3-amino-1-(2-pyridyl)-2-buten-1-one | 10284-86-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-amino-1-(2-pyridyl)-2-buten-1-one
• 英文别名: 3-Amino-1-(2-pyridyl)-2-buten-1-one；3-amino-1-pyridin-2-ylbut-2-en-1-one
• CAS: 10284-86-3
• 化学式: C₉H₁₀N₂O
• 分子量: 162.191
• InChiKey: ZOYVGZYONWUAFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  56
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-amino-1-(2-pyridyl)-2-buten-1-one 、 丁氧基(二苯基)硼烷 以 氯仿 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  Boron chelate complexes with some enaminones and diketones containing the pyridine fragment and their mutual transformations in solutions

  摘要：

  The interaction of Ph(2)BOBu with 4-amino-4-(2-pyridyl)-3-buten-2-one, 3-amino-1 -(2-pyridyl)-2-buren-1-one, and 1-(2-pyridyl)butan-1,3-dione was investigated. The 5- or 6-membered chelates with N, O- or N, N-coordination of boron are formed depending on the pyridine-containing ligand structure. These complexes are capable of mutual transformation in solutions.

  DOI：

  10.1007/bf01435803

文献信息

• Boron chelate complexes with some enaminones and diketones containing the pyridine fragment and their mutual transformations in solutions
  作者：V. A. Dorokhov、V. S. Bogdanov、L. S. Vasil'ev、Nguen Cuu Khoa

  DOI：10.1007/bf01435803

  日期：1996.3

  The interaction of Ph(2)BOBu with 4-amino-4-(2-pyridyl)-3-buten-2-one, 3-amino-1 -(2-pyridyl)-2-buren-1-one, and 1-(2-pyridyl)butan-1,3-dione was investigated. The 5- or 6-membered chelates with N, O- or N, N-coordination of boron are formed depending on the pyridine-containing ligand structure. These complexes are capable of mutual transformation in solutions.