phosphorus acid dichloride cyclohexyl ester | 54921-67-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: phosphorus acid dichloride cyclohexyl ester
• 英文别名: cyclohexyl phosphorodichloridite；Cyclohexyl phosphorodichloridoite；dichloro(cyclohexyloxy)phosphane
• CAS: 54921-67-4
• 化学式: C₆H₁₁Cl₂OP
• 分子量: 201.033
• InChiKey: UZHPBEXRXQZMSO-UHFFFAOYSA-N

物化性质

• 沸点：
  217.1±7.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2909209000

反应信息

• 作为反应物：
  描述：

  phosphorus acid dichloride cyclohexyl ester 在 磺酰氯 作用下， 以 四氯化碳 为溶剂， 生成 Ethyl-cyclohexyl-chlor-phosphat
  参考文献：
  名称：

  Maklyaev,F.L. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3357 - 3360

  摘要：

  DOI：
• 作为产物：
  描述：

  氯磷酸二环己基酯 生成 亚磷酸三环己酯 、 phosphorus acid dichloride cyclohexyl ester
  参考文献：
  名称：

  Chauzov, V. A.; Studnev, Yu. N.; Ragulin, L. I., Journal of general chemistry of the USSR, 1989, vol. 59, # 6.1, p. 1146 - 1148

  摘要：

  DOI：

文献信息

• The Synthesis and Some Chemical Properties of New 1,2:5,6-DI-<i>O</i>-Isopropylidene-α -D-Glucofuranose Hydrophosphoryl Derivatives
  作者：Edvard E. Nifantyev、Tatyana S. Kukhareva、Dmitriy V. Khodarev、Larisa K. Vasyanina

  DOI：10.1080/104265090968073

  日期：2005.12

  Methods for the synthesis of major monosaccharide hydrophosphoryl derivatives have been developed with the phosphorylation of 1,2:5,6-di-O-isopropylidene-α -D-glucofuranose (diacetoneglucose) as an example. The study of their chemical transformations has been launched.

  以 1,2:5,6-二-O-异亚丙基-α-D-呋喃葡萄糖（二丙酮葡萄糖）的磷酸化为例，开发了主要单糖氢磷酰衍生物的合成方法。已经启动了对其化学转化的研究。
• Production of phosphinites and phosphonites
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0233716A1

  公开（公告）日：1987-08-26

  Phosphinites or phosphonites are produced by reacting potassium or sodium aryls with compounds of formula ROPCIX in which X is an R'O, Cl or aryl group, R and R' being alkyl or cycloalkyl groups at a temperature of at most 10°C.

  亚膦酸盐或亚膦酸盐是通过芳基钾或钠与式 ROPCIX 的化合物反应制得的，式中 X 为 R'O、Cl 或芳基，R 和 R' 为烷基或环烷基，反应温度不超过 10°C。
• Process for transhalogenating a halophosphorus compound with fluoride
  申请人：ETHYL CORPORATION

  公开号：EP0312790A2

  公开（公告）日：1989-04-26

  Phosphorus compounds having at least one chlorine, bromine or iodine bonded directly to phosphorus are trans­halogenated with fluorine by reaction with a fluoride salt, e.g., KF or ammonium fluoride, in the presence of a hydrogen halide salt of a pyridine-type nitrogen base, e.g., pyridine hydrochloride.

  在吡啶型氮基（如盐酸吡啶）的卤化氢盐存在下，与氟化盐（如 KF 或氟化铵）反应，使至少有一个氯、溴或碘直接与磷键合的磷化合物与氟反卤化。
• Transhalogenation of halophosphorus compounds
  申请人：ETHYL CORPORATION

  公开号：EP0353598A2

  公开（公告）日：1990-02-07

  Phosphorus compounds having at least one chlorine, bromine or iodine bonded directly to phosphorus are trans­halogenated with fluorine by reaction with a hydrogen fluoride salt of a pyridine-type nitrogen base, e.g., pyridine hydrofluoride in an inert solvent.

  通过在惰性溶剂中与吡啶型氮基（如氟化氢吡啶）的氟化氢盐反应，使至少有一个氯、溴或碘直接与磷键合的磷化合物与氟发生反卤化反应。
• Process for transhalogenating a halophosphorus compound with hydrogen fluoride
  申请人：ALBEMARLE CORPORATION

  公开号：EP0357048A2

  公开（公告）日：1990-03-07

  Phosphorus compounds having at least one chlorine, bromine or iodine bonded directly to phosphorus are trans­halogenated with fluorine by reaction with anhydrous hydrogen fluoride in an inert solvent in a manner such that said anhydrous hydrogen fluoride is added to said phosphorus compound at a rate such that said anhydrous hydrogen fluoride reacts with said phosphorus compound without the accumulation of an amount of unreacted anhy­drous hydrogen fluoride which is sufficient to cause substantial decomposition of the desired fluorophosphorus product.

  至少有一个氯、溴或碘直接与磷键合的磷化合物，通过在惰性溶剂中与无水氟化氢反应，用氟进行反卤化，反应的方式是将所述无水氟化氢加入到所述磷化合物中，加入的速度使所述无水氟化氢与所述磷化合物反应，而不会积累一定量的未反应的无水氟化氢，足以导致所需的氟磷产品的大量分解。