2-butenoic acid 2-phenylethyl ester | 6289-54-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-butenoic acid 2-phenylethyl ester
• 英文别名: 2-Phenylethyl but-2-enoate
• CAS: 6289-54-9
• 化学式: C₁₂H₁₄O₂
• 分子量: 190.242
• InChiKey: DVHGIHSWUYRIPZ-UHFFFAOYSA-N

物化性质

• LogP：
  3.122 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  巴豆酸 、 苯乙醇 在 N,N-二甲基苯胺 3-甲基-1,3-苯并噻唑-2-硒酮 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 为溶剂， 反应 9.0h， 以57%的产率得到2-butenoic acid 2-phenylethyl ester
  参考文献：
  名称：

  INTERMOLECULAR DEHYDRATION BETWEEN CARBOXYLIC ACIDS AND ALCOHOLS BY THE USE OF DIETHYL AZODICARBOXYLATE AND 3-METHYLBENZOTHIAZOLE-2-SELONE

  摘要：

  在二乙基偶氮二羧酸酯和3-甲基苯并噻唑-2-硒酮存在下，羧酸与醇的反应生成相应的酯，并保持醇碳原子的构型。

  DOI：

  10.1246/cl.1984.855

文献信息

• Polymer latex of high acrylonitrile content, film, pattern forming material and lithographic printing plate precursor using the same, and method for production of polymer latex
  申请人：FUJIFILM Corporation

  公开号：EP1905787A2

  公开（公告）日：2008-04-02

  A method for producing a polymer latex includes: mixing a polymerizable monomer in which acrylonitrile accounts for 70% by weight or more of a total of the polymerizable monomer, water and a polymerization initiator to conduct emulsion polymerization; and distilling off a monomer unpolymerized in the emulsion polymerization.

  生产聚合物胶乳的方法包括：混合可聚合单体（其中丙烯腈占可聚合单体总重量的 70% 或以上）、水和聚合引发剂，以进行乳液聚合；以及蒸馏掉乳液聚合中未聚合的单体。
• Process for producing acrylonitrile-containing polymer latex
  申请人：FUJIFILM Corporation

  公开号：EP1935910A2

  公开（公告）日：2008-06-25

  A process for producing a polymer latex includes a step of mixing at least one kind of polymerizable monomer with water and a polymerization initiator to perform a polymerization, wherein the at least one kind of polymerizable monomer includes an acrylonitrile in an amount of 50 mass% or more based on a total amount of the at least one kind of polymerizable monomer.

  一种生产聚合物胶乳的工艺包括将至少一种可聚合单体与水和聚合引发剂混合以进行聚合的步骤，其中至少一种可聚合单体包括丙烯腈，其用量为至少一种可聚合单体总量的 50 质量%或以上。
• Dye-containing curable composition, color filter, and producing process thereof
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030232259A1

  公开（公告）日：2003-12-18

  A dye-containing curable composition including a binder and a dye that is soluble in an organic solvent, in which the binder contains a structural unit represented by the following general formula (I) and has a glass transition temperature in a range of 0 to 250° C. In general formula (I), R 1 represents a hydrogen atom or a methyl group; R 2 represents an oxygen atom, —NH—, or —N(R 3 -R 4 )—; R 3 represents a substituted or unsubstituted divalent group; and R 4 represents a group containing an unsaturated double bond. 1

  一种含染料的可固化组合物，包括一种粘合剂和一种可溶于有机溶剂的染料，其中粘合剂含有由以下通式（I）表示的结构单元，其玻璃化转变温度在 0 至 250 摄氏度范围内。 在通式（I）中，R 1 代表氢原子或甲基；R 2 代表氧原子、-NH- 或-N(R 3 -R 4 )-; R 3 代表取代或未取代的二价基团；和 R 4 代表含有不饱和双键的基团。 1
• Alkali-soluble gap filling material forming composition for lithography
  申请人：Takei Satoshi

  公开号：US20060041078A1

  公开（公告）日：2006-02-23

  There is provided a gap fill material forming composition for lithography that is used in dual damascene process and contributes toward an improvement in production efficiency. Concretely, it is a gap fill material forming composition characterized in that the composition is used in manufacture of semiconductor device by a method comprising coating a photoresist on a substrate having a hole with aspect ratio shown in height/diameter of 1 or more, and transferring an image to the substrate by use of lithography process, and that the composition is coated on the substrate prior to coating of the photoresist, and comprises a polymer having a hydroxy group or a carboxy group and a crosslinking agent. The gap fill material layer obtained from the gap fill material forming composition can be etched back with an alkaline aqueous solution.

  本发明提供了一种用于光刻的间隙填充材料成型组合物，该组合物可用于双大马士革工艺，并有助于提高生产效率。具体地说，它是一种间隙填充材料成形组合物，其特征在于，该组合物用于通过在具有高宽比为 1 或以上的孔的基板上涂布光刻胶，并通过光刻工艺将图像转移到基板上的方法制造半导体器件，并且该组合物在涂布光刻胶之前涂布在基板上，由具有羟基或羧基的聚合物和交联剂组成。由间隙填充材料成型组合物得到的间隙填充材料层可以用碱性水溶液蚀刻回来。
• Lithographic printing plate precursor using a polymer latex of high acrylonitrile content
  申请人：FUJIFILM Corporation

  公开号：EP1905787B1

  公开（公告）日：2011-05-18