclosed, comprising a support having formed at least one surface thereof the pressure-sensitive adhesive layer comprising the pressure-sensitive adhesive composition.

  本发明公开了一种压敏胶组合物，该组合物具有良好的粘合力和内聚力，并具有良好的稳定性。该组合物包括具有 2 至 14 个碳原子的烷基的（甲基）丙烯酸烷基酯（a）和末端具有羧基或羟基并具有 3 至 14 个碳原子的烷基作为酯侧链的（甲基）丙烯酸烷基酯（b）的共聚物。特别是当单体（b）的烷基的碳原子数比单体（a）的烷基的碳原子数少一个或不少于相同数目时，官能团的效果可以最有效地表现出来。本发明还公开了一种压敏胶带或胶片，包括一个支撑物，其至少一个表面形成了包含压敏胶组合物的压敏胶层。
• Mesogen containing compounds
  申请人：TRANSITIONS OPTICAL, INC.

  公开号：EP2698412A2

  公开（公告）日：2014-02-19

  Compounds including at least one mesogenic substructure and at least one long flexible segment and methods of synthesizing the same,are disclosed. Formulations which include various embodiments of the mesogen containing compounds and their use in articles of manufacture and ophthalmic devices are also disclosed.

  本发明公开了包含至少一种介源亚基结构和至少一种长柔性段的化合物以及合成方法。此外，还公开了包括含介原化合物的各种实施方案的制剂及其在制造品和眼科设备中的用途。