tris(4-(anthracen-9-yl)phenyl)amine | 914370-95-9

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: tris(4-(anthracen-9-yl)phenyl)amine
• 英文别名: (TPA-AN)；4-(9-Anthracenyl)-N,N-bis[4-(9-anthracenyl)phenyl]benzenamine；4-anthracen-9-yl-N,N-bis(4-anthracen-9-ylphenyl)aniline
• CAS: 914370-95-9
• 化学式: C₆₀H₃₉N
• 分子量: 773.976
• InChiKey: GTKNNFWHHKOLGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.5
• 重原子数：
  61
• 可旋转键数：
  6
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-溴蒽 在 四(三苯基膦)钯 、 正丁基锂 、 sodium carbonate 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 72.5h， 生成 tris(4-(anthracen-9-yl)phenyl)amine
  参考文献：
  名称：

  Highly efficient deep-blue electroluminescence based on the triphenylamine-cored and peripheral blue emitters with segregative HOMO–LUMO characteristics

  摘要：

  为了获得高效稳定的蓝色电致发光，特意设计并合成了两种新型星形化合物，它们由中心三苯胺（TPA）和外围蒽（AN）或菲（PA）两个官能团组成，在最高占位分子轨道和最低未占位分子轨道（HOMO 和 LUMO）之间具有明显的分离电子密度分布特征。作为发光层，它们不仅表现出高效的深蓝色电致发光，而且由于结合了多种优势特性（电化学、热和形态稳定性），在有机发光二极管（OLED）中也具有良好的稳定性。特别是对于三苯胺羰基菲（TPA-PA）来说，7.23% 的外部量子效率是未掺杂深蓝色有机发光二极管的最佳结果，而且该器件的寿命也得到了提高，在相同的器件条件下是 2-甲基-9,10-二（2-萘基）蒽（MADN）的两倍。

  DOI：

  10.1039/c1jm14639d

文献信息

• Extended Fluorochromism of Anthracene Trimers with a<i>meta</i>‐Substituted Triphenylamine or Triphenylphosphine Core
  作者：Zhiou Li、Hiromi Ishizuka、Yoshihisa Sei、Munetaka Akita、Michito Yoshizawa

  DOI：10.1002/asia.201200310

  日期：2012.8

  Combining meta‐triphenylamine or triphenylphosphine with three anthracene fluorophores gives rise to fluorescent non‐planar triskelions 1 and 2. The emissive properties of 1 are highly solvatochromic, yielding blue to pale green and even pale yellow fluorescence, whereas the blue emission of 2 is solvent‐insensitive. Anthracene trimers 1 and 2 are both emissive in the solid state, displaying yellow

  将间三苯胺或三苯膦与三个蒽荧光团结合使用会产生荧光非平面三骨架1和2。的发射性质1是高度溶剂化，得到蓝色至浅绿色和甚至淡黄色荧光，而蓝色发射2是溶剂不敏感。蒽三聚体1和2均以固态发射，分别显示出黄色和浅绿色荧光，并具有中等的量子产率。
• A Fluorescent Organic Probe for Naked‐Eye Detection of Chloromethanes
  作者：Xinhan Wang、Jiawei Li、Cheng Chen、Mingyan Wu

  DOI：10.1002/cplu.202400354

  日期：2024.10

  An organic fluorescent probe has been synthesized for naked-eye recognition of chloromethanes such as CH2Cl2, CHCl3, and CCl4. The fluorescence response mechanism was elucidated through the guest-loaded crystal structure analysis.

  已经合成了一种有机荧光探针，用于肉眼识别氯甲烷，如 CH2、Cl2、CHCl3 和 CCl4。通过载客体晶体结构分析阐明荧光响应机制。
• ORGANIC ELECTROLUMINESCENT ELEMENT AND DISPLAY
  申请人：Kambe Emiko

  公开号：US20110024736A1

  公开（公告）日：2011-02-03

  An organic electroluminescent includes an organic layer with a total thickness of 150 nm or over is included between an anode and a cathode. The organic layer includes a light-emitting layer containing a host material of a polycyclic aromatic hydrocarbon compound with a basic skeleton having three to seven ring members, and hole supply layers arranged between the anode and the light-emitting layer and having a smaller thickness than a thickness of the light-emitting layer.
• ORGANIC ELECTROLUMINESCENT ELEMENT AND DISPLAY DEVICE
  申请人：SONY CORPORATION

  公开号：US20150171356A1

  公开（公告）日：2015-06-18

  An organic electroluminescence device that includes, between an anode 41 and a cathode 42 , an organic layer stacked structure 43 that comprises stacked plural emitting layers that emit light of different colors, wherein the organic electroluminescent device comprises, between the emitting layers, at least one intermediate layer that comprises a compound represented by the following formula (1) in which at least one of Ar 1 , Ar 2 and Ar 3 is a group represented by the following formula (2):
• US8530062B2
  申请人：——

  公开号：US8530062B2

  公开（公告）日：2013-09-10