3-Ethyl-4-methylthiazoliumion | 45515-51-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-Ethyl-4-methylthiazoliumion
• 英文别名: 3-ethyl-4-methylthiazolium；3-Ethyl-4-methyl-1,3-thiazol-3-ium
• CAS: 45515-51-3
• 化学式: C₆H₁₀NS
• 分子量: 128.218
• InChiKey: RINJIXCXBIVUQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  32.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-Ethyl-4-methylthiazoliumion 在 水 作用下， 生成 (Z)-2-(Ethyl-formyl-amino)-propene-1-thiol anion
  参考文献：
  名称：

  Barrabass, Susanne; Heiber-Langer, Irmgard; Knoche, Wilhelm, Journal of the Chemical Society. Perkin transactions II, 1994, # 1, p. 131 - 134

  摘要：

  DOI：
• 作为产物：
  描述：

  (Z)-2-(Ethyl-formyl-amino)-propene-1-thiol anion 在 氢气 作用下， 生成 3-Ethyl-4-methylthiazoliumion 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Barrabass, Susanne; Heiber-Langer, Irmgard; Knoche, Wilhelm, Journal of the Chemical Society. Perkin transactions II, 1994, # 1, p. 131 - 134

  摘要：

  DOI：

文献信息

• An Unprecedented Chemospecific and Stereoselective Tandem Nucleophilic Addition/Cycloaddition Reaction of Nucleophilic Carbenes with Ketenimines
  作者：Ying Cheng、Yang-Guang Ma、Xiao-Rong Wang、Jun-Ming Mo

  DOI：10.1021/jo802289s

  日期：2009.1.16

  study of the reaction between nucleophilic carbenes and ketenimines is reported. The interaction of thiazole and benzothiazole carbenes with ketenimines proceeded in a chemospecific and stereoselective manner to produce thiazole- and benzothiazole-spiro-pyrrole derivatives generally in good yields. The reaction was proposed to proceed via a tandem nucleophilic addition of carbene to the C═N bond of

  报道了对亲核性卡宾与酮亚胺之间反应的第一项研究。噻唑和苯并噻唑碳烯与酮亚胺的相互作用以化学特异性和立体选择性的方式进行，通常以高收率生产噻唑-和苯并噻唑-螺-吡咯衍生物。提出该反应是通过将卡宾串联亲核加成至酮亚胺的C═N键，然后将1，3-偶极中间体与酮亚胺的C═C键逐步[3 + 2]环加成而进行的。该反应为构建新的多官能噻唑-螺-吡咯或苯并噻唑-螺-吡咯化合物提供了有力的方案，而其他方法不易获得。
• Electric Double-Layer Capacitor
  申请人：Kikuchi Taketoshi

  公开号：US20090103241A1

  公开（公告）日：2009-04-23

  An activated carbon comprising a carbonized and activated compound represented by the formula (1): (wherein, R represents a hydrocarbon group having 1 to 12 carbon atoms, said hydrocarbon group may be optionally substituted with hydroxyl group, alkyl group, alkoxy group, aryl group, aryloxy group, sulfonyl group, halogen atoms, nitro group, thioalkyl group, cyano group, carboxyl group, amino group or amide group, R′ represents hydrogen atom or methyl group, and n represents an integer of 4, 6, or 8).

  一种活性炭，包括由式（1）所表示的碳化和活化化合物： 其中，R表示具有1至12个碳原子的碳氢基团，该碳氢基团可以选择地被羟基、烷基、烷氧基、芳基、芳氧基、磺酰基、卤素原子、硝基、硫代烷基、氰基、羧基、氨基或酰胺基取代；R′表示氢原子或甲基基团；n表示4、6或8的整数。
• ELECTRIC DOUBLE LAYER CAPACITOR
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1905740A1

  公开（公告）日：2008-04-02

  An activated carbon comprising a carbonized and activated compound represented by the formula (1): (wherein, R represents a hydrocarbon group having 1 to 12 carbon atoms, said hydrocarbon group may be optionally substituted with hydroxyl group, alkyl group, alkoxy group, aryl group, aryloxy group, sulfonyl group, halogen atoms, nitro group, thioalkyl group, cyano group, carboxyl group, amino group or amide group, R' represents hydrogen atom or methyl group, and n represents an integer of 4, 6, or 8).

  一种活性炭，包含由式（1）代表的碳化和活化化合物： (其中，R 代表具有 1 至 12 个碳原子的烃基，所述烃基可选择性地被羟基、烷基、烷氧基、芳基、芳氧基、磺酰基、卤素原子、硝基、硫代烷基、氰基、羧基、氨基或酰胺基取代，R'代表氢原子或甲基，n 代表 4、6 或 8 的整数）。
• ACTIVATED CARBON AND METHOD FOR PRODUCING THE SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2093191A1

  公开（公告）日：2009-08-26

  An activated carbon obtained by activating a carbide of a compound (1) with an alkali metal hydroxide, wherein the compound (1) is obtained, for example, by dehydration condensation of a resorcinol and an aldehyde using an acid catalyst.

  通过用碱金属氢氧化物活化化合物(1)的碳化物而获得的活性炭，其中化合物(1)例如是通过使用酸催化剂对间苯二酚和醛进行脱水缩合而获得的。
• ACTIVATED CARBON AND PROCESS FOR PRODUCING THE SAME
  申请人：Kurakane Kosuke

  公开号：US20100321863A1

  公开（公告）日：2010-12-23

  An activated carbon obtained by activating a carbide of a compound (1) with an alkali metal hydroxide, wherein the compound (1) is obtained, for example, by dehydration condensation of a resorcinol and an aldehyde using an acid catalyst.